Citation: LEI Li-Ling, YANG Qing-Xiang, ZHAO Jun-Hong, ZHANG Yan, JIA Chao-Yang, LU Ran, NIE Li-Min, CHEN Zhi-Jun. Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 658-666. doi: 10.11862/CJIC.2019.078 shu

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite

Zhengzhou Institute of Light Industry, Zhengzhou 450000, China

Corresponding author: CHEN Zhi-Jun, mcchenzj@zzuli.edu.cn
Received Date: 20 November 2018
Revised Date: 21 February 2019

Figures(11)

In order to improve the ability to remove 2-nitro-1, 3-benzenediol (NRC) in water, Fe₃O₄/GO/PPy ternary composites were prepared by hydrothermal method using GO prepared by modified Hummers method. UV-visible absorption spectroscopy (UV-Vis), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), ζ potential analysis to study the structural of magnetic nanocomposites, while the pH value of the solution, the amount of adsorbent, initial concentration, adsorption time and temperature on the adsorption of NRC were studied by adsorption kinetics and adsorption isotherms. The results showed that the prepared Fe₃O₄/GO/PPy composites were layered dispersed structure; GO layer structure was stripped; PPy and Fe₃O₄ particles irregularly interspersed among the GO sheets. Fe₃O₄ particles were the polyhedral crystal structure with polyhedral size in the range of 100~300 nm. The interface between Fe₃O₄ and PPy particles in the graphene sheet layer was in close contact with each other; Fe₃O₄/GO/PPy could easily separated in water because of the superparamagnetism. Fe₃O₄/GO/PPy could be separated with 40 s under external magnetic field and the removal ratio of the NRC was 91.6%. The adsorption property of Fe₃O₄/GO/PPy for NRC obtained the strongest adsorption under the NRC initial concentration (C₀) was 200 mg·L^-1, pH value was 5.00±0.05, tempreture (T) was 318.15 K, adsorbent dosage (m) was 10 mg·L^-1 and time (t) was 6 h, and the adsorption amount reached 163.3 mg·g^-1. The adsorption kinetics of NRC follows the second-order kinetic model, and the adsorption isotherm conforms to the Langmuir model. After using NRC for five times, the removal rate decreased from 91.6% to 77.6%, that illustrated Fe₃O₄/GO/PPy magnetic complex possessed good stability and repeated use ability.
- adsorption,
- organic-inorganic hybrid composites,
- graphene,
- 2-nitro-1, 3-benzenediol
1. [1]
  (a) SONG Lian-Peng(宋连朋), WEI Lian-Yu(魏连雨), ZHAO Le-Jun(赵乐军), et al. Water Supply and Sewerage(给水排水), 2013, 39(3): 39-44
  (b)HUANG Tai-Biao(黄太彪), LI Liu-Zhu(李刘柱), GAO Song(高嵩), et al. Industrial Water and Wastewater(工业用水与废水), 2016, 47(4): 12-15
2. [2]
  (a) Korotcenkov G, Brinzari V, Cho B K. Microchim. Acta, 2016, 183(3): 1033-1054
  (b)Qin Y L, Long M, Tan B H, et al. Nano-Micro. Lett., 2014, 6(2): 125-135
3. [3]
  (a) Leong M L, Lee K M, Lai S O, et al. Desalination, 2011, 270(1): 181-187
  (b)Ben-Youssef C, Vázquez-Rodríguez G A. Bioresour. Technol., 2011, 102(4): 3740-3747
4. [4]
  Steevensz A, Madur S, Feng W, et al. Enzyme Microb. Technol., 2014, 55(2):65-71
5. [5]
  Madani K. J. Environ. Stud. Sci., 2014, 4(4):315-328 doi: 10.1007/s13412-014-0182-z
6. [6]
