Citation: HAN Jia-Xing, LIU Zheng, LIANG Chu-Xin, TANG Qun, LI Qing-Wei, ZHANG Shu-Fen. Syntheses, Crystal Structures and Properties of Transition Metal Complexes Based on Pyridine-2, 5-dicarboxylic Acid or Thiophene-2, 5-dicarboxylic Acid Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(4): 605-612. doi: 10.11862/CJIC.2019.069 shu

Syntheses, Crystal Structures and Properties of Transition Metal Complexes Based on Pyridine-2, 5-dicarboxylic Acid or Thiophene-2, 5-dicarboxylic Acid Ligand

HAN Jia-Xing ¹ ,
LIU Zheng ^1,, ,
LIANG Chu-Xin ¹ ,
TANG Qun ^1,, ,
LI Qing-Wei ¹ ,
ZHANG Shu-Fen ^1,2

1.
Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, Guangxi 541004, China
2.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116024, China

Corresponding author: LIU Zheng, lisa4.6@163.com TANG Qun, tangq@glut.edu.cn
Received Date: 3 July 2018
Revised Date: 7 December 2018

Figures(15)

Three transition metal coordination polymer materials were successfully synthesized by solvothermal method with the main ligand 2, 5-pyridinedicarboxylic acid (H₂L₁) or thiophene 2, 5-dicarboxylic acid (H₂L₂), and co-ligand 4, 4'-bipyridyl (4, 4'-bipy) or 1, 10-phenanthroline (phen). The complexes were characterized by X-ray single crystal diffraction, infrared spectroscopy (IR), fluorescence spectroscopy (FL) and thermogravimetric analysis (TG/DTG). The analysis of single crystal structure shows that all complexes belong to monoclinic system. Complexes 1 and 2 crystalize in P1 space group, and complex 3 crystalizes in P2/n. Complex 1 and complex 3 are zero-dimensional dinuclear small molecules, and complex 2 has a two-dimensional network structure.
- heterocyclic carboxyl ligand,
- transition metal complex,
- crystal structure,
- property
1. [1]
  Gao M, Zhang G, Tian M, et al. Inorg. Chim. Acta, 2019, 485:58-63 doi: 10.1016/j.ica.2018.09.079
2. [2]
  Xu X, Xu X Y, Mei H, et al. Food Chem., 2019, 276:419-426 doi: 10.1016/j.foodchem.2018.10.051
3. [3]
  Li Q L, Li H M, Xu S, et al. Food Chem., 2019, 176:50-56
4. [4]
  Zhang Z H, Dong M F, Hao X H, et al. Food Chem., 2019, 276:140-146 doi: 10.1016/j.foodchem.2018.10.019
5. [5]
  Wang J Y, Zhang L H, Sun Y L, et al. Fuel Process. Technol., 2018, 177:81-88 doi: 10.1016/j.fuproc.2018.04.013
6. [6]
  Xuan D L, Ishida T, Taketoshi A, et al. Appl. Catal. B, 2019, 241:539-547 doi: 10.1016/j.apcatb.2018.09.053
7. [7]
  Li X H, Zhang J, Zhou F, et al. Mol. Catal., 2018, 452:93-99 doi: 10.1016/j.mcat.2017.09.038
8. [8]
  Nasrollahzadeh M, Issaabadi Z, Safari R. Sep. Purif. Technol., 2019, 209:136-144 doi: 10.1016/j.seppur.2018.07.022
9. [9]
  Wang Y P, Li X Y, Li H H, et al. Inorg. Chem. Commun., 2016, 70:27-30 doi: 10.1016/j.inoche.2016.05.008
10. [10]
  Fang M, Chen Z, Yin G W, et al. Inorg. Chem. Commun., 2016, 70:51-55 doi: 10.1016/j.inoche.2016.05.025
11. [11]
  Jiang D Y, Sui W, Liu B, et al. Chin. J. Struct. Chem., 2016, 35(9):1445-1450
12. [12]
  Hong D F, Wang S J, Zou Y, et al. Mol. Cryst. Liq. Cryst., 2018, 664(10):175-181
13. [13]
  ZHENG Yun-Yun, HUANG Rui-Min, et al. Chinese J. Inorg. Chem., 2018, 34(4):733-738
14. [14]
