Citation: GAO Xiao-Ming, SHANG Yan-Yan, LIU Li-Bo, GAO Kai-Long. Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi₂O₃ Nanosheets[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 580-588. doi: 10.11862/CJIC.2019.092 shu

Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi₂O₃ Nanosheets

Shaanxi Key Laboratory of Chemical Reaction Engineering, Department of Chemistry and Chemical Engineering, Yan′an University, Yan′an, Shaanxi 716000, China

Corresponding author: GAO Xiao-Ming, dawn1026@163.com
Received Date: 2 January 2019
Revised Date: 22 February 2019

Figures(11)

Cd-doped δ-Bi₂O₃ (Cd-δ-Bi₂O₃) were prepared by the alcoholic-hydrothermal method, and characterized by X-ray diffraction (XRD), transmission electron microscope (TEM) and so on. The results showed that Cd-δ-Bi₂O₃ was assembled by 2D nanosheets. Cd in the form of Cd²⁺ was introduced in the lattice gap of δ-Bi₂O₃ and belonged to interstitial doping. Due to Cd doping, the band gap was decreased, the light-harvesting capability was enhanced, and the transmission and separation efficiency of carriers was improved. At room temperature and atmospheric pressure, the photocatalytic nitrogen fixation was investigated under visible light irradiation. The results showed that the photocatalytic nitrogen fixation rate of 6%Cd-δ-Bi₂O₃ with 3 h of light irradiation was 1.6 mmol·g^-1·h^-1·L^-1, which was 10.67 times higher than that of δ-Bi₂O₃. The mechanism of photocatalytic N₂ fixation was discussed by means of photocurrent and impedance. Doping Cd defect serves as the trap of photogenerated electrons, which delays the surface transfer of photogenerated electrons and enhances the chemisorption of target molecules.
- Cd doping δ-Bi₂O₃,
- 2D nanosheets,
- photocatalytic nitrogen fixation,
- doping defect
1. [1]
  Bickley R I, Vishwanathan V. Nature, 1979, 280:306-308 doi: 10.1038/280306a0
2. [2]
  Wang S Y, Hai X, Ding X, et al. Adv. Mater., 2017, 29(31):1701774 doi: 10.1002/adma.201701774
3. [3]
  Li H, Shang J, Ai Z H, et al. J. Am. Chem. Soc., 2015, 137(19):6393-6399
4. [4]
  Di J, Zhu C, Ji M X, et al. Angew. Chem., 2018, 130(45):15063-15067 doi: 10.1002/ange.201809492
5. [5]
  Pan C S, Zhu Y F. Catal. Sci. Technol., 2015, 5(6):3071-3083 doi: 10.1039/C5CY00202H
6. [6]
  Wang H L, Zhang L S, Chen Z G, et al. Chem. Soc. Rev., 2014, 43(15):5234-5244 doi: 10.1039/C4CS00126E
7. [7]
  Yi S S, Zhang X B, Wulan B R, et al. Energy Environ. Sci., 2018, 11(11):3128-3156 doi: 10.1039/C8EE02096E
8. [8]
  Cheng L, Xiang Q J, Liao Y L, et al. Energy Environ. Sci., 2018, 11(6):1362-1391
9. [9]
  XIE Yi-Ting, TAN Juan, WANG Ya-Fei, et al. Chinese J. Inorg. Chem., 2018, 34(12):2153-2160 doi: 10.11862/CJIC.2018.267
10. [10]
  Oshikiri T, Ueno K, Misawa H. Angew. Chem. Int. Ed., 2014, 53(37):9802-9805 doi: 10.1002/anie.201404748
11. [11]
  Zhao W R, Xi H P, Zhang M, et al. Chem. Commun., 2015, 51(23):4785-4788 doi: 10.1039/C5CC00589B
12. [12]
  Bai Y, Ye L Q, Chen T, et al. ACS Appl. Mater. Interfaces, 2016, 8(41):27661-27668
13. [13]
