Citation: XUE Wen-Zhao, ZHAO Xiao-Lei, YAN Xue-Xue, ZHANG Xue-Jie, WU Wei-Na, WANG Yuan, CHEN Zhong. Ga(Ⅲ) and In(Ⅲ) Complexes with 3-Ethyl- 2-acetylpyrazine N(4)-(p-Tolyl) thiosemicarbazone:Synthesis, Crystal Structure and DNA-Binding Activity[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 745-751. doi: 10.11862/CJIC.2019.085 shu

Ga(Ⅲ) and In(Ⅲ) Complexes with 3-Ethyl- 2-acetylpyrazine N(4)-(p-Tolyl) thiosemicarbazone:Synthesis, Crystal Structure and DNA-Binding Activity

1.
College of Chemistry and Chemical Engineering, Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan 454000, China
2.
School of Materials and Mechanical and Electrical Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China

Corresponding author: ZHAO Xiao-Lei, zhaoxiaolei@hpu.edu.cn; chenzhonglzu@hotmail.com CHEN Zhong,
Received Date: 4 December 2018
Revised Date: 17 January 2019

Figures(4)

Two novel complexes, [Ga(L)₂]NO₃·4CH₃OH (1) and[In(L)₂]NO₃·1.75CH₃OH (2) based on HL (HL=3-ethyl-2-acetylpyrazine N(4)-(p-tolyl)thiosemicarbazone) were synthesized and characterized by X-ray diffraction analyses. Complexes 1 and 2 are isostructural and crystallize in the monoclinic system, space group P2₁/c with different crystal methanol molecules. The metal center in each complex is surrounded by two monoanionic L^- with[N₂S] donor set, thus giving a distorted octahedral coordination geometry. In addition, the fluorescence spectra indicate that the interactions of complexes with DNA are stronger than that of ligand HL.
- thiosemicarbazone,
- Ga(III),
- In(III),
- crystal structure,
- DNA-binding activity
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1.
沈阳化工大学材料科学与工程学院沈阳 110142