Citation: YU Ya-Ze, SUN Li-Ping, ZHAO Hui, HUO Li-Hua. Preparation and Electrochemical Properties of LaBiMn₂O₆-Sm_0.2Ce_0.8O_1.9 Composite Cathode for IT-SOFCs[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 589-597. doi: 10.11862/CJIC.2019.081 shu

Preparation and Electrochemical Properties of LaBiMn₂O₆-Sm_0.2Ce_0.8O_1.9 Composite Cathode for IT-SOFCs

Key laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Corresponding author: ZHAO Hui, zhaohui98@yahoo.com
Received Date: 26 November 2018
Revised Date: 21 February 2019

Figures(9)

The composite cathode LaBiMn₂O₆-Sm_0.2Ce_0.8O_1.9 (LBM-SDC) was prepared by glycine-nitrate combustion method. The phase and morphology evolution of the composite cathode were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. The results showed that LBM had good chemical stability with SDC at 1 000℃. Due to the introduction of SDC, the length of the thriple-phase boundary was extended and the thermal matching between the cathode and the electrolyte was enhanced, resulting in an improvement in the electrochemical performance of the composite cathode. The electrochemical impedance spectrum (EIS) results indicated that the cathode polarization resistance (R_p) decreased steadily with the addition of SDC. The optimum addition of 30%(w/w) SDC in the composite cathode leads to the lowest Rp of 0.186 Ω·cm² at 700℃ in air, which is 74% less than the pristine LBM cathode (R_P=0.717 Ω·cm²). This is because an additional oxygen ion conduction path is generated after the introduction of SDC; thereby the oxygen reduction reaction is promoted. The maximum power density of the electrolyte-support single cell Ni-SDC/SDC/LBM-30%SDC reached 234 mW·cm^-2 at 700℃. The power density maintains a stable value at 230 mW·cm^-2 throughout a test period of 90 h, indicating that LBM-30%SDC had sufficient stability during the operation. The oxygen partial pressure measurement indicated that the oxygen molecule adsorption-diffusion process is the reaction rate-limiting step of the composite cathode.
1. [1]
  Adler S B. Chem. Rev., 2004, 104:4791-4843 doi: 10.1021/cr020724o
2. [2]
  Zhou W, Liang F L, Shao Z P, et al. Sci. Rep., 2012, 2:327-333 doi: 10.1038/srep00327
3. [3]
  Choi J J, Cho K S, Choi J H, et al. Int. J. Hydrogen Energy, 2012, 37:6830-6835 doi: 10.1016/j.ijhydene.2012.01.055
4. [4]
  Brett D J L, Atkinson A, Brandon N P, et al. Chem. Soc. Rev., 2008, 37(8):1568-1578 doi: 10.1039/b612060c
5. [5]
  Choi S, Park S, Kim J, et al. Electrochem. Commun., 2013, 34:5-8 doi: 10.1016/j.elecom.2013.04.016
6. [6]
  Sung J G, Kim T, Han K J, et al. AlChE J., 2018, 64(3):940-949 doi: 10.1002/aic.v64.3
7. [7]
  Yunphuttha C, Porntheeraphat S, Wongchaisuwat A, et al. Phys. Chem. Chem. Phys., 2016, 18(25):16786-16793 doi: 10.1039/C6CP02338J
8. [8]
  Lee Y L, Kleis J, Rossmeisl J, et al. Phys. Rev. B, 2009, 80(22):224101 doi: 10.1103/PhysRevB.80.224101
9. [9]
  Kundu A K, Pralong V, Caignaert V, et al. J. Mater. Chem., 2007, 17(31):3347-3353 doi: 10.1039/b705027e
10. [10]
  Ranjith R, Kundu A K, Filippi M, et al. Appl. Phys. Lett., 2008, 92(6):062909 doi: 10.1063/1.2842409
11. [11]
  Reddy M P, Shakoor R A, Mohamed A M A. Mater. Chem. Phys., 2016, 177:346-352 doi: 10.1016/j.matchemphys.2016.04.038
12. [12]
