Citation: WANG Hai-Wen, WANG Yi-Dan, MAO Qian-Long, AN Guo-Qiang, CHE Qiang, ZHANG Shun-Jiang, YIN Xin. Sulfur-Doped Ordered Mesoporous Carbon as Fuel Cell Electrocatalyst for Oxygen Reduction[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 369-375. doi: 10.11862/CJIC.2019.056 shu

Sulfur-Doped Ordered Mesoporous Carbon as Fuel Cell Electrocatalyst for Oxygen Reduction

School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China

Corresponding author: YIN Xin, youshikiyin@ecust.edu.cn
Received Date: 27 September 2018
Revised Date: 7 January 2019

Figures(6)

The novel sulfur-doped ordered mesoporous carbon (S-OMC) was prepared via one-step hard-template method employing thymol blue as a single precursor. The S-OMC obtained at 900℃ showed appropriate graphitization degree and hierarchical pore structures with a high surface area of 1 230 m²·g^-1 and a pore size distribution centered at 4.6 nm. These unique local structures and thio-phene S active sites for oxygen reduction reaction (ORR) contributed to the efficient catalytic performance of this ordered mesoporous carbon. It exhibited the ORR half wave potential of -0.21 V in 0.1 mol·L^-1 KOH, and with superior stability and methanol tolerance in alkaline media. This one-step nanocasting route provides an industrially feasible synthesis for S doped ordered mesoporous carbon and shows efficient electroreduction activity for ORR compared to commercial Pt/C.
- oxygen reduction,
- electrocatalysis,
- fuel cell
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