Citation: CHENG Shao-Wen, ZHANG Na, ZHUO Ning-Ze, ZHU Yue-Hua, CHEN Yong-Hao, JIANG Peng, DU Wen-Hui, YE En-Gan, WANG Hai-Bo. Synthesis, Luminescent Properties and Energy Transfer Behavior of Apatite Phosphor Ba₁₀(PO₄)₆F₂: Ce³⁺, Tb³⁺[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 209-216. doi: 10.11862/CJIC.2019.038 shu

Synthesis, Luminescent Properties and Energy Transfer Behavior of Apatite Phosphor Ba₁₀(PO₄)₆F₂: Ce³⁺, Tb³⁺

CHENG Shao-Wen ¹ ,
ZHANG Na ^2,3,, ,
ZHUO Ning-Ze ^2,3 ,
ZHU Yue-Hua ^2,3 ,
CHEN Yong-Hao ⁴ ,
JIANG Peng ⁴ ,
DU Wen-Hui ⁴ ,
YE En-Gan ⁴ ,
WANG Hai-Bo ^3,,

1.
Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China
2.
Institute of Electronic and Photonic Materials of Light Industry, Nanjing 210015, China
3.
Research Institute of Electronic and Photonic Materials, Nanjing Tech University, Nanjing 210015, China
4.
College of Material Science and Engineering, Nanjing Tech University, Nanjing 210009, China

Corresponding author: ZHANG Na, zhangna8389@163.com WANG Hai-Bo, wanghaibo88@163.com
Received Date: 23 August 2018
Revised Date: 22 November 2018

Figures(10)

