Citation: ZHAO Na, LI Yu, FENG An-Sheng, ZOU Xun-Zhong. Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(Ⅱ) and Nickel(Ⅱ) Coordination Polymers Constructed from Biphenyl-Type Tricarboxylic Acids[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(7): 1248-1254. doi: 10.11862/CJIC.2019.094 shu

Syntheses, Crystal Structures, and Magnetic Properties of Two Cobalt(Ⅱ) and Nickel(Ⅱ) Coordination Polymers Constructed from Biphenyl-Type Tricarboxylic Acids

Guangdong Research Center for Special Building Materials and Its Green Preparation Technology/Foshan Research Center for Special Functional Building Materials and Its Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China

Corresponding author: LI Yu, liyuletter@163.com ZOU Xun-Zhong, 2017018009@gdip.edu.cn
Received Date: 10 January 2019
Revised Date: 1 March 2019

Figures(9)

Two 1D cobalt(Ⅱ) and 2D nickel(Ⅱ) coordination polymers, namely[Co(μ₂-H₂btc)₂(4, 4'-bipy)₂]_n (1) and {[Ni₃(μ₄-dppa)₂(H₂O)₆]·2H₂O}_n (2), have been constructed hydrothermally using H₃btc (H₃btc=biphenyl-2, 4, 4'-tricarboxylic acid), H₃dppa (H₃dppa=5-(3, 4-dicarboxylphenyl)picolinic acid), 4, 4'-bipy(4, 4'-bipy=4, 4'-bipyridine), and cobalt or nickel chlorides. Single-crystal X-ray diffraction analyses reveal that both compounds crystallize in the triclinic system, space group \begin{document}$ P\bar 1$\end{document}. Compound 1 has a 1D double-helix chain structure, which is assembled to a 3D supramolecular framework through O-H…O/N hydrogen bond. Compound 2 shows a 2D sheet based on 1D chain units. Moreover, 4, 4'-bipy can tune the structures of both coordination polymers by its coordination or template effect. Magnetic studies for compound 1 demonstrate a ferromagnetic coupling between the adjacent Co(Ⅱ) centers.
- coordination polymer,
- double-helix chain,
- template effect,
- tricarboxylic acid,
- magnetic properties
1. [1]
  Zheng X D, Lu T B. CrystEngComm, 2010, 12:324-336 doi: 10.1039/B911991D
2. [2]
  Yan W, Han L J, Jia, H L, et al. Inorg. Chem., 2016, 55:8816-8821 doi: 10.1021/acs.inorgchem.6b01328
3. [3]
  Li Q P, Du S W. RSC Adv., 2015, 5:9898-9903 doi: 10.1039/C4RA14939D
4. [4]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 12:1126-1162
5. [5]
  Ou Y C, Gao X, Zhou Y, et al. Cryst. Growth Des., 2016, 16:946-952 doi: 10.1021/acs.cgd.5b01500
6. [6]
  Zeng M H, Yin Z, Tan Y X, et al. J. Am. Chem. Soc., 2014, 136:4680-4688 doi: 10.1021/ja500191r
7. [7]
  Gu J Z, Wen M, Cai Y, et al. Inorg. Chem., 2019, 58:2403-2412 doi: 10.1021/acs.inorgchem.8b02926
8. [8]
  Zou J Y, Li L, You S Y, et al. Cryst. Growth Des., 2018, 18:3997-4003 doi: 10.1021/acs.cgd.8b00344
9. [9]
  Zhang L N, Zhang C, Zhang B, et al. CrystEngComm, 2015, 17:2837-2846 doi: 10.1039/C5CE00263J
10. [10]
  Du M, Li C P, Liu C S, et al. Coord. Chem. Rev., 2013, 257:1282-1305 doi: 10.1016/j.ccr.2012.10.002
11. [11]
  Chen X M, Tong M L. Acc. Chem. Res., 2007, 40:162-170 doi: 10.1021/ar068084p
12. [12]
  Singh R, Bharatdwaj P K. Cryst. Growth Des., 2013, 13:3722-3733 doi: 10.1021/cg400756z
13. [13]
  Gu J Z, Gao Z Q, Tang Y. Cryst. Growth Des., 2012, 12:3312-3323 doi: 10.1021/cg300442b
14. [14]
  Gu J Z, Cui Y H, Liang X X, et al. Cryst. Growth Des., 2016, 16:4658-4670 doi: 10.1021/acs.cgd.6b00735
15. [15]
  GU Wen-Jun, GU Jin-Zhong. Chinese J. Inorg. Chem., 2017, 33(2):227-236
