Citation: PAN Xun, KUANG Xiao-Nan, ZHU Ning, REN Zhi-Gang, YANG Yu-Ping, XIN Xiu-Lan, LI Zhong-Feng, HAN Hong-Liang, JIN Qiong-Hua. Syntheses, Spectroscopic Properties and THz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on N-Donor and P-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 361-368. doi: 10.11862/CJIC.2019.026 shu

Syntheses, Spectroscopic Properties and THz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on N-Donor and P-Donor Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 26 October 2018
Revised Date: 23 November 2018

Figures(8)

Two novel copper(Ⅰ) complexes[Cu(bdppmapy)(2, 2'-bipy)]BF₄ (1) and[Cu(bdppmapy)(2, 2'-bipy)]I (2) (2, 2'-bipy=2, 2'-bipyridine, bdppmapy=N, N-bis((diphenylphosphino)methyl)-2-pyridinamine) have been synthesized in mixed solvents of CH₃OH and CH₂Cl₂ (1:1, V/V) and characterized by single-crystal X-ray diffraction, elemental analysis, IR, ¹H NMR and ³¹P NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). Complex 1, a mononuclear complex, was generated by the reaction of[Cu(CH₃CN)₄]BF₄ and bdppmapy with 2, 2'-bipy in 1:1:1 molar ratio. In complex 1, the central Cu(Ⅰ) forms a distorted tetrahedral geometry by coordinating with the diphosphine ligand (bdppmapy) and chelating N-donor ligand (2, 2'-bipy). Like 1, 2 was obtained by the reaction of CuI and bdppmapy with 2, 2'-bipy in 1:1:1 molar ratio. In the asymmetric unit of 2, the bdppmapy and 2, 2'-bipy ligands chelate central Cu(Ⅰ), respectively. The luminescent spectra show that the emission mechanism is metal-to-ligand charge transfer (MLCT). The application of terahertz time-domain spectroscopy also provides useful information for the research of complexes.
- copper(Ⅰ) complex,
- fluorescence,
- terahertz spectra,
- 2, 2'-bipyridine,
- N, N-bis((diphenylphosphino)methyl)-2-pyridinamine
1. [1]
  McMillin D R, McNett K M. Chem. Rev., 1998, 98:1201-1219 doi: 10.1021/cr9601167
2. [2]
  Xin X L, Chen M, Ai Y B, et al. Inorg. Chem., 2014, 53:2922-2931 doi: 10.1021/ic402685u
3. [3]
  He L H, Luo Y S, Di B S, et al. Inorg. Chem., 2017, 56:10311-10324 doi: 10.1021/acs.inorgchem.7b01159
4. [4]
  Daichi K, Michihiro N, Yasuo F, et al. Dalton Trans., 2017, 46:14804-14811 doi: 10.1039/C7DT02938A
5. [5]
  Eunjin K, Jineun K, Kang Y L, et al. Inorg. Chem., 2017, 56:943-949 doi: 10.1021/acs.inorgchem.6b02571
6. [6]
  Chen J L, Zeng X H, Luo Y S, et al. Dalton Trans., 2017, 46:13077-13087 doi: 10.1039/C7DT02848B
7. [7]
  Pablo A, Cristian V, Dayra E, et al. Dalton Trans., 2017, 46:13432-13445 doi: 10.1039/C7DT02244A
8. [8]
  Jintoku H, Ihara H, Matsuzawa Y, et al. Chem. Eur. J., 2017, 23:16961-16965 doi: 10.1002/chem.201704154
9. [9]
  Evans O R, Lin W. Acc. Chem. Res., 2002, 35:511-522 doi: 10.1021/ar0001012
10. [10]
  Raman N, Selvan A. J. Mol. Struct., 2011, 985:173-183 doi: 10.1016/j.molstruc.2010.10.038
11. [11]
  Krylova V A, Djurovich P I, Whited M T, et al. Chem. Commun., 2010, 46:6696-6698 doi: 10.1039/c0cc01864c
12. [12]
  Mara M W, Fransted K A, Chen L X, et al. Coord. Chem. Rev., 2015:2-18, 282-283
13. [13]
  Mjos K D, Orvig C. Chem. Rev., 2014, 114:4540-4563 doi: 10.1021/cr400460s
14. [14]
  Cui Y Z, Yuan Y, Han H L, et al. Z. Anorg. Allg. Chem., 2016, 642(18):953-959 doi: 10.1002/zaac.201600193
15. [15]
  Huang X, Li Z F, Jin Q H, et al. Polyhedron, 2013, 65:129-135 doi: 10.1016/j.poly.2013.08.018
16. [16]
  Zhang Y R, Cui Y Z, Jin Q H, et al. Polyhedron, 2017, 122:86-98 doi: 10.1016/j.poly.2016.10.033
