Citation: LEI Li-Ling, YANG Qing-Xiang, ZHAO Jun-Hong, ZHANG Yan, JIA Chao-Yang, LU Ran, NIE Li-Min, CHEN Zhi-Jun. Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 658-666. doi: 10.11862/CJIC.2019.078 shu

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite

Zhengzhou Institute of Light Industry, Zhengzhou 450000, China

Corresponding author: CHEN Zhi-Jun, mcchenzj@zzuli.edu.cn
Received Date: 20 November 2018
Revised Date: 21 February 2019

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In order to improve the ability to remove 2-nitro-1, 3-benzenediol (NRC) in water, Fe₃O₄/GO/PPy ternary composites were prepared by hydrothermal method using GO prepared by modified Hummers method. UV-visible absorption spectroscopy (UV-Vis), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), ζ potential analysis to study the structural of magnetic nanocomposites, while the pH value of the solution, the amount of adsorbent, initial concentration, adsorption time and temperature on the adsorption of NRC were studied by adsorption kinetics and adsorption isotherms. The results showed that the prepared Fe₃O₄/GO/PPy composites were layered dispersed structure; GO layer structure was stripped; PPy and Fe₃O₄ particles irregularly interspersed among the GO sheets. Fe₃O₄ particles were the polyhedral crystal structure with polyhedral size in the range of 100~300 nm. The interface between Fe₃O₄ and PPy particles in the graphene sheet layer was in close contact with each other; Fe₃O₄/GO/PPy could easily separated in water because of the superparamagnetism. Fe₃O₄/GO/PPy could be separated with 40 s under external magnetic field and the removal ratio of the NRC was 91.6%. The adsorption property of Fe₃O₄/GO/PPy for NRC obtained the strongest adsorption under the NRC initial concentration (C₀) was 200 mg·L^-1, pH value was 5.00±0.05, tempreture (T) was 318.15 K, adsorbent dosage (m) was 10 mg·L^-1 and time (t) was 6 h, and the adsorption amount reached 163.3 mg·g^-1. The adsorption kinetics of NRC follows the second-order kinetic model, and the adsorption isotherm conforms to the Langmuir model. After using NRC for five times, the removal rate decreased from 91.6% to 77.6%, that illustrated Fe₃O₄/GO/PPy magnetic complex possessed good stability and repeated use ability.
- adsorption,
- organic-inorganic hybrid composites,
- graphene,
- 2-nitro-1, 3-benzenediol
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe3O4/GO/PPy Composite

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通讯作者: 陈斌, bchen63@163.com

Preparation and Adsorption of 2-Nitro-1, 3-benzenediol of Fe₃O₄/GO/PPy Composite