Citation: WANG Ting-Wei, CHEN Xing-Han, CHEN Hong-Jin, SHAO Jun-Yan, SHI Heng, XING Jie-Ni, LÜ Guang-Yu, ZHANG Rui, LIU Jian. Synthesis, Structure and Magnetic Properties of Binuclear Pinene Pyridyl Pyrazine Dy(Ⅲ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1183-1187. doi: 10.11862/CJIC.2019.136 shu

Synthesis, Structure and Magnetic Properties of Binuclear Pinene Pyridyl Pyrazine Dy(Ⅲ) Complex

Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

Corresponding author: ZHANG Rui, zhangrui@njfu.edu.cn LIU Jian, liu.jian@njfu.edu.cn
Received Date: 19 January 2019
Revised Date: 6 April 2019

Figures(6)

Single ion magnets based on Dy(Ⅲ) complexes are of particular interest due to their doubly degenerate high spin ground state and strong axial single-ion anisotropy. Herein, a new dinuclear dysprosium (Dy) complex[Dy₂(PY)(TTA)₆] (1) was prepared by the reaction between a chiral pinene pyridyl pyrazine ligand (PY) and β-diketone Dy compound (Dy(TTA)₃). X-ray single crystal diffraction characterization of the obtained complex indicated that the configuration inversion of chiral pinene group occurred during the crystal growth, which results in a central symmetry configuration. The temperature-dependent susceptibility test revealed that the prepared Dy complex exhibits slow magnetic relaxation in the absence of external dc magnetic field.
- pinene pyridyl,
- β-diketone,
- dinuclear dysprosium complex,
- magnetic property
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