Citation: LI Shan-Shan, ZHANG Mei-Na, LI Zheng, LI Xia. Nickel Complex Constructed by Biphenyldicarboxylic Acid: Synthesis, Crystal Structure and Photocatalytic Activity of Rhodamine B[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1148-1154. doi: 10.11862/CJIC.2019.149 shu

Nickel Complex Constructed by Biphenyldicarboxylic Acid: Synthesis, Crystal Structure and Photocatalytic Activity of Rhodamine B

Department of Chemistry, Capital Normal University, Beijing 100048, China

Corresponding author: LI Xia, xiali@cnu.edu.cn
Received Date: 5 December 2018
Revised Date: 5 May 2019

Figures(4)

Two complexes[Ni(3, 3'-dpdc)(dpp)]_n (1) and[Ni(2, 2'-dpdc)(phen)(H₂O)₂]_n (2) were obtained under different reaction conditions (2, 2'-H₂dpdc=2, 2'-biphenyldicarboxylic acid, 3, 3'-H₂dpdc=3, 3'-biphenyldicarboxylic acid, phen=1, 10-phenanthroline, dpp=1, 3-bis(4-pyridyl)propane), and their structures were characterized by X-ray single crystal diffraction. Complex 1 belongs to monoclinic system, space group P2₁/c. It has two-dimensional grid structure and the coordination environment of Ni(Ⅱ) ion is[NiO₂N₄]. The two carboxyl groups of the 3, 3'-dpdc ligand coordinate to the Ni(Ⅱ) ion by a bidentate chelate coordination mode to form a Ni-(3, 3'-dpdc) one-dimensional chain structure, and the dpp ligand adopts a single nitrogen atom bridged coordination mode to connect two Ni(Ⅱ)) ions to form a Ni-dpp one-dimensional chain. The two chains penetrate each other to form a two-dimensional grid structure. The two-dimensional grid structure is stacked into a three-dimensional structure by C15D-H15…O2, C21-H21A…O1 hydrogen bonding. Complex 2 belongs to orthorhombic crystal system, space group P2₁2₁2₁. The complex shows a one-dimensional zigzag structure. The coordination envrionment of Ni(Ⅱ) ion is[NiO₄N₂]. The two carboxyl groups of 2, 2'-dpdc adopt a single-tooth bridged coordination mode. The adjacent Ni(Ⅱ) ions are linked by 2, 2'-dpdc ligand to form the Ni-2, 2'-dpdc zigzag chain structure, and the chains are connected to form a three-dimensional supramolecular structure by O-H…O and C-H…π. The photocatalytic degradation of the organic dye rhodamine B by two complexes was investigated. The results show that complexes can degrade rhodamine B efficiently.
- transition metal complex,
- 2, 2'-biphenyldicarboxylic acid,
- 3, 3'-biphenyldicarboxylic acid,
- rhodamine B,
- crystal structure,
- photocatalysis
1. [1]
  Maurin G, Serre C, Cooper A, et al. Chem. Soc. Rev., 2017, 46(11):3104-3107 doi: 10.1039/C7CS90049J
2. [2]
  Poater J, Gimferrer M, Poater A. Inorg. Chem., 2018, 57(12):6981-6990 doi: 10.1021/acs.inorgchem.8b00670
3. [3]
  Stock N, Biswas S. Chem. Rev., 2012, 112(2):933-969
4. [4]
  Zhou H C J, Kitagawa S. Chem. Soc. Rev., 2014, 43(16):5415-5418 doi: 10.1039/C4CS90059F
5. [5]
  Lin Z J, Lv J, Hong M C, et al. Chem. Soc. Rev., 2014, 43(16):5867-5895 doi: 10.1039/C3CS60483G
6. [6]
  Han S D, Wang D, Pan J, et al. Inorg. Chem., 2018, 57(18):11318-11321 doi: 10.1021/acs.inorgchem.8b02030
7. [7]
  Maurin G, Serre C, Cooper A, et al. Chem. Soc. Rev., 2017, 46(11):3104-3107 doi: 10.1039/C7CS90049J
8. [8]
  Wang Y, He M H, Gao X X, et al. Inorg. Chem. Front., 2018, 5(11):2811-2817 doi: 10.1039/C8QI00946E
9. [9]
  Ren J W, Ledwaba M, Musyoka N M, et al. Coord. Chem. Rev., 2017, 349:169-197 doi: 10.1016/j.ccr.2017.08.017
10. [10]
  Espallargas G M, Coronado E. Chem. Soc. Rev., 2018, 47(2):533-557 doi: 10.1039/C7CS00653E
11. [11]
  Coronado E, Espallargas G M. Chem. Soc. Rev., 2013, 42(4):1525-1539 doi: 10.1039/C2CS35278H
