Citation: ZHANG Ting, MA Shi-Jie, PAN Yi, GUAN Ji-Biao, ZHANG Ming, ZHU Han, DU Ming-Liang. Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 674-686. doi: 10.11862/CJIC.2019.077 shu

Honeycomb-like Carbon Materials Derived from Pomelo Peels for the Simultaneous Detection of Heavy Metal Ions

ZHANG Ting ¹ ,
MA Shi-Jie ¹ ,
PAN Yi ¹ ,
GUAN Ji-Biao ¹ ,
ZHANG Ming ¹ ,
ZHU Han ² ,
DU Ming-Liang ^2,,

1.
College of Materials and Textiles, Zhejiang Sci-Tech University, Hangzhou 310018, China
2.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, Jiangsu 214122, China

Corresponding author: DU Ming-Liang, du@jiangnan.edu.cn
Received Date: 25 September 2018
Revised Date: 22 January 2019

Fund Project: 国家自然科学基金 51373154国家自然科学基金 51573166国家自然科学基金(No.51373154, 51573166)资助项目

Figures(10)

The metal-free carbon materials were obtained by a facile KOH activation and pyrolysis process from inexpensive and readily available pomelo peels, and possessed honeycomb-like nanostructures with a high specific surface area of 1 055 m²·g^-1 and a high graphitization degree. A porous activated carbon (PAC) material modified electrode was utilized as the working electrode for the simultaneous detection of Cd²⁺, Pb²⁺, and Cu²⁺ using square-wave anodic stripping voltammetry (SWASV) and exhibited high sensitivity, repeatability, stability and a low detection limit. The interconnected micropores and mesopores act as efficient ion-transfer channels and provid active surface areas with high accessibility, which serve as transport highways to accelerate mass diffusion and significantly promote exchange efficiency. High graphitization degree increases the electrical conductivity of the material and accelerates electron transport.
- carbonaceous materials,
- pomelo peels,
- honeycomb-like nanostructures,
- porous materials,
- heavy metal ion detection,
- square-wave anodic stripping voltammetry (SWASV)
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