  XIAO Yao, HU Wen-Juan, REN Yan-Biao, et al. Prog. Chem., 2018, 30(4):325-337
14. [14]
  Liu J, Kelley M S, Wu W Q, et al. Proc. Natl. Acad. Sci. U.S.A., 2016, 113(20):5530-5535 doi: 10.1073/pnas.1605512113
15. [15]
  He R G, Xu D F, Cheng B, et al. Nanoscale Horiz., 2018, 3(5):464-504
16. [16]
  Cao S W, Shen B J, Tong T, et al. Adv. Funct. Mater., 2018, 28(21):1800136 doi: 10.1002/adfm.v28.21
17. [17]
  Huang Y K, Kang S F, Yang Y, et al. Appl. Catal. B, 2016, 196:89-99 doi: 10.1016/j.apcatb.2016.05.022
18. [18]
  Lamers M, Fiechter S, Friedrich D, et al. J. Mater. Chem. A, 2018, 6(38):18694-18700
19. [19]
  Liu Y, Yang Z H, Song P P, et al. Appl. Surf. Sci., 2018, 430:561-570
20. [20]
  Pan C S, Zhu Y F. J. Mater. Chem., 2011, 21(12):4235-4241 doi: 10.1039/c0jm03655b
21. [21]
  Cheng H F, Huang B B, Dai Y. Nanoscale, 2014, 6(4):2009-2026 doi: 10.1039/c3nr05529a
22. [22]
  Zhu S J, Lu L L, Zhao Z W, et al. J. Phy. Chem. C, 2017, 121(17):9394-9401
23. [23]
  Wang W Y, Wang X W, Cao Z Q, et al. J. Phy. Chem. C, 2018, 122(41):23582-23590 doi: 10.1021/acs.jpcc.8b07444
24. [24]
  Zhang N, Gao C, Xiong Y J. J. Energy Chem., 2019, 37:43-57 doi: 10.1016/j.jechem.2018.09.010
25. [25]
  Tan C L, Cao X H, Wu X J, et al. Chem. Rev., 2017, 117(9):6225-6331
26. [26]
  Wu Y P, Zhu J H, Huang L. Carbon, 2019, 143:610-640 doi: 10.1016/j.carbon.2018.11.053
27. [27]
  Chen Y, Fan Z X, Zhang Z C, et al. Chem. Rev., 2018, 118(13):6409-6455 doi: 10.1021/acs.chemrev.7b00727
28. [28]
  Eswar N K, Adhikari S, Ramamurthy P C, et al. Phys. Chem. Chem. Phys., 2018, 20(5):3710-3723 doi: 10.1039/C7CP04888B
29. [29]
  Li H, Li J, Ai Z H, et al. Angew. Chem. Int. Ed., 2018, 57(1):122-138
30. [30]
  Zhu Q Y, Wang Z Y, Chen L F, et al. ACS Appl. Nano Mater., 2018, 1(9):5083-5091 doi: 10.1021/acsanm.8b01186
31. [31]
  Wei Z, Liu Y F, Wang J, et al. Nanoscale, 2015, 7(33):13943-13950 doi: 10.1039/C5NR02345A
32. [32]
  Li M J, Yokoyama S, Takahashi H, et al. Appl. Catal. B, 2019, 241:284-291 doi: 10.1016/j.apcatb.2018.09.050
33. [33]
  Yin W J, Bai L J, Zhu Y Z, et al. ACS Appl. Mater. Interfaces, 2016, 8(35):23133-23142 doi: 10.1021/acsami.6b07754
34. [34]
  Zhao W R, Zhang J, Zhu X, et al. Appl. Catal. B, 2014, 144:468-477 doi: 10.1016/j.apcatb.2013.07.047
1. [1]
  Runhua Chen , Qiong Wu , Jingchen Luo , Xiaolong Zu , Shan Zhu , Yongfu Sun . Defective Ultrathin Two-Dimensional Materials for Photo-/Electrocatalytic CO₂ Reduction: Fundamentals and Perspectives. Acta Physico-Chimica Sinica, 2025, 41(3): 100019-0. doi: 10.3866/PKU.WHXB202308052
2. [2]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
3. [3]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
4. [4]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . Simultaneously Improving Inter-Plane Crystallization and Incorporating K Atoms in g-C₃N₄ Photocatalyst for Highly-Efficient H₂O₂ Photosynthesis. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-0. doi: 10.3866/PKU.WHXB202406005
5. [5]
