Citation: LAN Dong-Hui, TANG Ting, DAI Wei-Li, TAN Nian-Yuan, WU Shui-Sheng, AU Chak-Tong, YI Bing. Synergistic Effects in Multi-group Functionalized Graphene Oxide for CO₂ Cycloaddition Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 442-448. doi: 10.11862/CJIC.2019.060 shu

Synergistic Effects in Multi-group Functionalized Graphene Oxide for CO₂ Cycloaddition Reaction

LAN Dong-Hui ^1,2,, ,
TANG Ting ¹ ,
DAI Wei-Li ² ,
TAN Nian-Yuan ¹ ,
WU Shui-Sheng ¹ ,
AU Chak-Tong ^1,, ,
YI Bing ^1,,

1.
Hunan Provincial Key Laboratory of Environmental Catalysis and Waste Regeneration, College of Chemistry and Chemical Engineering, Hunan Institute of Engineering, Xiangtan, Hunan 411104, China
2.
Key Laboratory of Jiangxi Province for Persistant Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China

Corresponding author: LAN Dong-Hui, donghuilan@hnu.edu.cn AU Chak-Tong, pctau@hkbu.edu.hk YI Bing, bingyi2004@126.com
Received Date: 12 October 2018
Revised Date: 24 December 2018

Figures(8)

Based on the synergetic effects among hydrogen bond donors, halide anions and suitable amines for the CO₂ cycloaddition reaction, the multi-functionalized graphene oxide (containing silanol group, quaternary ammonium salt and tertiary amine) were synthesized by a "in-situ approach". Hexamethylenetetramine that is non-toxic, cheap and rich in tertiary amine was used as precursor for quaternary ammonium salt. Then, further quaternization was conducted by adding halohydrocarbon for the formation of multi-cationic quaternary ammonium salt functionalized graphene oxide (F-GO) heterogeneous catalysts. As characterized by X-ray photoelectron spectroscopy and elemental analysis, the loading of quaternary ammonium salt and tertiary amine was up to 2.23 and 2.49 mmol·g^-1, respectively. The "multi-cationic approach" is proved to be beneficial to improve the amount of ionic liquids and catalytic activity. The F-GO was used as metal-free heterogeneous catalyst for the synthesis of cyclic carbonates through the cycloaddition of CO₂ towards propylene epoxide under mild conditions without solvent and co-catalyst. The yield of propylene carbonate was up to 99.2% (100℃, 2 MPa, 4 h). The synergetic effects was investigated by comparing the catalytic activity of F-GO functionalized with different groups. A plausible mechanism was proposed for the CO₂ cycloaddition reaction over F-GO. In addition, F-GO is a water-tolerant and stable catalyst for the cycloaddition reaction, and there was no significant loss of catalytic activity after six runs.
- catalysis,
- cycloaddition,
- graphene oxide,
- functional,
- carbon dioxide,
- synergistic
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沈阳化工大学材料科学与工程学院沈阳 110142

Synergistic Effects in Multi-group Functionalized Graphene Oxide for CO2 Cycloaddition Reaction

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通讯作者: 陈斌, bchen63@163.com

Synergistic Effects in Multi-group Functionalized Graphene Oxide for CO₂ Cycloaddition Reaction