Citation: LIANG Zhi-Wen, CHEN Xiao-Rou, YU Hui, WEI Zhen-Hong, ZHANG Xiu-Xiu, CAI Hu. Influences of cis-, trans-1, 2-Cyclohexanediamine Configurations on Iodoantimonate Organic-Inorganic Hybrid Isomers[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 337-343. doi: 10.11862/CJIC.2019.027 shu

Influences of cis-, trans-1, 2-Cyclohexanediamine Configurations on Iodoantimonate Organic-Inorganic Hybrid Isomers

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: WEI Zhen-Hong, weizh@ncu.edu.cn
Received Date: 7 August 2018
Revised Date: 28 November 2018

Figures(8)

Reactions of cis-and trans-1, 2-cyclohexanediamine (DAC) with antimony iodide in concentrated HI aqueous solution afforded two organic-inorganic hybrid isomers (cis-1, 2-DACH₂)[SbI₅]·H₂O (1) and {(trans-1, 2-DACH₂)[SbI₅]·H₂O}_n (2), respectively. The single-crystal X-ray diffraction revealed that the inorganic component in compound 1 is a dimer[Sb₂I₁₀] built up from two[SbI₆] octahedra by sharing I-I edge, and that in compound 2 is a zigzag chain constructed with corner-sharing octahedral[SbI₆] units. In addition, both compounds have been investigated and compared by UV-Vis, fluorescent spectra, and DFT calculation.
- 1, 2-cyclohexanediamine,
- antimony iodide,
- cis-and trans-configuration,
- organic-inorganic hybrid,
- crystal structure
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