  Fan JIA , Wenbao XU , Fangbin LIU , Haihua ZHANG , Hongbing FU . Synthesis and electroluminescence properties of Mn²⁺ doped quasi-two-dimensional perovskites (PEA)₂Pb_yMn_1-yBr₄. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1114-1122. doi: 10.11862/CJIC.20230473
6. [6]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . Improving Photocatalytic H₂O₂ Production over iCOF/Bi₂O₃ S-Scheme Heterojunction in Pure Water via Dual Channel Pathways. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-0. doi: 10.3866/PKU.WHXB202407012
7. [7]
  Gaopeng Liu , Lina Li , Bin Wang , Ningjie Shan , Jintao Dong , Mengxia Ji , Wenshuai Zhu , Paul K. Chu , Jiexiang Xia , Huaming Li . Construction of Bi Nanoparticles Loaded BiOCl Nanosheets Ohmic Junction for Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(7): 2306041-0. doi: 10.3866/PKU.WHXB202306041
8. [8]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
9. [9]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-0. doi: 10.3866/PKU.WHXB202312024
10. [10]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
11. [11]
  Xianghai Song , Xiaoying Liu , Zhixiang Ren , Xiang Liu , Mei Wang , Yuanfeng Wu , Weiqiang Zhou , Zhi Zhu , Pengwei Huo . Insights into the greatly improved catalytic performance of N-doped BiOBr for CO₂ photoreduction. Acta Physico-Chimica Sinica, 2025, 41(6): 100055-0. doi: 10.1016/j.actphy.2025.100055
12. [12]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-0. doi: 10.3866/PKU.WHXB202402016
13. [13]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . Molten Intermediate Transportation-Oriented Synthesis of Amino-Rich g-C₃N₄ Nanosheets for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-0. doi: 10.3866/PKU.WHXB202406021
14. [14]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
15. [15]
  Huanhuan XIE , Yingnan SONG , Lei LI . Two-dimensional single-layer BiOI nanosheets: Lattice thermal conductivity and phonon transport mechanism. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 702-708. doi: 10.11862/CJIC.20240281
16. [16]
  Xiaorui Chen , Xuan Luo , Tongming Su , Xinling Xie , Liuyun Chen , Yuejing Bin , Zuzeng Qin , Hongbing Ji . Ga-doped Cu/γ-Al₂O₃ bifunctional interface sites promote the direct hydrogenation of CO₂ to DME. Acta Physico-Chimica Sinica, 2025, 41(10): 100126-0. doi: 10.1016/j.actphy.2025.100126
17. [17]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
18. [18]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-0. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Jinhui Jiang , Jiaqi Sun , Yongyi Chen , Lei Zhang , Pengyu Dong . W₁₈O₄₉/Al-doped SrTiO₃ S-scheme heterojunction aided by the LSPR effect for full-spectrum solar light-driven photocatalytic hydrogen evolution. Acta Physico-Chimica Sinica, 2025, 41(11): 100145-0. doi: 10.1016/j.actphy.2025.100145

Get Citation

PDF

XML

Metrics

PDF Downloads(12)
Abstract views(1277)
HTML views(316)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi2O3 Nanosheets

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Photocatalytic Nitrogen Fixation Performance of Cd Doping δ-Bi₂O₃ Nanosheets