Citation: HU Feng-Xian, DAI Yong, YU Gui-Yun. Preparation and Photocatalytic Activity of Cerium Oxide/Bismuth Molybdate Composite Photocatalyst[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(3): 433-441. doi: 10.11862/CJIC.2019.050 shu

Preparation and Photocatalytic Activity of Cerium Oxide/Bismuth Molybdate Composite Photocatalyst

HU Feng-Xian ^1,2 ,
DAI Yong ^2,, ,
YU Gui-Yun ^2,,

1.
School of Chemistry & Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China
2.
School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng, Jiangsu 224051, China

Corresponding author: DAI Yong, 123daiyong123@163.com YU Gui-Yun, yuguiyun1@163.com
Received Date: 29 September 2018
Revised Date: 27 December 2018

Figures(13)

Cerium oxide/Bismuth molybdate catalysts were synthesized by hydrothermal method. The relationships between cerium oxide and the composition, structure, photocatalytic activity of Bismuth molybdate were further investigated under the different acid-base reaction system solutions. The samples were characterized by X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy. It was found that the addition of CeO₂ seriously affected the morphology, composition, structure and photocatalytic properties of bismuth molybdate in different acid-base synthesis systems. The reaction product was more beneficial to the formation of Bi₂MoO₆ in the acidic system and made for the formation of Bi_3.64Mo_0.36O_6.55/Bi₂MoO₆ in alkaline condition without CeO₂. When CeO₂ was added to reaction-solution system, the composition and structure of the substances were almost unchanged in the acidic system; the photocatalytic activity was greatly enhanced. The morphology, composition, structure and photocatalytic properties of the materials have changed greatly under alkaline conditions. The reaction product was more beneficial to the formation of Bi_3.64Mo_0.36O_6.55. Therefore, under alkaline conditions, the addition of CeO₂ promoted the conversion of Bi₂MoO₆ to Bi_3.64Mo_0.36O_6.55.
- cerium oxide,
- bismuth molybdate,
- hydrothermal method,
- photocataly,
- rhodamine B
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