Advanced Search

Citation: BU Guan, SUN Jing, ZHOU Chen, YU Wen-Sheng, WANG Yuan, TANG Juan. Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)3phen] and[Eu(PCBA)3phen][J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 203-208. doi: 10.11862/CJIC.2019.029 shu

Preparation and Properties of the Temperature Sensitive Paints[Eu(PBrBA)3phen] and[Eu(PCBA)3phen]

  • School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Jilin Provincial Science and Technology Innovation Center of Optical Materials and Chemistry, Changchun 130022, China

Figures(6)

  • Europiumsesquioxide (Eu2O3), parachlorobenzoic-acid (PCBA), parabromobenzoic acid (PBrBA) and o-phenanthroline (phen) were used as raw materials to synthesize two kinds of probe molecules Eu(PCBA)3phen and Eu(PBrBA)3phen. And these two probe molecules were doped in the substrate of polymethyl methacrylate (MMA), benzoyl (BPO) peroxide as initiator, to prepare two kinds of temperature sensitive paints. The infrared spectrometer, ultraviolet spectrometer, scanning electron microscope and fluorescence spectrometer were utilized to analyze the structure, fluorescence properties, morphology and temperature sensitivity of the probes, respectively. Meanwhile the effects of different ligands on the fluorescence properties of the probe molecules and the relevant temperature sensitive paints were studied. The results showed that Eu3+ was coordinated with the main ligand of PCBA and PBrBA, respectively, and the second ligand phen was involved in the coordination, which confirms that two new complexes were synthesized. Both complexes emit characteristic fluorescence of Eu3+, and the ternary complex of phenanthroline europium with PBrBA as the main ligand has better fluorescent properties. Furthermore, the temperature sensitive paints based on these two probes both had temperature-quenching performance in a range of 50~90℃, and the temperature sensitive paint doped with Eu(PCBA)3phen had better temperature sensitivity.
  • 加载中
    1. [1]

      Ruyten W M. Rev. Sci. Instrum., 1997, 68(9):3452-3457

    2. [2]

      Wang J F, Zhang D H, Liu X, et al. J. Chem. Eng. Data, 2010, 55(12):5608-5613  doi: 10.1021/je1004565

    3. [3]

      SUN Meng-Ting, LU Si-Yu, SUN Jing, et al. Chinese J. Inorg. Chem., 2017, 33(7):1217-1222
       

    4. [4]

      Cattafesta Ⅲ L N, Iyer V, Masad J A, et al. AIAA J., 1995, 33(11):2032-2037  doi: 10.2514/3.12944

    5. [5]

      ZHANG Min, SUN Jing, LIU Hui-Min, et al. Chinese J. Inorg. Chem., 2016, 32(3):421-426
       

    6. [6]

      ZENG Xue-Jun, LI Ming, LIU Tai-Kui, et al. Acta Aerodynamica Sinica, 2004, 22(4):494-498  doi: 10.3969/j.issn.0258-1825.2004.04.024

    7. [7]

      DAI Jing-Min. Techniques of Automation and Application, 2004, 23(3):11-16  doi: 10.3969/j.issn.1003-7241.2004.03.003

    8. [8]

      WU Sheng-Nan, CHEN Yong-Jie, XING Zhen-Fang, et al. Acta Optica Sinica, 2015, 35(1):305-312
       

    9. [9]

      LU Si-Yu, LIU Xu-Ri, BI Guan, et al. Chinese J. Inorg. Chem., 2018(4):683-688
       

    10. [10]

      Fey U, Engler R H, Egami Y, et al. 20th International Congress on Instrumentation in Aerospace Simulation Facilities. Gottingen: [s.n.], 2003: 77-88

    11. [11]

      Whan R E, Crosby G A, et al. J. Mol. Spectrosc., 1962, 8(1):315-327
       

    12. [12]

      SONG Ya-Jiao, SUN Jing, ZHU Peng, et al. Chinese J. Inorg. Chem., 2013, 29(6):1171-1175
       

    13. [13]

      Latva M, Takalo H, Mukkala V M, et al. J. Lumin., 1997, 75(2):149-169  doi: 10.1016/S0022-2313(97)00113-0

  • 加载中
    1. [1]

      Junjie Zhang ,  Yue Wang ,  Qiuhan Wu ,  Ruquan Shen ,  Han Liu ,  Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084

    2. [2]

      Laiying Zhang ,  Yinghuan Wu ,  Yazi Yu ,  Yecheng Xu ,  Haojie Zhang ,  Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126

    3. [3]

      Bao Jia ,  Yunzhe Ke ,  Shiyue Sun ,  Dongxue Yu ,  Ying Liu ,  Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121

    4. [4]

      Geyang Song ,  Dong Xue ,  Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030

    5. [5]

      Yanhui Zhong ,  Ran Wang ,  Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017

    6. [6]

      You Wu ,  Chang Cheng ,  Kezhen Qi ,  Bei Cheng ,  Jianjun Zhang ,  Jiaguo Yu ,  Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    7. [7]

      Ling Liu ,  Haibin Wang ,  Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080

    8. [8]

      Qi Wang ,  Yicong Gao ,  Feng Lu ,  Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141

    9. [9]

      Shihui Shi ,  Haoyu Li ,  Shaojie Han ,  Yifan Yao ,  Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002

    10. [10]

      Yingxian Wang ,  Tianye Su ,  Limiao Shen ,  Jinping Gao ,  Qinghe Wu . Introduction of Chinese Lacquer from the Perspective of Chemistry: Popularizing Chemistry in Lacquer and Inherit Lacquer Art. University Chemistry, 2024, 39(5): 371-379. doi: 10.3866/PKU.DXHX202312015

    11. [11]

      Daojuan Cheng ,  Fang Fang . Exploration and Implementation of Science-Education Integration in Organic Chemistry Teaching for Pharmacy Majors: A Case Study on Nucleophilic Substitution Reactions of Alkyl Halides. University Chemistry, 2024, 39(11): 72-78. doi: 10.12461/PKU.DXHX202403105

    12. [12]

      Tingyu Zhu ,  Hui Zhang ,  Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011

    13. [13]

      Jiakun BAI , Ting XU , Lu ZHANG , Jiang PENG , Yuqiang LI , Junhui JIA . A red-emitting fluorescent probe with a large Stokes shift for selective detection of hypochlorous acid. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1095-1104. doi: 10.11862/CJIC.20240002

    14. [14]

      Jinlong YAN , Weina WU , Yuan WANG . A simple Schiff base probe for the fluorescent turn-on detection of hypochlorite and its biological imaging application. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1653-1660. doi: 10.11862/CJIC.20240154

    15. [15]

      Jin Tong ,  Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113

    16. [16]

      Yong Shu ,  Xing Chen ,  Sai Duan ,  Rongzhen Liao . How to Determine the Equilibrium Bond Distance of Homonuclear Diatomic Molecules: A Case Study of H2. University Chemistry, 2024, 39(7): 386-393. doi: 10.3866/PKU.DXHX202310102

    17. [17]

      Yiling Wu ,  Peiyao Jin ,  Shenyue Tian ,  Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034

    18. [18]

      Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440

    19. [19]

      Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

    20. [20]

      Wenyan Dan ,  Weijie Li ,  Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060

Get Citation
PDF
XML
Metrics
  • PDF Downloads(6)
  • Abstract views(1204)
  • HTML views(231)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return