Citation: GE You, PAN Pei-Feng, PENG Xia, LIU Rui-Qing, ZHU Hong-Li, FENG Xiao-Miao, SHEN Qing-Ming, HUANG Zhen-Dong, MA Yan-Wen. Dual-Confined Sulfur Cathodes Encapsulated in MnO₂ Nanotubes and Wrapped with PEDOT for High-Performance Lithium-Sulfur Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(5): 769-779. doi: 10.11862/CJIC.2019.063 shu

Dual-Confined Sulfur Cathodes Encapsulated in MnO₂ Nanotubes and Wrapped with PEDOT for High-Performance Lithium-Sulfur Batteries

Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials(IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: LIU Rui-Qing, iamrqliu@njupt.edu.cn FENG Xiao-Miao, iamxmfeng@njupt.edu.cn
Received Date: 2 January 2019
Revised Date: 19 February 2019

Figures(5)

α-MnO₂ nanotubes were developed as host material to fill with sulfur in their tubular hollow space, and then the sulfur were further encapsulated by a thin layer of poly(3, 4-ethylenedioxythiophene) (PEDOT) exterior coating via an in situ polymerization process. Such a dual-confined sulfur cathode, denoted as S@α-MnO₂-PEDOT, showed high performance in lithium-sulfur batteries. It could reach a capacity of 774.4 mAh·g^-1 at a current density of 1 675 mA·g^-1 (1C) after 200 cycles and 854.1 mAh·g^-1 at a current density of 3 350 mA·g^-1 (2C), manifesting excellent cycling stability and rate capability. The outstanding performances are attributed to the new architecture. In the novel architecture, α-MnO₂ nanotubes not only provide the physical confinement for sulfur, but also enhance the chemical interaction between the sulfur host material and polysulfides. Simultaneously, PEDOT was introduced to enhance conductivity of sulfur-containing nanocomposites and further reduce the loss of sulfur due to volumetric change and the excessive dissolution of lithium polysulfides.
- lithium-sulfur batteries,
- MnO₂ nanotube,
- PEDOT,
- hydrothermal self-assembly
1. [1]
  Chen Y, Choi S H, Su D W, et al. Nano Energy, 2018, 47:331-339 doi: 10.1016/j.nanoen.2018.03.008
2. [2]
  Yang Y, Zheng G Y, Cui Y. Chem. Soc. Rev., 2013, 42:3018-3032 doi: 10.1039/c2cs35256g
3. [3]
  Manthiram A, Fu Y Z, Chung S H, et al. Chem. Rev., 2014, 114:11751-11787 doi: 10.1021/cr500062v
4. [4]
  Cheng Z B, Pan H, Xiao Z B, et al. J. Mater. Chem. A, 2018, 6:7375-7381 doi: 10.1039/C8TA01298A
5. [5]
  LI Yan-Bing, DUAN Xiao-Bo, HAN Ya-Miao, et al. Chinese J. Inorg. Chem., 2015, 31(4):641-648
6. [6]
  Chen T, Ma L B, Cheng B R, et al. Nano Energy, 2017, 38:239-248 doi: 10.1016/j.nanoen.2017.05.064
7. [7]
  Ma L B, Zhang W J, Wang L, et al. ACS Nano, 2018, 12:4868-4876 doi: 10.1021/acsnano.8b01763
8. [8]
  ZHAO Bin, LI Nian-Wu, LÜ Hong-Ling, et al. Chinese J. Inorg. Chem., 2014, 30(4):733-740
9. [9]
  WANG Ying, MI Kan, XIONG Sheng-Lin. Chinese J. Inorg. Chem., 2017, 33(2):243-248
10. [10]
  Wei Y J, Kong Z K, Pan Y K, et al. J. Mater. Chem. A, 2018, 6:5899-5909 doi: 10.1039/C8TA00222C
11. [11]