  Gurudevaru C, Gopalakrishnan M, Swnthilkumar K, et al. Appl. Organomet. Chem., 2018, 32:3998-4016 doi: 10.1002/aoc.v32.2
15. [15]
  Pang X L, Li L, Yu X D, et al. Dalton Trans., 2018, 47:11530-11538 doi: 10.1039/C8DT02404A
16. [16]
  Gharagozlou M, Naghibi S, Ataei M. J. Chin. Chem. Soc., 2018, 65:1210-1217 doi: 10.1002/jccs.2018.65.issue-10
17. [17]
  Lu X X, Shi C, Zhu J, et al. Food Hydrocolloids, 2019, 88:58-67 doi: 10.1016/j.foodhyd.2018.09.034
18. [18]
  Palamarchuk M, Voit A, Papynov E, et al. J. Hazard. Mater., 2019, 363:233-241 doi: 10.1016/j.jhazmat.2018.08.080
19. [19]
  QIAN Yan-Tao, PENG Ye-Dong, ZHANG Wen-Wei, et al. Chinese J. Inorg. Chem., 2015, 5(31):857-864
20. [20]
  LI Guo-Wu, XIONG Ming, SHI Ni-Cheng, et al. Earth Science Frontiers, 2003, 10(2):492-493 doi: 10.3321/j.issn:1005-2321.2003.02.041
21. [21]
  Sheldrick G M. Acta Crystallogr. Sect. C:Cryst. Struct. Commun., 2015, C71(1):3-8
22. [22]
  Sheldrick G M. SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Germany, 1997.
23. [23]
  QIU Dong-Fang, GUO Ying-Cheng, FENG Yu-Quan, et al. Chinese J. Inorg. Chem., 2010, 9(26):1663-1668
24. [24]
25. [25]
  LIU Hong, DONG Yi-Ping, LIAO Ya-Si, et al. Chemical Reagents, 2014, 86(10):897-900
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
3. [3]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
4. [4]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
5. [5]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
9. [9]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
10. [10]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
11. [11]
  Lei Feng , Ze-Min Zhu , Ying Yang , Zongbin He , Jiafeng Zou , Man-Bo Li , Yan Zhao , Zhikun Wu . Long-Pursued Structure of Au₂₃(S-Adm)₁₆ and the Unexpected Doping Effects. Acta Physico-Chimica Sinica, 2024, 40(5): 2305029-0. doi: 10.3866/PKU.WHXB202305029
12. [12]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
13. [13]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
14. [14]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
15. [15]
  Linjie ZHU , Xufeng LIU . Synthesis, characterization and electrocatalytic hydrogen evolution of two di-iron complexes containing a phosphine ligand with a pendant amine. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 939-947. doi: 10.11862/CJIC.20240416
16. [16]
  Lifang HE , Wenjie TANG , Yaoze LUO , Mingsheng LIANG , Jianxin TANG , Yuxuan WU , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two dialkyltin complexes constructed based on 2, 2′-bipyridin-6, 6′-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1601-1609. doi: 10.11862/CJIC.20250012
17. [17]
  Xiaogang YANG , Xinya ZHANG , Jing LI , Huilin WANG , Min LI , Xiaotian WEI , Xinci WU , Lufang MA . Synthesis, structure, and photoelectric properties of Zinc(Ⅱ)-triphenylamine based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2078-2086. doi: 10.11862/CJIC.20250167
18. [18]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029

Get Citation

PDF

XML

Metrics

PDF Downloads(32)
Abstract views(2084)
HTML views(534)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142