Citation: LUO Wu-Kui, CHEN Feng, YAN Gui-Yang, BAI Yun-Shan. Synthesis, Characterization and Adsorption Property for the Methylene Blue of the Sphere-like TiSAPO-34 Molecular Sieve[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 629-634. doi: 10.11862/CJIC.2019.080 shu

Synthesis, Characterization and Adsorption Property for the Methylene Blue of the Sphere-like TiSAPO-34 Molecular Sieve

1.
Fujian Province Key Laboratory of Featured Materials in Biochemical Industry, College of Chemistry and Materials, Ningde Normal University, Ningde, Fujian 352100, China
2.
College of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi′an 710062, China;

Corresponding author: LUO Wu-Kui, luowukui222@163.com
Received Date: 29 October 2018
Revised Date: 20 January 2019

Figures(8)

The TiSAPO-34 molecular sieves have been successfully synthesized via a facile hydrothermal method. Scanning electron microscopy (SEM), powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR), N₂ adsorption-desorption, UV-Vis diffuse reflectance spectra (UV-Vis DRS) and thermogravimetric (TG) have been employed to determine the properties of the samples. The TiSAPO-34 molecular sieves could be served as efficient adsorbents for adsorbing a typical contaminants, methylene blue (MB) from water. Moreover, the doped amount of titanium, the stability and recyclability of the catalysts have been investigated in detail. The results revealed that the resulting samples were the spherical microporous molecular sieve, which with good thermal stability. Interestingly, a certain amount of Ti atoms could embed the matrix of SAPO-34 molecular sieves successfully, and the skeleton structure of SAPO-34 molecular sieves still maintained. Importantly, the samples synthetic after crystallization at 190℃ for 24 h exhibited the optimal adsorption performance for the adsorption of MB, giving an adsorption rate of 80% after 1 hour.
- microporous materials,
- molecular sieve,
- synthesis,
- adsorption
1. [1]
  An A K, Guo J X, Jeong S, et al. Water Res., 2016, 103:362-371 doi: 10.1016/j.watres.2016.07.060
2. [2]
  Adeyemo A A, Adeoye I O, Bello O S. Appl. Water Sci., 2017, 7(2):543-568 doi: 10.1007/s13201-015-0322-y
3. [3]
  Yao L, Zhang L Z, Wang R, et al. J. Hazard. Mater., 2016, 301:462-470 doi: 10.1016/j.jhazmat.2015.09.027
4. [4]
  HAO Zhi-Xian, ZHAO Hai-Tao, WANG Li-Jun, et al. Acta Phys.-Chim. Sin., 2009, 25(5):829-834 doi: 10.3866/PKU.WHXB20090513
5. [5]
  Liu Y X, Liu X M, Zhao L M, et al. J. Catal., 2017, 347:170-184 doi: 10.1016/j.jcat.2017.01.015
6. [6]
  Wang C X, Zhang L H, Liu Y T. Appl. Catal. B, 2013, 136(12):48-55
7. [7]
  Kikhtyanin O V, Toktarev A V, Ayupov A B, et al. Appl. Catal. A, 2010, 378(1):96-106 doi: 10.1016/j.apcata.2010.02.005
8. [8]
  KONG Xiang-Li, QIU Ming-Hui, YANG Lu, et al. J. Inorg. Mater., 2018, 33(9):956-962
9. [9]
  Andonova S, Tamm S. Appl. Catal. B, 2016, 180:775-787 doi: 10.1016/j.apcatb.2015.07.007
10. [10]
  CHEN Zhi, LIU Xing-Ping, LIU Song. Chinese J. Inorg. Chem., 2010, 26(6):989-996
11. [11]
  Natarajan T S, Bajaj H C, Tayade R J. J. Colloid Interface Sci., 2014, 433(1):104-114
12. [12]
  Xu G Y, Lu M, Sun G G. Transition Met. Chem., 2012, 37:235-240 doi: 10.1007/s11243-011-9566-z
13. [13]
  ZHANG Wu, JI Yan-Yan, PENG Han. Chem. J. Chinese Universities, 2018, 39(9):1985-1992
14. [14]
  Deng X J, Wang Y N, Shen L, et al. Ind. Eng. Chem. Res., 2013, 52(3):1190-1196 doi: 10.1021/ie302467t
15. [15]
  Ding J H, Wu P. Appl. Catal. A, 2014, 488:86-95 doi: 10.1016/j.apcata.2014.09.038
16. [16]
  Yadav R, Singh A K, Sakthivel A. Catal. Lett., 2016, 146(4):800-810 doi: 10.1007/s10562-015-1688-z
17. [17]
  Jin F, Wu Y X, Liu S W, et al. Catal. Today, 2015, 264:98-108
18. [18]
  Novara C, Alfayate A, Berlier G, et al. Phys. Chem. Chem. Phys., 2013, 15(26):11099-11105 doi: 10.1039/c3cp51214b
19. [19]
  Kulkarni S J, Rao R R, Subrahmanyam M, et al. Appl. Catal. A, 1996, 139(1):59-74
20. [20]
  HU Song-Qing, XU Ben-Jing, YAN Zi-Feng, et al. Journal of China University of Petroleum:Edition of Natural Science, 2006, 30(3):113-118
21. [21]
  GU Wei, YAN Ming, SUN Lin, et al. Chinese J. Inorg. Chem., 2017, 33(3):493-500
22. [22]
  YU Yang, TONG Ming-Xing, HE Yu-Lan, et al. J. Inorg. Mater., 2017, 32(4):365-371
23. [23]
  Li X Y, Pi Y H, Xia Q B. et al. Appl. Catal. B, 2016, 191:192-201 doi: 10.1016/j.apcatb.2016.03.034
24. [24]
  Perego C, Carati A, Ingallina P, et al. Appl. Catal. A, 2001, 221(1):63-72
25. [25]
  LIU Hong-Xing, XIE Zai-Ku, ZHANG Cheng-Fang, et al. Chin. J. Chem. Phys., 2003, 16(6):521-526 doi: 10.3969/j.issn.1674-0068.2003.06.018
1. [1]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
7. [7]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
8. [8]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
9. [9]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
10. [10]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
11. [11]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
12. [12]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
13. [13]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
16. [16]
  Yonghui ZHOU , Rujun HUANG , Dongchao YAO , Aiwei ZHANG , Yuhang SUN , Zhujun CHEN , Baisong ZHU , Youxuan ZHENG . Synthesis and photoelectric properties of fluorescence materials with electron donor-acceptor structures based on quinoxaline and pyridinopyrazine, carbazole, and diphenylamine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 701-712. doi: 10.11862/CJIC.20230373
17. [17]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
18. [18]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
19. [19]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
20. [20]
  Fei Xie , Chengcheng Yuan , Haiyan Tan , Alireza Z. Moshfegh , Bicheng Zhu , Jiaguo Yu . d带中心调控过渡金属单原子负载COF吸附O₂的理论计算研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2407013-. doi: 10.3866/PKU.WHXB202407013

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(360)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142