Citation: CHEN Pei-Lei, HUANG Ji-Chun, CHEN Yi-Xin, JI Chong-Xing, ZHU De-Cheng, LI De-Cheng. Structure and Electrochemical Properties of xLi₂MnO₃-(1-x)Li[Ni_0.8Co_0.15Al_0.05]O₂ (0.5 ≤ x ≤ 0.8)[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(6): 937-946. doi: 10.11862/CJIC.2019.112 shu

Structure and Electrochemical Properties of xLi₂MnO₃-(1-x)Li[Ni_0.8Co_0.15Al_0.05]O₂ (0.5 ≤ x ≤ 0.8)

College of Energy, Soochow University, Suzhou, Jiangsu 215006, China

Corresponding author: LI De-Cheng, lidecheng@suda.edu.cn
Received Date: 28 September 2018
Revised Date: 21 March 2019

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A new type of material based on the rich lithium-layered solid solution material system, xLi₂MnO₃-(1-x)Li[Ni_0.8Co_0.15Al_0.05]O₂ (0.5 ≤ x ≤ 0.8) was obtained by spray dry process with post annealing treatment. The effect of x value on the structural and electrochemical properties of the materials was investigated by XRD, SEM, TEM, XPS, EIS and charge-discharge tested. Our results suggested that the crystal structure of the sample gradually changed from layered Li[Ni_0.8Co_0.15Al_0.05]O₂ type to Li₂MnO₃ type with the increase of x. Moreover, the quenching treatment in liquid nitrogen was helpful to improve the electrochemical properties of xLi₂MnO₃-(1-x)Li[Ni_0.8Co_0.15Al_0.05]O₂ (0.5 ≤ x ≤ 0.8), which was attributed to the change in terms of the micro structure and valence of the transit metals caused by quenching. The sample with x=0.6 after quenching treatment showed good electrochemical properties, with above 209 mAh·g^-1 of reversible capacity after 100 cycles.
- lithium-ion batteries,
- lithium-rich layered solid solution material,
- liquid-nitrogen quench
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通讯作者: 陈斌, bchen63@163.com

Structure and Electrochemical Properties of xLi₂MnO₃-(1-x)Li[Ni_0.8Co_0.15Al_0.05]O₂ (0.5 ≤ x ≤ 0.8)