Citation: LIU Hao, ZHAO Ding-Xuan, GONG Guo-Dong. Ferromagnetic Analysis of Hydrogenated Carbon Nanospheres[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1188-1194. doi: 10.11862/CJIC.2019.146 shu

Ferromagnetic Analysis of Hydrogenated Carbon Nanospheres

1.
School of Mechanical and Aerospace Engineering, Jilin University, Changchun 130012, China
2.
School of Mechanical Engineering, Yanshan University, Qinhuangdao, Hebei 066044, China
3.
College of Physics, Jilin University, Changchun 130012, China

Corresponding author: ZHAO Ding-Xuan, zdx-yw@ysu.edu.com
Received Date: 22 January 2019
Revised Date: 20 April 2019

Figures(7)

In order to study the origin of ferromagnetism of spherical carbon structure, we prepared two kinds of hydrogenated carbon nanospheres(HCNSs) by solvothermal synthesis at 80 and 120℃, respectively, using Na as reducing agent and chloroform as raw material. Then we performed systematic characterization on them. According to SEM images, we found that the average particle size of HCNSs synthesized at 80℃ was 150 nm, while the average particle size of HCNSs synthesized at 120℃ was 300 nm, and the dispersion of the latter is better than that of the former. The TEM images showed that both hydrogenated carbon nanospheres were in the form of onion-like graphite, and the graphite layer was distributed in a wave shape on the curved surface of the carbon sphere. It can be seen from the X-ray photoelectron spectroscopy that the degree of hydrogenation of the hydrogenated carbon nanospheres at 80℃ is higher, which is consistent with the results of elemental analysis. The infrared spectroscopy (IR) of the HCNSs indicates that the two nanospheres have relative low carbon-hydrogen bond content. The Raman spectra of the HCNSs indicates that the obtained HCNSs have high degree of disorder and poor crystallinity. We magnetically characterized the HCNSs at room temperature, and the results show that both the HCNSs have ferromagnetism. The negative Gaussian curvature caused by wavy graphite layers and high concentration defects are the main reason for the ferromagnetism of HCNSs.
- hydrogenated carbon nanospheres,
- morphology features,
- degree of disorder,
- hydrogenation ferromagnetic,
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沈阳化工大学材料科学与工程学院沈阳 110142