Citation: CHEN Sheng-Tian, ZHANG Yu, ZHAO Jian-Ying, MA Kui-Rong, LI Rong-Qing, TANG Guo-Dong. High Sensitivity and Selectivity of Aminoantipyrine Schiff Base for the Recognition of Fe²⁺[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 737-744. doi: 10.11862/CJIC.2019.091 shu

High Sensitivity and Selectivity of Aminoantipyrine Schiff Base for the Recognition of Fe²⁺

1.
School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China
2.
Huaian Key Laboratory for Photoelectric Conversion and Energy Storage Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai′an, Jiangsu 223300, China

Corresponding author: ZHANG Yu, yuzhang@hytc.edu.cn ZHAO Jian-Ying, zhaojy008@hytc.edu.cn
Received Date: 23 November 2018
Revised Date: 23 January 2019

Figures(9)

An aminoantipyrine based chemosensor, (E)-1, 5-dimethyl-4-((2-(4-methylpyridin-2-yl)pyridin-4-yl)methyleneamino)-2-phenyl-1, 2-dihydropyrazol-3-one(L), derived from 4-aminoantipyrine and 2-(4-methylpyridin-2-yl) isonicotinaldehyde, was synthesized and the optical and metal sensing properties were investigated. The chemosensor L showed a selective colorimetric sensing ability for Fe²⁺ by changing colors from pale yellow to deep red in water-ethanol (9:1, V/V) medium, which facilitates the 'naked-eye' recognition of Fe²⁺ from other examined metal ions. The complex stoichiometry of Fe²⁺ to L(1:3, [FeL₃]²⁺) was obtained by Job's method. The association constant was determined to be 3.70×10²¹ L³·mol^-3. The present results indicate that the chemosensor L could be used as a selective, sensitive colorimetric sensor for Fe²⁺.
- Schiff base receptor,
- chemosensor for Fe²⁺,
- spectral characterization
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Sensitivity and Selectivity of Aminoantipyrine Schiff Base for the Recognition of Fe2+

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通讯作者: 陈斌, bchen63@163.com

High Sensitivity and Selectivity of Aminoantipyrine Schiff Base for the Recognition of Fe²⁺