  Wang M R, Zhang H Z, Zhou W, et al. J. Mater. Chem. A, 2016, 4:1653-1662 doi: 10.1039/C5TA08999A
12. [12]
  Cha E, Patel M D, Park J, et al. Nat. Nanotechnol., 2018, 13:337-344 doi: 10.1038/s41565-018-0061-y
13. [13]
  Xiao S, Liu S H, Zhang J Q, et al. J. Power Sources, 2015, 293:119-126 doi: 10.1016/j.jpowsour.2015.05.048
14. [14]
  Kim H, Lim H D, Kim J, et al. J. Mater. Chem. A, 2014, 2:33-47
15. [15]
  Evers S, Nazar L F. Acc. Chem. Res., 2013, 46:1135-1143 doi: 10.1021/ar3001348
16. [16]
  Pu J, Shen Z H, Zheng J X, et al. Nano Energy, 2017, 37:7-14 doi: 10.1016/j.nanoen.2017.05.009
17. [17]
  Xiao Z C, Kong D B, Song Q, et al. Nano Energy, 2018, 46:365-371 doi: 10.1016/j.nanoen.2018.02.016
18. [18]
  Yang W, Yang W, Song A L, et al. Nanoscale, 2018, 10:816-824 doi: 10.1039/C7NR06805K
19. [19]
  Gueon D, Hwang J T, Yang S B, et al. ACS Nano, 2018, 12:226-233 doi: 10.1021/acsnano.7b05869
20. [20]
  Kang W M, Fan L L, Deng N P, et al. Chem. Eng. J., 2018, 333:185-190 doi: 10.1016/j.cej.2017.09.134
21. [21]
  Perez S B, Balbuena P B. ChemSusChem, 2018, 11:1970-1980
22. [22]
  Song J C, Noh H J, Lee J H, et al. J. Power Sources, 2016, 332:72-78 doi: 10.1016/j.jpowsour.2016.09.092
23. [23]
  Zhang M, Meng Q H, Ahmad A, et al. J. Mater. Chem. A, 2017, 5:17647-17652 doi: 10.1039/C7TA03314A
24. [24]
  Yan J H, Li B Y, Liu X B. Nano Energy, 2015, 18:245-252 doi: 10.1016/j.nanoen.2015.10.024
25. [25]
  Zhang S S, Tran D T, Zhang Z C. J. Mater. Chem. A, 2014, 2:18288-18292 doi: 10.1039/C4TA04417G
26. [26]
  Hu H, Cheng H Y, Liu Z F, et al. Nano Lett., 2015, 15:5116-5123 doi: 10.1021/acs.nanolett.5b01294
27. [27]
  Tsao C H, Hsu C H, Zhou J D, et al. Electrochim. Acta, 2018, 276:111-117 doi: 10.1016/j.electacta.2018.04.013
28. [28]
  Shen J D, Liu J, Liu Z B, et al. Chem. Eur. J., 2017, 24:4573-4582
29. [29]
  Hong X J, Tang X Y, Wei Q, et al. ACS Appl. Mater. Interfaces, 2018, 10:9435-9443 doi: 10.1021/acsami.7b19609
30. [30]
  Yan M, Zhang Y, Li Y, et al. J. Mater. Chem. A, 2016, 4:9403-9412 doi: 10.1039/C6TA03211G
31. [31]
  Fang M M, Chen Z M, Liu Y, et al. J. Mater. Chem. A, 2018, 6:1630-1638 doi: 10.1039/C7TA08864G
32. [32]
  Hong Y J, Roh K C, Kang Y C. Carbon, 2018, 126:394-403 doi: 10.1016/j.carbon.2017.10.032
33. [33]
  Li W, Hicks-Garner J, Wang J, et al. Chem. Mater., 2014, 26:3403-3410 doi: 10.1021/cm500575q
34. [34]
  Liu X Y, Shan Z Q, Zhu K L, et al. J. Power Sources, 2015, 274:85-93 doi: 10.1016/j.jpowsour.2014.10.039
35. [35]
  Ma L, Wei S Y, Zhuang H L, et al. J. Mater. Chem. A, 2015, 3:19857-19866 doi: 10.1039/C5TA06348E
36. [36]
  Paolella A, Laul D, Timoshevskii V, et al. J. Phys. Chem. C, 2018, 122:1014-1023 doi: 10.1021/acs.jpcc.7b08719
37. [37]
  Yuan Z, Peng H J, Hou T Z, et al. Nano Lett., 2016, 16:519-527 doi: 10.1021/acs.nanolett.5b04166
38. [38]
  Lee J Y, Hwang T J, Lee Y H, et al. Mater. Lett., 2015, 158:132-135 doi: 10.1016/j.matlet.2015.06.003
39. [39]
  Li Z, Zhang J T, Lou X W. Angew. Chem. Int. Ed., 2015, 54:12886-12890 doi: 10.1002/anie.v54.44
