Citation: WANG Fei, TIAN Yi-Guang, ZHANG Qiao. Synthesis, Crystal Structure and luminescent Properties of Sr_0.955Al_2-xB_xSi₂O₈: 0.025Eu²⁺ Phosphors[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1085-1092. doi: 10.11862/CJIC.2019.126 shu

Synthesis, Crystal Structure and luminescent Properties of Sr_0.955Al_2-xB_xSi₂O₈: 0.025Eu²⁺ Phosphors

WANG Fei ^1,2,, ,
TIAN Yi-Guang ^3,, ,
ZHANG Qiao ³

1.
Experimental Center of Anhui Sanlian University, Hefei 230601, China
2.
College of Chemistry and Chemical Engineering, Anhui University, Hefei 230601, China
3.
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China

Corresponding author: WANG Fei, wangfchina@163.com TIAN Yi-Guang, gytian@wzu.edu.cn
Received Date: 27 December 2018
Revised Date: 10 April 2019

Figures(11)

A series of luminescence phosphors Sr_0.955Al_2-xB_xSi₂O₈:0.025Eu²⁺ (x=0~0.9) were prepared via solid-state reaction in a weak reductive atmosphere. The lattice positions and the luminescent mechanism of Eu²⁺ in the host were discussed, the effects of B(Ⅲ)-substitution on the host lattices and spectral properties were also investigated. It was found that the complete solid solutions were formed in the whole range of x=0~0.9, as B(Ⅲ) substituted for Al(Ⅲ) entered to SrAl₂Si₂O₈. The lattice parameters (a, b, c) and unit cell volume (V) of phosphors Sr_0.955Al_2-xB_xSi₂O₈:0.025Eu²⁺ (x=0~0.9) decreased linearly and lattice parameter (β) increased linearly as the increase of substitution amount of B(Ⅲ). A broad excitation spectrum consisted of four excitation bands, which was in a range of 225~400 nm, and an apparent peak at 350 nm. Full width at half maximum (FWHM) increased from 90 to 102 nm as increase of the substitution amount of B(Ⅲ). The emission spectrum was a broad-band in a range of 370~600 nm, which could be fitted two peaks of 409 and 447 nm, and its apparent peak was at 409 nm. Two fitted peaks were blue shifted and the intensity ratio of the fitted peaks decreased linearly as the increase of the substitution amount of B(Ⅲ)). The coordination number of Sr²⁺ was 9 in SrAl₂Si₂O₈:Eu²⁺, which has been confirmed by the experimental results and empirical formula of Van Uitert. The distance between the luminescent center Eu and the ligand O increased due to the Al(Ⅲ) replaced by B(Ⅲ), so that the crystal field strength of Eu²⁺ decreased, and the 5d energy level split of the luminescent center Eu²⁺ decreased, the center of gravity of the lowest emission level of Eu²⁺ was shifted upward, and the two fitted peaks were linearly blue-shifted.
- luminescence,
- SrAl₂Si₂O₈:Eu²⁺,
- B(Ⅲ)-substitution,
- crystal structure,
- luminescent properties
1. [1]
  Nakamura S, Mukai T, Senoh M. Appl. Phys. Lett., 1994, 64:1687-1689 doi: 10.1063/1.111832
2. [2]
  Ci Z P, Que M D, Shi Y R, et al. Inorg. Chem., 2014, 53:2195-2199 doi: 10.1021/ic402859s
3. [3]
  Xia Z G, Liu Q L. Prog. Mater. Sci., 2016, 84:59-117 doi: 10.1016/j.pmatsci.2016.09.007
4. [4]
  Lin C C, MeijerinkA, Liu R S. J. Phys. Chem. Lett., 2016, 7:495-503 doi: 10.1021/acs.jpclett.5b02433
5. [5]
  Zhong J S, Chen D Q, Yuan S, et al. Inorg. Chem., 2018, 57:8978-8987 doi: 10.1021/acs.inorgchem.8b00947
6. [6]
  Ye S, Xiao F, Pan Y X, et al. Mater. Sci. Eng. R, 2010, 71:1-34 doi: 10.1016/j.mser.2010.07.001
7. [7]
