Citation: LIU Hao, ZHAO Ding-Xuan, GONG Guo-Dong. Ferromagnetic Analysis of Hydrogenated Carbon Nanospheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1188-1194. doi: 10.11862/CJIC.2019.146 shu

Ferromagnetic Analysis of Hydrogenated Carbon Nanospheres

1.
School of Mechanical and Aerospace Engineering, Jilin University, Changchun 130012, China
2.
School of Mechanical Engineering, Yanshan University, Qinhuangdao, Hebei 066044, China
3.
College of Physics, Jilin University, Changchun 130012, China

Corresponding author: ZHAO Ding-Xuan, zdx-yw@ysu.edu.com
Received Date: 22 January 2019
Revised Date: 20 April 2019

Figures(7)

In order to study the origin of ferromagnetism of spherical carbon structure, we prepared two kinds of hydrogenated carbon nanospheres(HCNSs) by solvothermal synthesis at 80 and 120℃, respectively, using Na as reducing agent and chloroform as raw material. Then we performed systematic characterization on them. According to SEM images, we found that the average particle size of HCNSs synthesized at 80℃ was 150 nm, while the average particle size of HCNSs synthesized at 120℃ was 300 nm, and the dispersion of the latter is better than that of the former. The TEM images showed that both hydrogenated carbon nanospheres were in the form of onion-like graphite, and the graphite layer was distributed in a wave shape on the curved surface of the carbon sphere. It can be seen from the X-ray photoelectron spectroscopy that the degree of hydrogenation of the hydrogenated carbon nanospheres at 80℃ is higher, which is consistent with the results of elemental analysis. The infrared spectroscopy (IR) of the HCNSs indicates that the two nanospheres have relative low carbon-hydrogen bond content. The Raman spectra of the HCNSs indicates that the obtained HCNSs have high degree of disorder and poor crystallinity. We magnetically characterized the HCNSs at room temperature, and the results show that both the HCNSs have ferromagnetism. The negative Gaussian curvature caused by wavy graphite layers and high concentration defects are the main reason for the ferromagnetism of HCNSs.
- hydrogenated carbon nanospheres,
- morphology features,
- degree of disorder,
- hydrogenation ferromagnetic,
1. [1]
  LI Yan-Bing, DUAN Xiao-Bo, HAN Ya-Miao, et al. Chinese J. Inorg. Chem., 2014, 31:641-648
2. [2]
  CI Ying, GE Jun, WANG Xiao-Feng, et al. Chinese J. Inorg. Chem., 2007, 23:365-368 doi: 10.3321/j.issn:1001-4861.2007.02.034
3. [3]
  Wang Q, Li H, Chen L, et al. Carbon, 2001, 39:2211-2214 doi: 10.1016/S0008-6223(01)00040-9
4. [4]
  Lee K T, Jung Y S, Oh S M. J. Am. Chem. Soc., 2003, 125:5652-5653 doi: 10.1021/ja0345524
5. [5]
  Hu G, Ma D, Cheng M, et al. Chem. Commun., 2002, 8:1948-1949
6. [6]
  Mi Y, Liu Y, Yuan D, et al. Chem. Lett., 2005, 34:846-847 doi: 10.1246/cl.2005.846
7. [7]
  Ng S W L, Yilmaz G, Ong W L, et al. Appl. Catal. B, 2018, 220:533-541 doi: 10.1016/j.apcatb.2017.08.069
8. [8]
  Yan L, Di L, Yan T, et al. ACS Sustainable Chem. Eng., 2018, 6:5265-5272 doi: 10.1021/acssuschemeng.7b04922
9. [9]
  Zhao S, Yan T, Hui W, et al. Appl. Surf. Sci., 2016, 369:460-469 doi: 10.1016/j.apsusc.2016.02.085
10. [10]
  Hui W, Shi L, Yan T, et al. J. Mater. Chem. A, 2014, 2:4739-4750 doi: 10.1039/C3TA15152B
11. [11]
  Park N, Yoon M, Berber S, et al. Phys. Rev. Lett., 2003, 91:237204 doi: 10.1103/PhysRevLett.91.237204
12. [12]
  Harigaya K. J. Phys.:Condens. Matter, 2001, 13:1295-302 doi: 10.1088/0953-8984/13/6/309
13. [13]
  Esquinazi P, Setzer A, Hhne R, et al. Phys. Rev. B, 2002, 66:024429 doi: 10.1103/PhysRevB.66.024429
14. [14]
  Maruyama M, Kusakabe K, Tsuneyuki S, et al. J. Phys. Chem. Solids, 2004, 65:119-122 doi: 10.1016/j.jpcs.2003.10.004
