Citation: HONG Xin-Chao, SUN Jing, ZHOU Chen, TANG Juan, BI Guan. Fluorescence Characteristics of Cr³⁺ in Different Matrices Y₃Ga₅O₁₂ or Ga₂O₃[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1059-1064. doi: 10.11862/CJIC.2019.125 shu

Fluorescence Characteristics of Cr³⁺ in Different Matrices Y₃Ga₅O₁₂ or Ga₂O₃

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Changchun 130022, China

Corresponding author: SUN Jing, sj-cust@126.com ZHOU Chen, 59982153@qq.com
Received Date: 18 January 2019
Revised Date: 25 March 2019

Figures(9)

Two kinds of polycrystalline powders Ga_2-2xO₃:2xCr³⁺ (Ga₂O₃:xCr) and Y₃Ga_5-5xO₁₂:5xCr³⁺ (YGG:xCr) (x=0.01, 0.03, 0.05, 0.07) were synthesized by sol-gel high temperature solid phase synthesis with Ga₂O₃, Y₂O₃, Cr(NO₃)₃ ·9H₂O as raw materials and citric acid as complexing agent. The X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM) and fluorescence spectroscopy (PL) were used to test and analyze the structure, composition, morphology and fluorescence performance of the powders. XRD and IR showed that all the samples has crystal structure independently on the substituent element; SEM photographs showed that the morphology of the Ga₂O₃:xCr sample was cylindrical polyhedron, and the morphology of the YGG:xCr powder was in the shape of short rod, both of two phosphor powders had agglomeration. The emission peak of two powders observed at 742 and 740 nm is due to ²E-⁴A₂ transition from Cr³⁺ ions. The results showed that the fluorescence emission intensity of YGG:xCr was higher, and the emission peak wavelength region is suitable for photosynthesis in plants.
- Cr³⁺ doping,
- Ga₂O₃,
- Y₃Ga₅O₁₂,
- fluorescence,
- sol-gel high temperature solid phase synthesis
1. [1]
  LIU Wen-Ke, YANG Qi-Chang. Science & Technology Review, 2013, 31(33):11
2. [2]
  Suzuki A, Kurosawa S, Nagata S, et al. Opt. Mater., 2015, 36(9):1484-1487
3. [3]
  Dierkes T, Plewa J, Juestel T. J. Alloy. Compd., 2017, 693(2):291-302
4. [4]
  Kim S J, Hahn E J, Heo J W, et al. Sci. Hortic., 2004, 101(1):143-151
5. [5]
  Shimizu H, Saito Y, Nakashima H, et al. IFAC Proceedings Volumes, 2011, 44:605-609 doi: 10.3182/20110828-6-IT-1002.02683
6. [6]
  Yeh N, Chung J P. Renewable Sustainable Energy Rev., 2009, 13(8):2175-2180 doi: 10.1016/j.rser.2009.01.027
7. [7]
  Morrow R C. Hortscience, 2008, 43(7):1947-1950 doi: 10.21273/HORTSCI.43.7.1947
8. [8]
  Tamulaitis G, Duchovskis P, Bliznikas Z, et al. J. Phys. D:Appl. Phys., 2005, 38(17):3182-3187 doi: 10.1088/0022-3727/38/17/S20
9. [9]
  Bula R J, Morrow R C, Tibbitts T W, et al. Hortscience, 1991, 26(2):203-205 doi: 10.21273/HORTSCI.26.2.203
10. [10]
  Brown C S, Schuerger A C, Sager J C. J. Am. Soc. Hortic. Sci., 1995, 120(5):808-813 doi: 10.21273/JASHS.120.5.808
11. [11]
  McDonald M S. Photobiology of Higher Plants. Weinheim:Wiley, 2003:21-28
12. [12]
  CAO Guo-Xi, HU He-Fang, ZHOU Shi-Gui. Acta Optica Sinica, 2002, 22(2):226-232 doi: 10.3321/j.issn:0253-2239.2002.02.023
13. [13]
  ZHANG Jun-Gang, LI Bin, XIA Chang-Tai, et al. Scientia Sinica:Technologica, 2007, 37(1):370-374
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  YanYuan Jia , Rong Rong , Jie Liu , Jing Guo , GuoYu Jiang , Shuo Guo . Unity is Strength, and Independence Shines: A Science Popularization Experiment on AIE and ACQ Effects. University Chemistry, 2024, 39(9): 349-358. doi: 10.12461/PKU.DXHX202402035
3. [3]
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4. [4]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
5. [5]
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6. [6]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
7. [7]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
8. [8]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
11. [11]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
12. [12]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
13. [13]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
14. [14]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
15. [15]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
16. [16]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
17. [17]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
18. [18]
  Haojie Duan , Hejingying Niu , Lina Gan , Xiaodi Duan , Shuo Shi , Li Li . Reinterpret the heterogeneous reaction of α-Fe₂O₃ and NO₂ with 2D-COS: The role of SDS, UV and SO₂. Chinese Chemical Letters, 2024, 35(6): 109038-. doi: 10.1016/j.cclet.2023.109038
19. [19]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
20. [20]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942

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Fluorescence Characteristics of Cr³⁺ in Different Matrices Y₃Ga₅O₁₂ or Ga₂O₃