  Hadjltaief H B, Costa P D, Beaunier P, et al. Appl. Clay Sci., 2014, 91-92(15):46-54
7. [7]
  Shimizu A, Tokumura M, Nakajima K, et al. J. Hazard. Mater., 2012, 201(1):60-67
8. [8]
  Nikazar M, Alizadeh M, Lalavi R, et al. Iran. J. Environ. Health Sci. Eng., 2014, 12(1):12-21 doi: 10.1186/2052-336X-12-12
9. [9]
  Yang C F, Yang S Y, Qian Y, et al. Ind. Eng. Chem. Res., 2013, 52(34):12108-12115 doi: 10.1021/ie4007535
10. [10]
  (a) Ehtash M, Fournier-Salaün M C, Dimitrov K, et al. Chem. Eng. J., 2014, 250(6): 42-47
  (b)Kazemi P, Peydayesh M, Bandegi A, et al. Chem. Eng. Res. Des., 2014, 92(2): 375-383
11. [11]
  Zhou C, Zhu H, Wang Q, et al. RSC Adv., 2017, 7(30):18466-18479 doi: 10.1039/C7RA01147D
12. [12]
  (a) Bizerea S O, Preda E, Botez A, et al. Environ. Sci. Pollut. Res., 2013, 20: 6367-6381
  (b)Guo X L, Wang J, Wang Y, et al. Procedia Environ. Sci., 2012, 12(12): 152-158
  (c)Giraldo L, Moreno-Piraján J C. J. Anal. Appl. Pyrolysis, 2014, 106: 41-47
13. [13]
  Wu Z B, Yuan X Z, Zhang J, et al. ChemCatChem, 2017, 9(2):23-45
14. [14]
  (a) Ekramul Mahmud H N, Huq A K O, Yahya R B. Cheminformatics, 2016, 47(13): 14778-14791
  (b)Setshedi K Z, Bhaumik M, Onyango M S, et al. Chem. Eng. J., 2015, 262(6): 921-931
  (c)Wu M, Han H F, Ni L L, et al. Materials, 2018, 11(1): 164-175
  (d)Simamora P, Saragih C S, Hasibuan D P, et al. Mater. Today, 2018, 5(7): 14970-14974
15. [15]
  (a) Hu H F, Yang L, Lin Z, et al. Int. J. Biol. Macromol., 2018, 114(15): 256-262
  (b)Dai Y M, Zou J Q, Liu D Y, et al. Colloids Surf. A, 2018, 550(5): 90-98
16. [16]
  Wang Y H, Li L L, Luo C N, et al. Int. J. Biol. Macromol., 2016, 86:505-511 doi: 10.1016/j.ijbiomac.2016.01.035
17. [17]
  Karthik R, Meenakshi S. Synth. Met., 2014, 198:181-187 doi: 10.1016/j.synthmet.2014.10.012
18. [18]
  Chandra V, Kim K S. Chem. Commun., 2011, 47(13):3942-3944 doi: 10.1039/c1cc00005e
19. [19]
  Wang Y Z, Wang Y S, Yan X R, et al. Chemosphere, 2016, 153:485-493 doi: 10.1016/j.chemosphere.2016.03.036
20. [20]
  Mthombeni N H, Mbakop S, Ochieng A, et al. J. Taiwan Inst. Chem. Eng., 2016, 66:172-180 doi: 10.1016/j.jtice.2016.06.016
21. [21]
  Gari V R D K, Min K. Monatsh. Chem., 2015, 146(9):1445-1453 doi: 10.1007/s00706-015-1429-4
22. [22]
  Kumar V, Jahan F, Raghuwanshi S, et al. Biotechnol. Bioprocess Eng., 2013, 18:787-795 doi: 10.1007/s12257-012-0793-8
23. [23]
  Setshedi K Z, Bhaumik M, Onyango M S, et al. Chem. Eng. J., 2015, 262:921-931 doi: 10.1016/j.cej.2014.10.034
24. [24]
  (a) Gao F, Gu H B, Wang H W, et al. RSC Adv., 2015, 5(74): 60208-60219
  (b)Zabihi M, Ahmadpour A, Asl A H. J. Hazard. Mater., 2009, 167(1): 230-236
  (c)Wang H, Yuan X Z, Yan W, et al.Chem. Eng. J., 2015, 262(4): 597-606
25. [25]
  (a) Huong P T, Lee B K, Kim J. Process Saf. Environ. Prot., 2016, 104: 314-322
  (b)Lu G R, Liu J M, Xiong Z H, et al. J. Chem. Eng. Data, 2016, 61(11): 3868-3876
  (c)Jia Z, Jiang M, Wu G. Chem. Eng. J., 2016, 307: 283-290
  (d)Li Y, Yang C X, Yan X P. Chem. Commun., 2017, 53(16): 2511-2514
  (e)Zhou M, Wu Y N, Qiao J, et al. J. Colloid Interface Sci., 2013, 405(9): 157-163