  Cai P Q, Qin L, Chen C L, et al. Inorg. Chem., 2018, 57:3073-3081 doi: 10.1021/acs.inorgchem.7b02938
8. [8]
  WANG Fei. Acta Photonica Sinica, 2018, 47(8):0816001
9. [9]
  Ray S, Tadge P, Nair G B, et al. Ceram. Int., 2018, 44:5506-5512 doi: 10.1016/j.ceramint.2017.12.190
10. [10]
  Homayoni H, Sahi S, Ma L. J. Lumin., 2018, 198:132-137 doi: 10.1016/j.jlumin.2018.02.042
11. [11]
  Tang Z B, Wang D Y, Khan W U, et al. J. Mater. Chem. C, 2016, 4:5307-5313 doi: 10.1039/C6TC01449F
12. [12]
  Kalaycioglu N O, Circir E. J. Therm. Anal. Calorim., 2013, 111:273-277 doi: 10.1007/s10973-012-2248-z
13. [13]
  Hai O, Jiang H Y, Xu D, et al. Mater. Res. Bull., 2016, 76:358-364 doi: 10.1016/j.materresbull.2015.12.048
14. [14]
  Yang W J, Luo L Y, Chen T M, et al. Chem. Mater., 2005, 17:3883-3888 doi: 10.1021/cm050638f
15. [15]
  Clabau F, Garcia A, Bonville P, et al. J. Solid State Chem., 2008, 181:1456-1461 doi: 10.1016/j.jssc.2008.03.011
16. [16]
  WANG Fei, TIAN Yi-Guang, ZHANG Qiao. Chinese J. Inorg. Chem., 2014, 30(11):2530-2536
17. [17]
  Shang M, Liang S, Qu N, et al. Chem. Mater., 2017, 29:1813-1829 doi: 10.1021/acs.chemmater.6b05493
18. [18]
  Zhou J, Wang Y H, Liu B T, et al. J. Alloys Compd, 2009, 484:439-443 doi: 10.1016/j.jallcom.2009.04.118
19. [19]
  Chiari G, Calleri M, Bruno E, et al. Am. Mineral., 1975, 60:111-115
20. [20]
  Van Uitert L G. J. Lumin., 1984, 29:1-9 doi: 10.1016/0022-2313(84)90036-X
21. [21]
  Dorenbos P. J. Lumin., 2003, 104:239-260 doi: 10.1016/S0022-2313(03)00078-4
22. [22]
  Ye S, Liu Z S, Wang X T, et al. J. Lumin., 2009, 129:50-54 doi: 10.1016/j.jlumin.2008.07.015
1. [1]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
2. [2]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
3. [3]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
4. [4]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
5. [5]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
8. [8]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
9. [9]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
10. [10]
  Shuyan ZHAO . Field-induced Co^Ⅱ single-ion magnet with pentagonal bipyramidal configuration. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1583-1591. doi: 10.11862/CJIC.20240231
11. [11]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
12. [12]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
13. [13]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
14. [14]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
15. [15]
  Jiakun Bai , Junhui Jia , Aisen Li . An elastic organic crystal with piezochromic luminescent behavior. Chinese Journal of Structural Chemistry, 2024, 43(6): 100323-100323. doi: 10.1016/j.cjsc.2024.100323
16. [16]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
17. [17]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
18. [18]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
19. [19]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
20. [20]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(592)
HTML views(55)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Crystal Structure and luminescent Properties of Sr0.955Al2-xBxSi2O8: 0.025Eu2+ Phosphors

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis, Crystal Structure and luminescent Properties of Sr_0.955Al_2-xB_xSi₂O₈: 0.025Eu²⁺ Phosphors