12. [12]
  Dolgopolova E A, Rice A M, Martin C R, et al. Chem. Soc. Rev., 2018, 47(13):4710-4728 doi: 10.1039/C7CS00861A
13. [13]
  Ji G F, Gao X H, Zheng T X, et al. Inorg. Chem., 2018, 57(17):10525-10532 doi: 10.1021/acs.inorgchem.8b00313
14. [14]
  Qu X L, Zheng X L, Li X. RSC Adv., 2016, 6(73):69007-69015 doi: 10.1039/C6RA08419B
15. [15]
  Bernini M C, Platero-Prats A E, Snejko N, et al. CrystEngComm, 2012, 14(17):5493-5504 doi: 10.1039/c2ce06563k
16. [16]
  Devic T, Serre C. Chem. Soc. Rev., 2014, 43(16):6097-6115 doi: 10.1039/C4CS00081A
17. [17]
  Fan L M, Fan W L, Li B, et al. CrystEngComm, 2015, 17(48):9413-9422 doi: 10.1039/C5CE01740H
18. [18]
  Zhou Y, Qin L, Wu M K, et al. Cryst. Growth Des., 2018, 18(10):5738-5744 doi: 10.1021/acs.cgd.8b00895
19. [19]
  Ahmad N, Younus H A, Chughtai A H, et al. Catal. Sci. Technol., 2018, 8(16):4010-4017 doi: 10.1039/C8CY00579F
20. [20]
  Li Y X, Yang Z X, Wang Y L, et al. Nat. Comm., 2017, 8(1):1354 doi: 10.1038/s41467-017-01208-w
21. [21]
  Wei F H, Chen D, Liang Z, et al. Nanomaterials, 2018, 8(4):248-258 doi: 10.3390/nano8040248
22. [22]
  WANG Ren-Shu, FENG Jing, LEI Yi-Zhu, et al. Chinese J. Inorg. Chem., 2018, 34(7):1221-1230
23. [23]
  ZHOU Xin, ZHANG Mei-Na, LI Xia, et al. Chinese J. Inorg. Chem., 2018, 34(7):1285-1292
24. [24]
  Dong X W, Yao Y, Li Y G, et al. J. Mol. Struct., 2017, 1149:744-749 doi: 10.1016/j.molstruc.2017.08.029
25. [25]
  Wang X L, Xiong Y, Liu X X, et al. Polyhedron, 2018, 151:264-272 doi: 10.1016/j.poly.2018.05.050
26. [26]
  Babu R, Roshan R, Gim Y, et al. J. Mater. Chem. A, 2017, 5(30):15961-15969 doi: 10.1039/C7TA04004K
27. [27]
  Qian J, Jiang F, Su K, et al. Inorg. Chem., 2014, 53(23):12228-12230 doi: 10.1021/ic501728z
28. [28]
  Peedikakkal A M P, Quah H S, Chia S, et al. Inorg. Chem., 2018, 57(18):11341-11348 doi: 10.1021/acs.inorgchem.8b00637
29. [29]
  Wang Z, Zhang J H, Pan M, et al. J. Mater. Chem. A, 2018, 6(36):17698-17705 doi: 10.1039/C8TA06249H
30. [30]
  Li J M, Li R, Li X. CrystEngComm, 2018, 20(34):4962-4972 doi: 10.1039/C8CE00915E
31. [31]
  Lu L, Wang J, Cai S L, et al. J. Coord. Chem., 2017, 70(19):3409-3421 doi: 10.1080/00958972.2017.1390224
32. [32]
  Fan T T, Li J J, Li X, et al. CrystEngComm, 2015, 17(48):9443-9451 doi: 10.1039/C5CE01772F
33. [33]
  Sheldrick G M. SHELXS 97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.
34. [34]
  Sheldrick G M. SHELXL 97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
35. [35]
  Pan Y, Liu W C, Liu D, et al. Inorg. Chem. Comm., 2019, 100:93-96
1. [1]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
2. [2]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
3. [3]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
4. [4]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
5. [5]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
6. [6]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
7. [7]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
8. [8]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
9. [9]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
10. [10]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
11. [11]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
14. [14]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
15. [15]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
19. [19]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
20. [20]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(500)
HTML views(110)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142