Citation: ZHU Kai, OUYANG Jie, LIU Jia-Man, ZHU Yu-Xin, ZENG Qian, CUI Yan-Juan. Preparation and Photocatalytic Hydrogen Evolution from Water of Oxygen Doped Carbon Nitride Nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 1005-1012. doi: 10.11862/CJIC.2019.114 shu

Preparation and Photocatalytic Hydrogen Evolution from Water of Oxygen Doped Carbon Nitride Nanosheets

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, Jiangsu 212008, China

Corresponding author: CUI Yan-Juan, yjcui@just.edu.cn
Received Date: 2 January 2019
Revised Date: 22 March 2019

Figures(9)

Oxygen-doped carbon nitride nanosheets catalyst (CNO) was synthesized by two-step thermal polymerization method using oxalic acid as oxygen source, melamine and urea as raw materials. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet-visible absorption spectroscopy (UV-Vis), X-ray photoelectron spectroscopy (XPS), fluorescence spectroscopy (PL), and electrochemical measurements were carried out to characterize and analyze the structures of catalysts. The photocatalytic reduction properties of CNO were tested by H₂ production from water splitting under visible light irradiation. The results showed that O elements directly replaced N in the triazine ring structure and bonded to the sp² hybridized carbon to form CNO. The CNO showed good layered structure, improved absorption of visible light, and lowered band gap. Due to the O doping, the separation and transmission of photogenerated electron-hole pairs were accelerated. Under visible light irradiation, the hydrogen generation rate from water by CNO was greatly enhanced and the evolution rate was up to 88.6 μmol·h^-1, which was 3.91 times as undoped CN.
- carbon nitride,
- oxygen doping,
- photocatalysis,
- hydrogen generation
1. [1]
  Cates E L, Chinnapongse S L, Kim J H, et al. Environ. Sci. Technol., 2012, 46(22):12316-12328 doi: 10.1021/es303612p
2. [2]
  Marin M L, Santos-Juanes L, Arques A, et al. Chem. Rev., 2012, 112(3):1710-1760 doi: 10.1021/cr2000543
3. [3]
  Wang Y, Feng C X, Zhang M, et al. Appl. Catal. B, 2011, 104(3):268-274
4. [4]
  Zhao D, Chen C S, Yu C L, et al. J. Phys. Chem. C, 2009, 113(30):13160-13165 doi: 10.1021/jp9002774
5. [5]
  Zhao L, Lin X Z, Lai H B, et al. J. Mol. Catal., 2014, 28(3):276-281
6. [6]
  HUANG Tao, ZHANG Guo-Liang, ZHANG Hui, et al. Chemical Industry and Engineering Progress, 2010, 29(3):498-504
7. [7]
  ZHANG Jing, ZHANG Ya-Ping, YU Lian-Qing, et al. Inorganic Chemicals Industry, 2010, 42(9):6-9 doi: 10.3969/j.issn.1006-4990.2010.09.003
8. [8]
  NI Guang-Hong, FENG Ping. Nanoscience & Technology, 2010, 7(2):81-86
9. [9]
  ZHANG Ya-Ping, ZHANG An-Yu, YU Lian-Qing, et al. J. Inorg. Mater., 2016, 31(3):269-272
10. [10]
  Cao S, Low J, Yu J, et al. Adv. Mater., 2015, 27(13):2150-2176 doi: 10.1002/adma.201500033
11. [11]
  Liu J H, Xie S Y, Geng Z B, et al. Nano Lett., 2016, 16(10):6568-6573 doi: 10.1021/acs.nanolett.6b03229
12. [12]
  CHEN Yan, LIU Hai-Bo, et al. Chinese J. Inorg. Chem., 2017, 33(12):2255-2261 doi: 10.11862/CJIC.2017.218
13. [13]
  Li X H, Wang X C, Antonietti M, et al. J. Am. Chem. Soc., 2009, 131(5):1680-1681 doi: 10.1021/ja809307s
14. [14]
  Li X H, Wang X C, Antonietti M, et al. Chem. Sci., 2012, 3(6):2170-2174 doi: 10.1039/c2sc20289a
15. [15]
  Yan S C, Li Z S, Zou Z G, et al. Langmuir, 2010, 26(6):3894-3901 doi: 10.1021/la904023j
16. [16]
  Liu G, Niu P, Sun C H, et al. J. Am. Chem. Soc., 2010, 132(33):11642-11648 doi: 10.1021/ja103798k
17. [17]
  Yan D D, Dr X W, Thomas P, et al. ChemCatChem, 2010, 2(7):834-838 doi: 10.1002/cctc.201000057
18. [18]
  Liu Y A, Wang R X, Yang Z K, et al. Chin. J. Catal., 2015, 36(12):2135-2144 doi: 10.1016/S1872-2067(15)60985-8
19. [19]
  Jie F, Chang B B, Tian Y L, et al. J. Mater. Chem. A, 2013, 1(9):3083-3090 doi: 10.1039/c2ta00672c
20. [20]
  Ong W J, Tan L L, Ng Y H, et al. Chem. Rev., 2016, 116(12):7159-7329 doi: 10.1021/acs.chemrev.6b00075
21. [21]
  Li J H, Shen B, Hong Z H, et al. Chem. Commun., 2012, 48(98):12017-12019 doi: 10.1039/c2cc35862j
22. [22]
  Huang Z F, Song J, Pan L, et al. Nano Energy, 2015, 12:646-656 doi: 10.1016/j.nanoen.2015.01.043
23. [23]
  CUI Yan-Juan, WANG Yu-Xiong, WANG Hao, et al. Chin. J. Catal., 2016, 37(11):1899-1906
24. [24]
  Rong X S, Qiu F X, Rong J, et al. J. Solid State Chem., 2015, 230:126-134 doi: 10.1016/j.jssc.2015.07.003
25. [25]
  ZHAI Shun-Chen, GUO Pin, ZHEN Ji-Ming, et al. Acta Physica Sinica, 2017, 66(18):187102 doi: 10.7498/aps.66.187102
26. [26]
  LI Xin, WANG Tie-Cheng, QU Guang-Zhou, et al. Chinese Journal of Environmental Engineering, 2017, 11(5):2738-2742
27. [27]
  Fu Y S, Zhu J W, Hu C, et al. Nanoscale, 2014, 6(21):12555-12564 doi: 10.1039/C4NR03145H
28. [28]
  Oh J, Yoo R J, Kim S Y, et al. Chem. Eur. J., 2015, 21(16):6241-6246 doi: 10.1002/chem.v21.16
29. [29]
  Li J H, Shen B, Hong Z H, et al. Chem. Commun., 2012, 48(98):12017-12019 doi: 10.1039/c2cc35862j
1. [1]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
2. [2]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
3. [3]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
6. [6]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
9. [9]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
10. [10]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
11. [11]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
12. [12]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
13. [13]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
14. [14]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
15. [15]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
18. [18]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
19. [19]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
20. [20]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(2191)
HTML views(585)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142