  Javier H M, Javier R F, Thomas B, et al. Phys. Rev. B, 2018, 97:235129 doi: 10.1103/PhysRevB.97.235129
13. [13]
  Crisanto A G R, Sebastian L, María R, et al. Solid State Sci., 2018, 80:72-80 doi: 10.1016/j.solidstatesciences.2018.03.022
14. [14]
  Jaimes D M A, Blanco M C, Pomiro F, et al. J. Alloys Compd., 2017, 704:776-787 doi: 10.1016/j.jallcom.2016.12.308
15. [15]
  Ahmed T, Chen A, Yarotski D A, et al. APL Mater., 2017, 5(3):035601 doi: 10.1063/1.4964676
16. [16]
  Troncoso L, Martínez-Lope M J, Alonso J A, et al. J. Appl. Phys., 2013, 113(2):0231511
17. [17]
  Dager P K, Mogni L V, Soria S, et al. Ceram. Int., 2018, 44:2539-2546 doi: 10.1016/j.ceramint.2017.11.006
18. [18]
  Zhang Q, Wei T, Huang Y H. J. Power Sources, 2012, 198:59-65 doi: 10.1016/j.jpowsour.2011.09.092
19. [19]
  Li H, Sun L P, Feng Q M, et al. J. Solid State Electrochem., 2017, 21(1):273-280 doi: 10.1007/s10008-016-3364-7
20. [20]
  Sun L P, Li H, Li Q, et al. J. Power Sources, 2018, 392:8-14 doi: 10.1016/j.jpowsour.2018.04.083
21. [21]
  XIAO Hui, SUN Li-Ping, ZHAO Hui, et al. Chinese J. Inorg. Chem., 2015, 31(6):1139-1144
22. [22]
  Yao C, Meng J, Liu X J, et al. Electrochim. Acta, 2017, 229:429-437 doi: 10.1016/j.electacta.2017.01.153
23. [23]
  Martínez-Coronado R, Aguadero A, Alonso J A, et al. Solid State Sci., 2013, 18:64-70 doi: 10.1016/j.solidstatesciences.2013.01.001
24. [24]
  Li M, Wang Y, Wang Y L, et al. ACS Appl. Mater. Interfaces, 2014, 6(14):11286-11294 doi: 10.1021/am5017045
25. [25]
  Zou J, Park J, Yoon H, et al. Int. J. Hydrogen Energy, 2012, 37:8592-8602 doi: 10.1016/j.ijhydene.2012.02.132
26. [26]
  Qi H D, Fu X M, Liu M H, et al. J. Nanosci. Nanotechnol., 2018, 18(12):8403-8408 doi: 10.1166/jnn.2018.16379
27. [27]
  Chen Y, Zhang L L, Wang C, et al. Ionics, 2018, 24(9):2717-2728 doi: 10.1007/s11581-017-2424-z
28. [28]
  Meng Y J, Wang X Y, Xia C, et al. Int. J. Hydrogen Energy, 2018, 43:12697-12704 doi: 10.1016/j.ijhydene.2018.01.209
29. [29]
  Marshenyal S N, Politov B V, Osinkin D A, et al. J. Solid State Electrochem., 2018, 22(6):1863-1869 doi: 10.1007/s10008-018-3894-2
30. [30]
  Muhammed A S A, Anwar M, Raduwan N F, et al. J. Sol-Gel Sci. Technol., 2018, 86(2):493-504 doi: 10.1007/s10971-018-4636-8
31. [31]
  Ding X F, Liu H, Gao Z, et al. Int. J. Hydrogen Energy, 2017, 42:24968-24977 doi: 10.1016/j.ijhydene.2017.08.089
32. [32]
  Jin F J, Liu J C, Shen Y, et al. J. Alloys Compd., 2016, 685:483-491 doi: 10.1016/j.jallcom.2016.05.322
33. [33]
  Li F S, Xia S B, Xu Y X, et al. J. Alloys Compd., 2018, 753:292-299 doi: 10.1016/j.jallcom.2018.04.215
34. [34]
  LI Jian, CHENG Ji-Gui, YANG Cui, et al. Journal of Synthetic Crystals, 2009, 38(5):1093-1097 doi: 10.3969/j.issn.1000-985X.2009.05.010
35. [35]
  Simner S P, Anderson M D, Coleman J E, et al. J. Power Sources, 2006, 161:115-122 doi: 10.1016/j.jpowsour.2006.04.103
36. [36]
  Chen D F, Zhang Q, Lu L, et al. J. Power Sources, 2016, 303:305-316 doi: 10.1016/j.jpowsour.2015.10.090
37. [37]
  Chen D F, Lin Z J, Zhu H Y, et al. J. Power Sources, 2009, 191:240-252 doi: 10.1016/j.jpowsour.2009.02.051
38. [38]
  Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001, 143:379-389 doi: 10.1016/S0167-2738(01)00877-3
39. [39]
  Völker B, McMeeking R M, et al. J. Power Sources, 2012, 215:199-215 doi: 10.1016/j.jpowsour.2012.05.014