16. [16]
  Gu J Z, Cai Y, Qian Z Y, et al. Dalton Trans., 2018, 47:7431-7444 doi: 10.1039/C8DT01299G
17. [17]
  Gu J Z, Cai Y, Wen M, et al. Dalton Trans., 2018, 47:14327-14339 doi: 10.1039/C8DT02467G
18. [18]
  Wu Y P, Wu X Q, Wang J F, et al. Cryst. Growth Des., 2016, 16:2309-2316 doi: 10.1021/acs.cgd.6b00093
19. [19]
  Liu B, Zhou H F, Guan Z H, et al. Green Chem., 2016, 18:5418-5422 doi: 10.1039/C6GC01686C
20. [20]
  ZHAO Su-Qin, GU Jin-Zhong. Chinese J. Inorg. Chem., 2016, 32(9):1611-1618
21. [21]
  Stock N, Biswas S. Chem. Rev., 2012, 112:933-969 doi: 10.1021/cr200304e
22. [22]
  Su J, Yao L D, Zhao M, et al. Inorg. Chem., 2015, 54:6169-6175 doi: 10.1021/acs.inorgchem.5b00180
23. [23]
  Chandrasekhar V, Mohapatra C, Butcher R J. Cryst. Growth Des., 2012, 12:3285-3295 doi: 10.1021/cg3004189
24. [24]
  Burd S D, Ma S, Perman J A, et al. J. Am. Chem. Soc., 2012, 134:3663-3666 doi: 10.1021/ja211340t
25. [25]
  Spek A L. Acta Crystallogr. Sect. C:Struct. Chem., 2015, C71:9-18
1. [1]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
2. [2]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
3. [3]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
4. [4]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
5. [5]
  Zhenzhong MEI , Hongyu WANG , Xiuqi KANG , Yongliang SHAO , Jinzhong GU . Syntheses and catalytic performances of three coordination polymers with tetracarboxylate ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1795-1802. doi: 10.11862/CJIC.20240081
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
8. [8]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
9. [9]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
10. [10]
  Tiankai Sun , Hui Min , Zongsu Han , Liang Wang , Peng Cheng , Wei Shi . Rapid detection of nanoplastic particles by a luminescent Tb-based coordination polymer. Chinese Chemical Letters, 2024, 35(5): 108718-. doi: 10.1016/j.cclet.2023.108718
11. [11]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
12. [12]
  Jun Guo , Zhenbang Zhuang , Wanqiang Liu , Gang Huang . "Co-coordination force" assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries. Chinese Chemical Letters, 2024, 35(9): 109803-. doi: 10.1016/j.cclet.2024.109803
13. [13]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
14. [14]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
15. [15]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
16. [16]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
17. [17]
  Peng Zhou , Ziang Jiang , Yang Li , Peng Xiao , Feixiang Wu . Sulphur-template method for facile manufacturing porous silicon electrodes with enhanced electrochemical performance. Chinese Chemical Letters, 2024, 35(8): 109467-. doi: 10.1016/j.cclet.2023.109467
18. [18]
  Hongdao LI , Shengjian ZHANG , Hongmei DONG . Magnetic relaxation and luminescent behavior in nitronyl nitroxide-based annuluses of rare-earth ions. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 972-978. doi: 10.11862/CJIC.20230411
19. [19]
  Rui Wang , He Qi , Haijiao Zheng , Qiong Jia . Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment. Chinese Chemical Letters, 2024, 35(7): 109215-. doi: 10.1016/j.cclet.2023.109215
20. [20]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(320)
HTML views(63)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142