Citation: GUO Shu-Wang, GAO Zhan-Yong, SONG Jin-Ling, BULIN Chao-Ke, ZHANG Bang-Wen. ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1195-1202. doi: 10.11862/CJIC.2019.131 shu

ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids

School of Materials and Metallurgy & Instrumental Analysis Center, Inner Mongolia University of Science and Technology, Baotou, Inner Mongolia 014010, China

Corresponding author: ZHANG Bang-Wen, bangwenz@126.com
Received Date: 27 January 2019
Revised Date: 18 April 2019

Figures(5)

An ultra-thin MoS₂/reduced graphene oxide (UT-MoS₂/rGO) catalyst was prepared by one-step hydrothermal method, in which H₃PO₄·12MoO₃ and C₃H₇NO₂S were used as precursors and rGO was used as the carbon source. The microstructure of the UT-MoS₂/rGO catalyst and its catalytic performance for hydrogen evolution reaction (HER) were studied. The results showed that UT-MoS₂/rGO hybrid exhibited excellent electrocatalytic properties due to rich active sites from UT-MoS₂, robust support of electrically conducting rGO and good bonding between UT-MoS₂ and rGO. The initial overpotential was -66 mV; the overpotential was -145 mV at a current density of -10 mA·cm^-2 with the Tafel slope of 42.9 mV·dec^-1; the AC impedance was 0.76 Ω; the catalytic activity maintained 98% after 1 000 cycles at 0.1 to 0.2 V.
- hydrothermal synthesis,
- MoS₂,
- graphene,
- electrocatalysis,
- hydrogen evolution reaction
1. [1]
  Nrskov J K, Bligaard T, Rossmeisl J, et al. Nat. Chem., 2009, 1(1):37-46
2. [2]
  Hinnemann B, Moses P G, Bonde J, et al. J. Am. Chem. Soc., 2005, 127(15):5308-5309 doi: 10.1021/ja0504690
3. [3]
  Lukowski M A, Daniel A S, MengF, et al. J. Am. Chem. Soc., 2013, 135(28):10274-10277 doi: 10.1021/ja404523s
4. [4]
  Voiry D, Salehi M, Silva R, et al. Nano Lett., 2013, 13(12):6222-6227 doi: 10.1021/nl403661s
5. [5]
  Lin J, Peng Z W, Wang G, et al. Adv. Energy Mater., 2014, 4(10):1301875 doi: 10.1002/aenm.201301875
6. [6]
  Liu W L, Benson J, Dawson C, et al. Nanoscale, 2017, 9(36):13515-13526 doi: 10.1039/C7NR04790H
7. [7]
  Faber M S, Dziedzic R, Lukowski M A, et al. J. Am. Chem. Soc., 2014, 136(28):10053-10061 doi: 10.1021/ja504099w
8. [8]
  Kong D S, Wang H T, Lu Z L, et al. J. Am. Chem. Soc., 2014, 136(13):4897-4900 doi: 10.1021/ja501497n
9. [9]
  Vrubel H, Merki D, Hu X. Energy Environ. Sci., 2012, 5(3):6136-6144 doi: 10.1039/c2ee02835b
10. [10]
  Wang T Y, Liu L, Zhu Z W, et al. Energy Environ. Sci., 2013, 6(2):625-633
11. [11]
  Laursen A B, Kegnaes S, Dahl S, et al. Energy Environ. Sci., 2012, 5(2):5577-5591 doi: 10.1039/c2ee02618j
12. [12]
  Kibsgaard J, Chen Z B, Reinecke B N, et al. Nat. Mater., 2012, 11(11):963-969 doi: 10.1038/nmat3439
13. [13]
  Kong D S, Wang H T, Cha J J, et al. Nano Lett., 2013, 13(3):1341-1347 doi: 10.1021/nl400258t
14. [14]
  Jaramillo T F, Jrgensen K P, Bonde J, et al. Science, 2007, 317(5834):100-102 doi: 10.1126/science.1141483
15. [15]