40. [40]
  Pang S, Jiang X, Li X, et al. J. Power Sources, 2012, 204:53-59 doi: 10.1016/j.jpowsour.2012.01.034
41. [41]
  Chen D J, Ran R, Zhang K, et al. J. Power Sources, 2009, 188:96-105 doi: 10.1016/j.jpowsour.2008.11.045
42. [42]
  Pea-Martínez J, Marrero-López D, Ruiz-Morales J C, et al. Int. J. Hydrogen Energy, 2009, 34:9486-9495 doi: 10.1016/j.ijhydene.2009.09.041
43. [43]
  Zhao H, Huo L H, Gao S. J. Power Sources, 2004, 125:149-154 doi: 10.1016/j.jpowsour.2003.07.009
44. [44]
  Kim J D, Kim G D, Moon J W, et al. Solid State Ionics, 2001, 143(3):379-389
45. [45]
  Souza R A D, Kilner J A. Solid State Ionics, 1999, 126(1):153-161
46. [46]
  Souza R A D, Kilner J A. Solid State Ionics, 1998, 106(3):175-187
1. [1]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
4. [4]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
5. [5]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
6. [6]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
7. [7]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
8. [8]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
9. [9]
  Heng Zhang . Determination of All Rate Constants in the Enzyme Catalyzed Reactions Based on Michaelis-Menten Mechanism. University Chemistry, 2024, 39(4): 395-400. doi: 10.3866/PKU.DXHX202310047
10. [10]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
11. [11]
  Cunling Ye , Xitong Zhao , Hongfang Wang , Zhike Wang . A Formula for the Calculation of Complex Concentrations Arising from Side Reactions and Its Applications. University Chemistry, 2024, 39(4): 382-386. doi: 10.3866/PKU.DXHX202310043
12. [12]
  Houjin Li , Wenjian Lan . Name Reactions in University Organic Chemistry Laboratory. University Chemistry, 2024, 39(4): 268-279. doi: 10.3866/PKU.DXHX202310016
13. [13]
  Wentao Lin , Wenfeng Wang , Yaofeng Yuan , Chunfa Xu . Concerted Nucleophilic Aromatic Substitution Reactions. University Chemistry, 2024, 39(6): 226-230. doi: 10.3866/PKU.DXHX202310095
14. [14]
  Danqing Wu , Jiajun Liu , Tianyu Li , Dazhen Xu , Zhiwei Miao . Research Progress on the Simultaneous Construction of C—O and C—X Bonds via 1,2-Difunctionalization of Olefins through Radical Pathways. University Chemistry, 2024, 39(11): 146-157. doi: 10.12461/PKU.DXHX202403087
15. [15]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
16. [16]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
17. [17]
  Yuting Zhang , Zhiqian Wang . Methods and Case Studies for In-Depth Learning of the Aldol Reaction Based on Its Reversible Nature. University Chemistry, 2024, 39(7): 377-380. doi: 10.3866/PKU.DXHX202311037
18. [18]
  Ruitong Zhang , Zhiqiang Zeng , Xiaoguang Zhang . Improvement of Ethyl Acetate Saponification Reaction and Iodine Clock Reaction Experiments. University Chemistry, 2024, 39(8): 197-203. doi: 10.3866/PKU.DXHX202312004
19. [19]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
20. [20]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(760)
HTML views(179)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Electrochemical Properties of LaBiMn2O6-Sm0.2Ce0.8O1.9 Composite Cathode for IT-SOFCs

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Electrochemical Properties of LaBiMn₂O₆-Sm_0.2Ce_0.8O_1.9 Composite Cathode for IT-SOFCs