Citation: WU Cai-Hong, ZHENG Guo-Yuan, WANG Ji-Lin, MO Shu-Yi, ZOU Zheng-Guang, LONG Fei. Preparation and Adsorption Properties for Methyl Orange of Highly Dispersed Boehmite and Alumina Nanostructures[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 449-458. doi: 10.11862/CJIC.2019.061 shu

Preparation and Adsorption Properties for Methyl Orange of Highly Dispersed Boehmite and Alumina Nanostructures

WU Cai-Hong ^1,2 ,
ZHENG Guo-Yuan ^1,2,, ,
WANG Ji-Lin ^1,2 ,
MO Shu-Yi ^1,2 ,
ZOU Zheng-Guang ^1,2 ,
LONG Fei ^1,2

1.
School of Materials Science and Engineering, Key Laboratory of Nonferrous Materials and New Processing Technology of Ministry of Education, Guilin University of Technology, Guilin, Guangxi 541004, China
2.
Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi, Guilin University of Technology, Guilin, Guangxi 541004, China

Corresponding author: ZHENG Guo-Yuan, zhengguoyuan@glut.edu.cn
Received Date: 3 October 2018
Revised Date: 10 January 2019

Figures(9)

The nano boehmite (γ-AlO(OH)) was synthesized by template-free hydrothermal method with aluminum nitrate as the aluminum source and urea as the precipitant. The final products aluminum oxide (γ-Al₂O₃ and θ-Al₂O₃) were obtained by calcined at different temperatures. The products were characterized by X-ray diffraction (XRD), field emission scanning electron microcopy (FESEM), transmission electron microscopy (TEM), Fourier transfer infrared (FTIR), nitrogen adsorption-desorption method and UV-visible Spectrophotometer (UV-Vis). The adsorption properties of the product for methyl orange (MO) was studied, and the effect of adsorption time, pH value of the solution, methyl orange concentration and recycling on the adsorption performance of the products systematically were investigated. In addition, the adsorption theory studies on the adsorption process was conducted. The results showed that the products obtained by this method are more dispersible, uniform and complete in morphology compared to the products prepared by other methods. The products were highly dispersed nano-bundled structure. The maximum adsorption of γ-AlO(OH) on methyl orange reached 1 492.5 mg·g^-1. The adsorption mechanism of the products includes chemical adsorption mechanism, electrostatic adsorption mechanism and so on. The adsorption of MO on the three products accord with the Langmuir monolayer adsorption model, and the adsorption process are consistent with the pseudo-second-order kinetic.
- materials science,
- boehmite,
- hydrothermal method,
- aluminum oxide,
- methyl orange,
- adsorption,
- highly dispersed nanostructure
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沈阳化工大学材料科学与工程学院沈阳 110142