Citation: SHI Jing-Jing, XU Shan, LI Na, WANG Xiu-Guang, ZHAO Xiao-Jun, YANG En-Cui. A Layered Cd(Ⅱ)-Organic Coordination Polymer Exhibiting Dual-Responsive Sensing Towards 2, 4, 6-Trinitrophenol and Fe³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 351-360. doi: 10.11862/CJIC.2019.045 shu

A Layered Cd(Ⅱ)-Organic Coordination Polymer Exhibiting Dual-Responsive Sensing Towards 2, 4, 6-Trinitrophenol and Fe³⁺

College of Chemistry, Tianjin Normal University, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin 300387, China

Corresponding author: ZHAO Xiao-Jun, xiaojun_zhao15@163.com YANG En-Cui, encui_yang@163.com
Received Date: 2 October 2018
Revised Date: 5 December 2018

Figures(7)

A layered coordination polymer[Cd(QDA)]_n (1) with distorted Cd²⁺ octahedron extended by three-connected 2, 3-quinoline dicarboxylate linkers was hydrothermally synthesized, exhibiting intense blue fluorescence and highly thermal and chemical stability. More interestingly, the complex dispersed in ethanol can quickly probe the trace amounts of 2, 4, 6-trinitrophenol (K_sv=6.61×10⁴ L·mol^-1, LOD=0.83 μmol·L^-1) and Fe³⁺ (K_sv=1.74×10⁴ L·mol^-1, LOD=2.70 μmol·L^-1) through fluorescence quenching with high quenching constants (K_sv) and low limits of detection (LOD).
- coordination polymer,
- 2, 3-quinoline dicarboxylic acid,
- crystal structure,
- quenching constant,
- fluorescence sensing
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沈阳化工大学材料科学与工程学院沈阳 110142

A Layered Cd(Ⅱ)-Organic Coordination Polymer Exhibiting Dual-Responsive Sensing Towards 2, 4, 6-Trinitrophenol and Fe3+

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通讯作者: 陈斌, bchen63@163.com

A Layered Cd(Ⅱ)-Organic Coordination Polymer Exhibiting Dual-Responsive Sensing Towards 2, 4, 6-Trinitrophenol and Fe³⁺