  Yin Y, Han J C, Zhang Y M, et al. J. Am. Chem. Soc., 2016, 138(25):7965-7972 doi: 10.1021/jacs.6b03714
16. [16]
  Lau V W, Masters A F, Bond A M, et al. Chem. Eur. J., 2012, 18(26):8230-8239 doi: 10.1002/chem.v18.26
17. [17]
  Tang Y J, Wang Y, Wang X L, et al. Adv. Energy Mater., 2016, 6(12):1600116 doi: 10.1002/aenm.201600116
18. [18]
  Xie J F, Qu H C, Xin J P, et al. Nano Res., 2017, 10(4):1178-1188 doi: 10.1007/s12274-017-1421-x
19. [19]
  Jayabal S, Saranya G, Wu J, et al. J. Mater. Chem. A, 2017, 5(47):24540-24563 doi: 10.1039/C7TA08327K
20. [20]
  Yu X Y, Feng Y, Jeon Y, et al. Adv. Mater., 2016, 28(40):9006-9011 doi: 10.1002/adma.v28.40
21. [21]
  Wu L Q, Xu X B, Zhao Y Q, et al. Appl. Surf. Sci., 2017, 425:470-477 doi: 10.1016/j.apsusc.2017.06.223
22. [22]
  Zhao X, Ma X, Lu Q Q, et al. Electrochim. Acta, 2017, 249:72-78 doi: 10.1016/j.electacta.2017.08.004
23. [23]
  Ye L J, Chen S J, Li W J, et al. J. Phys. Chem. C, 2015, 119(17):9560-9567 doi: 10.1021/jp5128018
24. [24]
  Li R C, Yang L J, Xiong T L, et al. J. Power Sources, 2017, 356:133-139 doi: 10.1016/j.jpowsour.2017.04.060
25. [25]
  Guo J X, Li F F, Sun Y F, et al. J. Power Sources, 2015, 291:195-200 doi: 10.1016/j.jpowsour.2015.05.034
26. [26]
  Cao P F, Peng J, Li J Q, et al. J. Power Sources, 2017, 347:210-219 doi: 10.1016/j.jpowsour.2017.02.056
27. [27]
  Paniagua S A, Baltazar J, Sojoudi H, et al. Mater. Horiz., 2014, 1:111-115 doi: 10.1039/C3MH00035D
28. [28]
  Xu X B, Sun Y, Qiao W, et al. Appl. Surf. Sci., 2017, 396:1520-1527 doi: 10.1016/j.apsusc.2016.11.201
29. [29]
  Li Y G, Wang H L, Xie L M, et al. J. Am. Chem. Soc., 2011, 133(19):7296-7299 doi: 10.1021/ja201269b
30. [30]
  WAN Meng, YU Dan-Ni, ZHU Han, et al. Chinese J. Inorg. Chem., 2017, 33(4):595-600
31. [31]
  Hua S X, Qu D, An L, et al. Chin. J. Catal., 2017, 38(6):1028-1037 doi: 10.1016/S1872-2067(17)62830-4
32. [32]
  Guo Y X, Gan L F, Shang C S, et al. Adv. Funct. Mater., 2017, 27(5):1602699 doi: 10.1002/adfm.v27.5
33. [33]
  Yin X Y, Yan Y, Miao M, et al. Chem. Eur. J., 2017, 24(3):556-560
34. [34]
  Yu H T, Zhang B W, Bulin C K, et al. Sci. Rep., 2016, 6:36143 doi: 10.1038/srep36143
35. [35]
  Xu S R, Zhu Q, Chen T, et al. Mater. Chem. Phys., 2018, 219:399-410 doi: 10.1016/j.matchemphys.2018.08.048
36. [36]
  Bosch-Navarro C, Coronado E, Marti-Gastaldo C, et al. Nanoscale, 2012, 4(13):3977-3982 doi: 10.1039/c2nr30605k
37. [37]
  Gopalakrishnan D, Damien D, Shaijumon M M. ACS Nano, 2014, 8(5):5297-5303 doi: 10.1021/nn501479e
38. [38]
  Li H, Zhang Q, Yap C C R, et al. Adv. Funct. Mater., 2012, 22(7):1385-1390 doi: 10.1002/adfm.v22.7
39. [39]
  Li F, Li J, Lin X Q, et al. J. Power Sources, 2015, 300:301-308 doi: 10.1016/j.jpowsour.2015.09.084
40. [40]
  Bonde J, Moses P G, Jaramillo T F, et al. Faraday Discuss., 2009, 140:219-231 doi: 10.1039/B803857K
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ElectrocatalyticHydrogen Evolution Performance of Ultra-Thin MoS₂ Loaded Graphene Hybrids