A series of Ce³⁺-and Ce³⁺/Tb³⁺-activated Ba₁₀(PO₄)₆F₂ phosphors with apatite structure have been synthesized via high temperature solid-state reaction. X-ray diffraction (XRD), scanning electron microscopy (SEM), the photoluminenscence excitation (PLE) spectra and photoluminescence (PL) spectra were used to characterize samples. The results revealed that the fluorapatite structured Ba₁₀(PO₄)₆F₂:Ce³⁺, Tb³⁺ phosphor particles with irregular morphology have been obtained. The relative intensities of PL spectra of Ba_10-x(PO₄)₆F₂:xCe³⁺ phosphors increased with increasing x values, and reached the maximum at x=0.09. The as-prepared phosphors Ba₁₀(PO₄)₆F₂:Ce³⁺, Tb³⁺ phosphors exhibited broad excitation band ranging from 240 to 330 nm. The emission spectra of Ba₁₀(PO₄)₆F₂:Ce³⁺, Tb³⁺ phosphor showed the violet-emitting band centered at 335 and 358 nm and green light-emitting band centered at 542 nm, which originate from the 5d→4f transitions of Ce³⁺ and 4f→4f transitions of Tb³⁺, respectively. The spectral characteristics showed that the energy transfer occurs from Ce³⁺ to Tb³⁺ in Ba₁₀(PO₄)₆F₂:Ce³⁺, Tb³⁺ phosphors, and the energy transfer efficiency between Ce³⁺ and Tb³⁺ could reach up to 60%. The critical distance of Ce³⁺ and Tb³⁺ was calculated to be 0.79 nm, and the mechanism of energy transfer from Ce³⁺ to Tb³⁺ is dipole-dipole interaction. In addition, the energy transfer behavior and luminescence process were discussed in detail. By adjusting the concentration of Tb³⁺, the relationship between chromatic coordinate and the doping concentration of Tb³⁺ was studied. The Ba₁₀(PO₄)₆F₂:Ce³⁺, Tb³⁺ phosphors emission color could adjust from blue to green, and the chromatic coordinate tuned from (0.149 4, 0.045 1) to (0.280 1, 0.585 3) with increasing the concentration of Tb³⁺ from 0 to 0.52.
- high-temperature solid-state reaction,
- fluorapatite,
- Ce³⁺/Tb³⁺-activated phosphor,
- luminescence,
- energy transfer
1. [1]
  Li G G, Lin C C, Wei Y, et al. Chem. Commun., 2016, 52(46):7376-7379 doi: 10.1039/C6CC01969B
2. [2]
  Pust P, Weiler V, Hecht C, et al. Nat. Mater., 2014, 13(9):891-896 doi: 10.1038/nmat4012
3. [3]
  Jiang G X, Yang B B, Zhao G Y, et al. Opt. Mater., 2018, 83:93-98 doi: 10.1016/j.optmat.2018.05.074
4. [4]
  Guo Q F, Liao L B, Molokeev M S, et al. Mater. Res. Bull., 2015, 72:245-251 doi: 10.1016/j.materresbull.2015.07.029
5. [5]
  Feng L J, Tian Y, Wang L, et al. J. Mater. Sci., 2016, 51(6):2841-2849 doi: 10.1007/s10853-015-9592-x
6. [6]
  Shang M M, Geng D L, Zhang Y, et al. J. Mater. Chem., 2012, 22(36):19094-19104 doi: 10.1039/c2jm34092e
7. [7]
  Lv Y, Jin Y H, Wang C L, et al. RSC Adv., 2017, 7(69):43700-43707 doi: 10.1039/C7RA08090E
8. [8]
  Guo Q F, Wang Q D, Jiang L W, et al. Phys. Chem. Chem. Phys., 2016, 18(23):15545-15554 doi: 10.1039/C6CP01512C
9. [9]
  Li G G, Zhao Y, Wei Y, et al. Chem. Commun., 2016, 52(16):3376-3379 doi: 10.1039/C5CC09782G
10. [10]
  Sokolnicki J, Zych E. J. Lumin., 2015, 158:65-69 doi: 10.1016/j.jlumin.2014.09.033
11. [11]
  Zhu G, Shi Y R, Mikami M, et al. Opt. Mater. Express, 2013, 3(2):229-236 doi: 10.1364/OME.3.000229
12. [12]
  Que M D, Ci Z P, Wang Y H, et al. CrystEngComm, 2013, 15(32):6389-6395 doi: 10.1039/c3ce40482j
13. [13]
  Liu H K, Zhang Y Y, Liao L B, et al. J. Lumin., 2014, 156:49-54 doi: 10.1016/j.jlumin.2014.07.010
14. [14]
  Shang M M, Geng D L, Yang D M, et al. Inorg. Chem., 2013, 52(6):3102-3112 doi: 10.1021/ic3025759
15. [15]
  Fu L L, Fu Z L, Yu Y N, et al. Ceram. Int., 2015, 41(5):7010-7016 doi: 10.1016/j.ceramint.2015.02.004
16. [16]
  Li K, Geng D L, Shang M M, et al. J. Phys. Chem. C, 2014, 118(20):11026-11034 doi: 10.1021/jp501949m
17. [17]
  Wei L, Jia Y C, Lv W Z, et al. New J. Chem., 2013, 37(11):3701-3705 doi: 10.1039/c3nj00758h
18. [18]
  Li G G, Zhang Y, Geng D L, et al. ACS Appl. Mater. Interfaces, 2012, 4(1):296-305 doi: 10.1021/am201335d
19. [19]
  Li G G, Geng D L, Shang M M, et al. J. Phys. Chem. C, 2011, 115(44):21882-21892 doi: 10.1021/jp204824d
20. [20]
  Lee S H, Choi J I, Kim Y J, et al. Mater. Charact., 2015, 103:162-169 doi: 10.1016/j.matchar.2015.03.027
21. [21]
  Kang Y C, Kim E J, Lee D Y, et al. J. Alloys Compd., 2002, 347(1):266-270
22. [22]
  Tao Z X, Huang Y L, Seo H J. Dalton Trans., 2013, 42(6):2121-2129 doi: 10.1039/C2DT32117C
23. [23]
  White T J, Dong Z L. Acta Crystallogr. Sect. B:Struct. Sci., 2010, 59(1):1-16
24. [24]
  Mathew M, Mayer I, Dickens B, et al. J. Solid State Chem., 1979, 28(1):79-95
25. [25]
  Berry L G, Mason B, Dietrich R V. Mineralogy, Concepts, Descriptions, Determinations. San Francisco:W. H. Freeman, 1983:550-551
26. [26]
  Han X M, Lin J, Xing R B, et al. J. Phys.:Condens. Matter, 2003, 15(12):2115-2126 doi: 10.1088/0953-8984/15/12/328
27. [27]
  Liu H K, Luo Y, Mao Z Y, et al. J. Mater. Chem. C, 2014, 2(9):1619-1627 doi: 10.1039/c3tc32003k
28. [28]
  Zeng C, Liu H K, Hu Y M, et al. Opt. Laser Technol., 2015, 74:6-10 doi: 10.1016/j.optlastec.2015.05.003
29. [29]
  Jeon Y I, Bharat L K, Yu J S. J. Lumin., 2015, 166:93-100 doi: 10.1016/j.jlumin.2015.05.010
30. [30]
  Tang W J, Zhang F. Eur. J. Inorg. Chem., 2014(21):3387-3392
31. [31]
  Guan A X, Yao C Y, Wang G F, et al. J. Lumin., 2016, 32(4):1-6
32. [32]
  Jin Y H, Lv Y, Hu Y H, et al. J. Lumin., 2017, 185:106-111 doi: 10.1016/j.jlumin.2017.01.004
33. [33]
  Ding X, Wang Y H. Phys. Chem. Chem. Phys., 2017, 19(3):2449-2458 doi: 10.1039/C6CP08300E
34. [34]
  Guo Y, Moon B K, Choi B C, et al. Ceram. Int., 2016, 42(16):18324-18332 doi: 10.1016/j.ceramint.2016.08.163
35. [35]
  Liang C, You H P, Fu Y B, et al. Optik, 2017, 131:335-342 doi: 10.1016/j.ijleo.2016.11.099
36. [36]
  Dexter D L, Schulman J H. J. Chem. Phys., 1954, 22(6):1063-1070 doi: 10.1063/1.1740265
37. [37]
  Hussain S K, Giang T T H, Yu J S. J. Alloys Compd., 2018, 739:218-226 doi: 10.1016/j.jallcom.2017.12.200
38. [38]
  YU Ting, GAO Ming-Yan, SONG Yan, et al. Chinese J. Inorg. Chem., 2018, 34(5):857-863
39. [39]
  SUN Jia-Yue(孙家跃), DU Hai-Yan(杜海燕), HU Wen-Xiang(胡文祥). Solid Luminous Materials(固体发光材料). Beijing: Chemical Industry Press, 2003.
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Synthesis, Luminescent Properties and Energy Transfer Behavior of Apatite Phosphor Ba10(PO4)6F2: Ce3+, Tb3+

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通讯作者: 陈斌, bchen63@163.com

Synthesis, Luminescent Properties and Energy Transfer Behavior of Apatite Phosphor Ba₁₀(PO₄)₆F₂: Ce³⁺, Tb³⁺