Citation: TIAN Yu, Li LI, XIN Zi-Chan, ZHANG Wen-Zhi, XU Ying-Ming. Multimode Photodegradation and Photocatalytic Hydrogen Production of Flower Globular-like Heterostructure Composite ZnS/ZnO/ZnWO₄[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 493-504. doi: 10.11862/CJIC.2019.067 shu

Multimode Photodegradation and Photocatalytic Hydrogen Production of Flower Globular-like Heterostructure Composite ZnS/ZnO/ZnWO₄

TIAN Yu ^1,2 ,
Li LI ^1,2,, ,
XIN Zi-Chan ² ,
ZHANG Wen-Zhi ^2,, ,
XU Ying-Ming ²

1.
College of Materials Science and Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China
2.
College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, Heilongjiang 161006, China

Corresponding author: Li LI, qqhrlili@126.com ZHANG Wen-Zhi, qqhrll@163.com
Received Date: 9 November 2018
Revised Date: 26 December 2018

Figures(11)

The effects of microwave-assisted hydrothermal synthesis on the morphology and photocatalytic properties of a flower globular-like heterostructure composite were investigated. By the microwave-assisted hydrothermal two step process, ZnS/ZnO/ZnWO₄ composite was prepared. The crystal structure, composition, morphology, surface physicochemical properties and optical absorption properties were characterized by using X-ray diffraction (XRD), ultraviolet visible diffuse reflectance spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM), high resolution transmission electron microscope (HRTEM) and N₂ adsorption-desorption tests. The results showed that the composite exhibited a uniform flower globular-like shape. The flower structure consists of cubic ZnS nanoparticles, hexagonal ZnO and monoclinic ZnWO₄ nanorods. The grain size, specific surface area and pore volume of ZnO/ZnWO₄ composites were larger than those of ZnWO₄ composites due to microwave polarization. Moreover, microwave irradiation compounded ZnS and further increased the grain size of composite ZnS/ZnO/ZnWO₄. However, the specific surface area and pore volume of composite ZnS/ZnO/ZnWO₄ decreased due to the compactness of the inner sphere, but the composite still maintained a flower-like structure. The multimode photocatalytic degradation of malachite green enhanced by flower globular ZnS/ZnO/ZnWO₄ was studied. The experimental results of hydrogen production from photolysis water showed that ZnS/ZnO/ZnWO₄ composites had excellent hydrogen production ability (376.9 μmol·h^-1·g^-1), which was 246.5 times higher than that of commercial P25. The enhanced hydrogen production performance of the composites is related to the excellent flower globular shape, ternary heterostructure and multi-pathway photoelectron migration in photocatalytic reaction.
- microwave-assisted hydrothermal,
- ZnS,
- ZnO,
- ZnWO₄,
- photocatalysis,
- malachite green,
- water splitting
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Multimode Photodegradation and Photocatalytic Hydrogen Production of Flower Globular-like Heterostructure Composite ZnS/ZnO/ZnWO4

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通讯作者: 陈斌, bchen63@163.com

Multimode Photodegradation and Photocatalytic Hydrogen Production of Flower Globular-like Heterostructure Composite ZnS/ZnO/ZnWO₄