15. [15]
  Makarova T L, Sundqvist B, Hhne R, et al. Nature, 2001, 413:716-718 doi: 10.1038/35099527
16. [16]
  Casiraghi C, Ferrari A C, Robertson J. Phys. Rev. B:Condens. Matter, 2005, 72:085401 doi: 10.1103/PhysRevB.72.085401
17. [17]
  Ferrari A C, Robertson J. Phys. Rev. B:Condens. Matter, 2000, 61:14095-14107 doi: 10.1103/PhysRevB.61.14095
18. [18]
  Zhang Y, Talapatra S, Kar S, et al. Phys. Rev. Lett., 2007, 99:107201 doi: 10.1103/PhysRevLett.99.107201
19. [19]
  Friedman A L, Chun H, Jung Y J, et al. Phys. Rev. B:Condens. Matter, 2012, 81:760-762
20. [20]
  Lehtinen P O, Foster A S, Yuchen M, et al. Phys. Rev. Lett., 2004, 93:187202 doi: 10.1103/PhysRevLett.93.187202
1. [1]
  Zhiwen HU , Ping LI , Yulong YANG , Weixia DONG , Qifu BAO . Morphology effects on the piezocatalytic performance of BaTiO₃. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 339-348. doi: 10.11862/CJIC.20240172
2. [2]
  Shiyi WANG , Chaolong CHEN , Xiangjian KONG , Lansun ZHENG , Lasheng LONG . Polynuclear lanthanide compound [Ce₄^ⅢCe₆^Ⅳ(μ₃-O)₄(μ₄-O)₄(acac)₁₄(CH₃O)₆]·2CH₃OH for the hydroboration of amides to amine. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 88-96. doi: 10.11862/CJIC.20240342
3. [3]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
4. [4]
  Xiaojing Tian , Zhichun Huang , Qingsong Zhang , Xu Wang , Ning Yang , Nanping Deng . PNIPAm Thermo-Responsive Nanofibers Mats: Morphological Stability and Response Behavior under Cross-Linking. Acta Physico-Chimica Sinica, 2024, 40(4): 2304037-0. doi: 10.3866/PKU.WHXB202304037
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
7. [7]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
8. [8]
  Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO₄:Yb³⁺,Er³⁺ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
9. [9]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
10. [10]
  Baitong Wei , Rongxiu Zhu , Zhenghu Xu . Thalidomide: Defeating the Three Evils. University Chemistry, 2026, 41(2): 273-278. doi: 10.12461/PKU.DXHX202502020
11. [11]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
12. [12]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
13. [13]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
14. [14]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
15. [15]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
16. [16]
  Zhiyang Li , Hui Deng , Xinqi Cai , Zhuo Chen . Magnetic Core/Shell-Capsules Locally Neutralize Gastric Acid for Efficient Delivery of Active Probiotics. Acta Physico-Chimica Sinica, 2024, 40(7): 2306051-0. doi: 10.3866/PKU.WHXB202306051
17. [17]
  Xiaohui Li , Ze Zhang , Jingyi Cui , Juanjuan Yin . Advanced Exploration and Practice of Teaching in the Experimental Course of Chemical Engineering Thermodynamics under the “High Order, Innovative, and Challenging” Framework. University Chemistry, 2024, 39(7): 368-376. doi: 10.3866/PKU.DXHX202311027
18. [18]
  Wenwen Zhang , Peichao Zhang , Conghao Gai , Xiaoyun Chai , Yan Zou , Qingjie Zhao . Unveiling Kinetics at Natural Abundance: ¹³C NMR Isotope Effect Experiments. University Chemistry, 2025, 40(10): 203-207. doi: 10.12461/PKU.DXHX202411076
19. [19]
  Jianan Fang , Youhao Gu , Zexuan Gui , Laiying Zhang , Jiawei Yan , Ruming Yuan , Xiaoming Xu . Experimental Improvement and Expansion of the Electromotive Force Method to Determine the Mean Activity Coefficient of Electrolyte Solution. University Chemistry, 2025, 40(11): 263-271. doi: 10.12461/PKU.DXHX202504055
20. [20]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(1219)
HTML views(251)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142