40. [40]
  Kong W B, Yan L J, Luo Y F, et al. Adv. Funct. Mater., 2017, 27:1606663 doi: 10.1002/adfm.201606663
41. [41]
  Zhang J, Shi Y, Ding Y, et al. Nano Lett., 2016, 16:7276-7281
42. [42]
  Zefirov V V, Elmanovich I V, Levin E E, et al. J. Mater. Sci., 2018, 53:9449-9462 doi: 10.1007/s10853-018-2242-3
43. [43]
  Luo J, Zhu H T, Fan H M, et al. J. Phys. Chem. C, 2008, 112:12594-12598 doi: 10.1021/jp8052967
44. [44]
  Anilkumar K M, Jinisha B, Manoj M, et al. Appl. Surf. Sci., 2018, 442:556-564 doi: 10.1016/j.apsusc.2018.02.178
45. [45]
  Ji T, Tan L C, Hu X T, et al. Phys. Chem. Chem. Phys., 2015, 17:4137-4145 doi: 10.1039/C4CP04965A
46. [46]
  Reyes-Reyes M, Cruz-Cruz I, López-Sandoval R. J. Phys. Chem. C, 2010, 114:20220-20224 doi: 10.1021/jp107386x
47. [47]
  Sakamoto S, Okumura M, Zhao Z, et al. Chem. Phys. Lett., 2005, 412:395-398 doi: 10.1016/j.cplett.2005.07.040
48. [48]
  Chabu J M, Zeng K, Walle M D, et al. Chemistry Select, 2017, 2:11035-11039
49. [49]
  Ni L B, Zhao G J, Yang G, et al. ACS Appl. Mater. Interfaces, 2017, 9:34793-34803 doi: 10.1021/acsami.7b07996
50. [50]
  Rehman S, Tang T Y, Ali Z S, et al. Small, 2017, 13:1700087(8 Pages)
51. [51]
  Su Y S, Fu Y Z, Cochell T, et al. Nat. Commun., 2013, 4:2985-2992 doi: 10.1038/ncomms3985
52. [52]
  Zhao C C, Shen C, Xin F X, et al. Mater. Lett., 2014, 137:52-55 doi: 10.1016/j.matlet.2014.08.115
53. [53]
  Fang R P, Zhao S Y, Hou P X, et al. Adv. Mater., 2016, 28:3374-3382 doi: 10.1002/adma.201506014
54. [54]
  Ahn W, Kim K B, Jung K N, et al. J. Power Sources, 2012, 202:394-399 doi: 10.1016/j.jpowsour.2011.11.074
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2. [2]
  Jia Fu , Shilong Zhang , Lirong Liang , Chunyu Du , Zhenqiang Ye , Guangming Chen . PEDOT-based thermoelectric composites: Preparation, mechanism and applications. Chinese Chemical Letters, 2024, 35(9): 109804-. doi: 10.1016/j.cclet.2024.109804
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4. [4]
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5. [5]
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7. [7]
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8. [8]
  Lumin Zheng , Ying Bai , Chuan Wu . Multi-electron reaction and fast Al ion diffusion of δ-MnO₂ cathode materials in rechargeable aluminum batteries via first-principle calculations. Chinese Chemical Letters, 2024, 35(4): 108589-. doi: 10.1016/j.cclet.2023.108589
9. [9]
  Jianmei Han , Peng Wang , Hua Zhang , Ning Song , Xuguang An , Baojuan Xi , Shenglin Xiong . Performance optimization of chalcogenide catalytic materials in lithium-sulfur batteries: Structural and electronic engineering. Chinese Chemical Letters, 2024, 35(7): 109543-. doi: 10.1016/j.cclet.2024.109543
10. [10]
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Dual-Confined Sulfur Cathodes Encapsulated in MnO₂ Nanotubes and Wrapped with PEDOT for High-Performance Lithium-Sulfur Batteries