17. [17]
  ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2015, 31(10):2089-2094
18. [18]
  WANG Yu, CUI Yang-Zhe, LIU Min, et al. Chinese J. Inorg. Chem., 2018, 34(2):381-386
19. [19]
  Yang J H, Wu X Y, Ren Z G, et al. Cryst. Growth Des., 2013, 13:2124-2134 doi: 10.1021/cg4002048
20. [20]
  Zhang J F, Gan X, Fu W F, et al. Inorg. Chim. Acta, 2010, 363:338-345 doi: 10.1016/j.ica.2009.10.021
21. [21]
  Xu S, Liu M, Yang Y P, et al. Polyhedron, 2015, 87:293-301 doi: 10.1016/j.poly.2014.11.022
22. [22]
  Zhang L L, Zhong H, Deng C, et al. Appl. Phys. Lett., 2009, 94:211106 doi: 10.1063/1.3143613
23. [23]
  Sheldrick G M. SHELXTL NT Ver.5.1, University of Göttingen, Germany, 1997.
24. [24]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Madison, WI, USA, 1997.
25. [25]
  Niu J Y, Zhang S W, Chen H N, et al. Cryst. Growth Des., 2011, 11:3769-3777 doi: 10.1021/cg2001249
26. [26]
  John S F, Raymond J H, Campbell J P, et al. Polyhedron, 1993, 12:2425-2428 doi: 10.1016/S0277-5387(00)83064-8
27. [27]
  LIN Sen, LI Yue, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2016, 32(12):2165-2171
1. [1]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
2. [2]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
3. [3]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
4. [4]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
5. [5]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
6. [6]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
7. [7]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
8. [8]
  Le Ye , Wei-Xiong Zhang . Structural phase transition in a new organic-inorganic hybrid post-perovskite: (N,N-dimethylpyrrolidinium)[Mn(N(CN)2)3]. Chinese Journal of Structural Chemistry, 2024, 43(6): 100257-100257. doi: 10.1016/j.cjsc.2024.100257
9. [9]
  Hai-Yang Song , Jun Jiang , Yu-Hang Song , Min-Hang Zhou , Chao Wu , Xiang Chen , Wei-Min He . Supporting-electrolyte-free electrochemical [2 + 2 + 1] annulation of benzo[d]isothiazole 1,1-dioxides, N-arylglycines and paraformaldehyde. Chinese Chemical Letters, 2024, 35(6): 109246-. doi: 10.1016/j.cclet.2023.109246
10. [10]
  Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM₂@g-C₉N₄ electrocatalysts for enhanced CO reduction toward C₂ products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
11. [11]
  Kunyao Peng , Xianbin Wang , Xingbin Yan . Converting LiNO₃ additive to single nitrogenous component Li₂N₂O₂ SEI layer on Li metal anode in carbonate-based electrolyte. Chinese Chemical Letters, 2024, 35(9): 109274-. doi: 10.1016/j.cclet.2023.109274
12. [12]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
13. [13]
  Tong Li , Leping Pan , Yan Zhang , Jihu Su , Kai Li , Kuiliang Li , Hu Chen , Qi Sun , Zhiyong Wang . Electrochemical construction of 2,5-diaryloxazoles via N–H and C(sp³)-H functionalization. Chinese Chemical Letters, 2024, 35(4): 108897-. doi: 10.1016/j.cclet.2023.108897
14. [14]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
15. [15]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
16. [16]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
17. [17]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
18. [18]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
19. [19]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
20. [20]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(542)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142