  (f)YANG Qing-Xiang (杨清香), REN Shuang-Shuang(任爽爽), ZHAO Qian-Qian(赵倩倩), et al. Chinese J. Inorg.Chem.(无机化学学报), 2017, 33(5): 843-852
26. [26]
  Mthombeni N H, Mbakop S, Ochieng A, et al. J. Taiwan Inst. Chem. Eng., 2016, 66:172-180 doi: 10.1016/j.jtice.2016.06.016
1. [1]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
2. [2]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
3. [3]
  Anbang Du , Yuanfan Wang , Zhihong Wei , Dongxu Zhang , Li Li , Weiqing Yang , Qianlu Sun , Lili Zhao , Weigao Xu , Yuxi Tian . Photothermal Microscopy of Graphene Flakes with Different Thicknesses. Acta Physico-Chimica Sinica, 2024, 40(5): 2304027-0. doi: 10.3866/PKU.WHXB202304027
4. [4]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
5. [5]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
6. [6]
  Fugui XI , Du LI , Zhourui YAN , Hui WANG , Junyu XIANG , Zhiyun DONG . Functionalized zirconium metal-organic frameworks for the removal of tetracycline from water. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 683-694. doi: 10.11862/CJIC.20240291
7. [7]
  Xiaofang DONG , Yue YANG , Shen WANG , Xiaofang HAO , Yuxia WANG , Peng CHENG . Research progress of conductive metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 14-34. doi: 10.11862/CJIC.20240388
8. [8]
  Wei Li , Jinfan Xu , Yongjun Zhang , Ying Guan . 共价有机框架整体材料的制备及食品安全非靶向筛查应用——推荐一个仪器分析综合化学实验. University Chemistry, 2025, 40(6): 276-285. doi: 10.12461/PKU.DXHX202406013
9. [9]
  Chaolin Mi , Yuying Qin , Xinli Huang , Yijie Luo , Zhiwei Zhang , Chengxiang Wang , Yuanchang Shi , Longwei Yin , Rutao Wang . Galvanic Replacement Synthesis of Graphene Coupled Amorphous Antimony Nanoparticles for High-Performance Sodium-Ion Capacitor. Acta Physico-Chimica Sinica, 2024, 40(5): 2306011-0. doi: 10.3866/PKU.WHXB202306011
10. [10]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
11. [11]
  Tao Xu , Wei Sun , Tianci Kong , Jie Zhou , Yitai Qian . Stable Graphite Interface for Potassium Ion Battery Achieving Ultralong Cycling Performance. Acta Physico-Chimica Sinica, 2024, 40(2): 2303021-0. doi: 10.3866/PKU.WHXB202303021
12. [12]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
13. [13]
  Jing Wang , Pingping Li , Yuehui Wang , Yifan Xiu , Bingqian Zhang , Shuwen Wang , Hongtao Gao . Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater. University Chemistry, 2024, 39(5): 52-62. doi: 10.3866/PKU.DXHX202309097
14. [14]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
15. [15]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
16. [16]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
17. [17]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
18. [18]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
19. [19]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
20. [20]
  Shasha Ma , Zujin Yang , Jianyong Zhang . Facile Synthesis of FeBTC Metal-Organic Gel and Its Adsorption of Cr₂O₇²⁻: A Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(8): 314-323. doi: 10.3866/PKU.DXHX202401008

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(607)
HTML views(72)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe3O4/GO/PPy Composite

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite