Citation: PAN Xun, KUANG Xiao-Nan, ZHU Ning, REN Zhi-Gang, YANG Yu-Ping, XIN Xiu-Lan, LI Zhong-Feng, HAN Hong-Liang, JIN Qiong-Hua. Syntheses, Spectroscopic Properties and THz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on N-Donor and P-Donor Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 361-368. doi: 10.11862/CJIC.2019.026 shu

Syntheses, Spectroscopic Properties and THz Time Domain Spectroscopy of Two Copper(Ⅰ) Complexes Based on N-Donor and P-Donor Ligands

1.
Department of Chemistry, Capital Normal University, Beijing 100048, China
2.
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu 215123, China
3.
School of Science, Minzu University of China, Beijing 100081, China
4.
School of Food and Chemical Engineering, Beijing Technology and Business University, Beijing 100048, China

Corresponding author: JIN Qiong-Hua, jinqh@cnu.edu.cn
Received Date: 26 October 2018
Revised Date: 23 November 2018

Figures(8)

Two novel copper(Ⅰ) complexes[Cu(bdppmapy)(2, 2'-bipy)]BF₄ (1) and[Cu(bdppmapy)(2, 2'-bipy)]I (2) (2, 2'-bipy=2, 2'-bipyridine, bdppmapy=N, N-bis((diphenylphosphino)methyl)-2-pyridinamine) have been synthesized in mixed solvents of CH₃OH and CH₂Cl₂ (1:1, V/V) and characterized by single-crystal X-ray diffraction, elemental analysis, IR, ¹H NMR and ³¹P NMR spectroscopy, fluorescence spectra and THz time domain spectroscopy (THz-TDS). Complex 1, a mononuclear complex, was generated by the reaction of[Cu(CH₃CN)₄]BF₄ and bdppmapy with 2, 2'-bipy in 1:1:1 molar ratio. In complex 1, the central Cu(Ⅰ) forms a distorted tetrahedral geometry by coordinating with the diphosphine ligand (bdppmapy) and chelating N-donor ligand (2, 2'-bipy). Like 1, 2 was obtained by the reaction of CuI and bdppmapy with 2, 2'-bipy in 1:1:1 molar ratio. In the asymmetric unit of 2, the bdppmapy and 2, 2'-bipy ligands chelate central Cu(Ⅰ), respectively. The luminescent spectra show that the emission mechanism is metal-to-ligand charge transfer (MLCT). The application of terahertz time-domain spectroscopy also provides useful information for the research of complexes.
- copper(Ⅰ) complex,
- fluorescence,
- terahertz spectra,
- 2, 2'-bipyridine,
- N, N-bis((diphenylphosphino)methyl)-2-pyridinamine
1. [1]
  McMillin D R, McNett K M. Chem. Rev., 1998, 98:1201-1219 doi: 10.1021/cr9601167
2. [2]
  Xin X L, Chen M, Ai Y B, et al. Inorg. Chem., 2014, 53:2922-2931 doi: 10.1021/ic402685u
3. [3]
  He L H, Luo Y S, Di B S, et al. Inorg. Chem., 2017, 56:10311-10324 doi: 10.1021/acs.inorgchem.7b01159
4. [4]
  Daichi K, Michihiro N, Yasuo F, et al. Dalton Trans., 2017, 46:14804-14811 doi: 10.1039/C7DT02938A
5. [5]
  Eunjin K, Jineun K, Kang Y L, et al. Inorg. Chem., 2017, 56:943-949 doi: 10.1021/acs.inorgchem.6b02571
6. [6]
  Chen J L, Zeng X H, Luo Y S, et al. Dalton Trans., 2017, 46:13077-13087 doi: 10.1039/C7DT02848B
7. [7]
  Pablo A, Cristian V, Dayra E, et al. Dalton Trans., 2017, 46:13432-13445 doi: 10.1039/C7DT02244A
8. [8]
  Jintoku H, Ihara H, Matsuzawa Y, et al. Chem. Eur. J., 2017, 23:16961-16965 doi: 10.1002/chem.201704154
9. [9]
  Evans O R, Lin W. Acc. Chem. Res., 2002, 35:511-522 doi: 10.1021/ar0001012
10. [10]
  Raman N, Selvan A. J. Mol. Struct., 2011, 985:173-183 doi: 10.1016/j.molstruc.2010.10.038
11. [11]
  Krylova V A, Djurovich P I, Whited M T, et al. Chem. Commun., 2010, 46:6696-6698 doi: 10.1039/c0cc01864c
12. [12]
  Mara M W, Fransted K A, Chen L X, et al. Coord. Chem. Rev., 2015:2-18, 282-283
13. [13]
  Mjos K D, Orvig C. Chem. Rev., 2014, 114:4540-4563 doi: 10.1021/cr400460s
14. [14]
  Cui Y Z, Yuan Y, Han H L, et al. Z. Anorg. Allg. Chem., 2016, 642(18):953-959 doi: 10.1002/zaac.201600193
15. [15]
  Huang X, Li Z F, Jin Q H, et al. Polyhedron, 2013, 65:129-135 doi: 10.1016/j.poly.2013.08.018
16. [16]
  Zhang Y R, Cui Y Z, Jin Q H, et al. Polyhedron, 2017, 122:86-98 doi: 10.1016/j.poly.2016.10.033
17. [17]
  ZHANG Yan-Ru, WANG Meng-Qin, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2015, 31(10):2089-2094
18. [18]
  WANG Yu, CUI Yang-Zhe, LIU Min, et al. Chinese J. Inorg. Chem., 2018, 34(2):381-386
19. [19]
  Yang J H, Wu X Y, Ren Z G, et al. Cryst. Growth Des., 2013, 13:2124-2134 doi: 10.1021/cg4002048
20. [20]
  Zhang J F, Gan X, Fu W F, et al. Inorg. Chim. Acta, 2010, 363:338-345 doi: 10.1016/j.ica.2009.10.021
21. [21]
  Xu S, Liu M, Yang Y P, et al. Polyhedron, 2015, 87:293-301 doi: 10.1016/j.poly.2014.11.022
22. [22]
  Zhang L L, Zhong H, Deng C, et al. Appl. Phys. Lett., 2009, 94:211106 doi: 10.1063/1.3143613
23. [23]
  Sheldrick G M. SHELXTL NT Ver.5.1, University of Göttingen, Germany, 1997.
24. [24]
  Sheldrick G M. SHELXS-97 and SHELXL-97, Madison, WI, USA, 1997.
25. [25]
  Niu J Y, Zhang S W, Chen H N, et al. Cryst. Growth Des., 2011, 11:3769-3777 doi: 10.1021/cg2001249
26. [26]
  John S F, Raymond J H, Campbell J P, et al. Polyhedron, 1993, 12:2425-2428 doi: 10.1016/S0277-5387(00)83064-8
27. [27]
  LIN Sen, LI Yue, CUI Yang-Zhe, et al. Chinese J. Inorg. Chem., 2016, 32(12):2165-2171
1. [1]
  Gaofeng WANG , Shuwen SUN , Lixin Meng , Dequn PENG . Syntheses and fluorescent sensing properties of two coordination polymers based on 9, 9′-dihexyl-2, 7-di(pyridin-4-yl)fluorene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 331-339. doi: 10.11862/CJIC.20250260
2. [2]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
3. [3]
  Dongdong YANG , Jianhua XUE , Yuanyu YANG , Meixia WU , Yujia BAI , Zongxuan WANG , Qi MA . Design and synthesis of two coordination polymers for the rapid detection of ciprofloxacin based on triphenylpolycarboxylic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2466-2474. doi: 10.11862/CJIC.20240266
4. [4]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
5. [5]
  Yuanyu YANG , Jianhua XUE , Yujia BAI , Lulu CUI , Dongdong YANG , Qi MA . Design, synthesis, and detection of Al³⁺ of two zinc complexes based on Schiff base ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1207-1216. doi: 10.11862/CJIC.20250005
6. [6]
  Youbo HU , Donggang LI , Changhua SUN , Zhenzhong LU , Songjun GU . Coordination polymers based on anthracene- and pyrene-derived ligands: Crystal structure, fluorescent property, and framework isomerization. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1681-1688. doi: 10.11862/CJIC.20250004
7. [7]
  Yue Li , Qianyu Ding , Wansheng Liu , Yimeng Sun , Liyao Liu , Ye Zou , Yutao Cui , Jia Zhu , Chongan Di , Daoben Zhu . Bipyridine-bridged Φ-shaped cyclo[8]thiophene[2]pyrrole: Synthesis and fluorescence properties. Chinese Chemical Letters, 2026, 37(2): 111989-. doi: 10.1016/j.cclet.2025.111989
8. [8]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
9. [9]
  Xuehua SUN , Min MA , Jianting LIU , Rui TIAN , Hongmei CHAI , Huali CUI , Loujun GAO . Pr/N co-doped biomass carbon dots with enhanced fluorescence for efficient detection of 2,4-dinitrophenylhydrazine. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 561-573. doi: 10.11862/CJIC.20240294
10. [10]
  Shuai Liu , Wen Wu , Peili Zhang , Yunxuan Ding , Chang Liu , Yu Shan , Ke Fan , Fusheng Li . Mechanistic insights into acidic water oxidation by Mn(2,2′-bipyridine-6,6′-dicarboxylate)-based hydrogen-bonded organic frameworks. Chinese Journal of Structural Chemistry, 2025, 44(3): 100535-100535. doi: 10.1016/j.cjsc.2025.100535
11. [11]
  Kangmin Wang , Liqiu Wan , Jingyu Wang , Chunlin Zhou , Ke Yang , Liang Zhou , Bijin Li . Multifunctional 2-(2′-hydroxyphenyl)benzoxazoles: Ready synthesis, mechanochromism, fluorescence imaging, and OLEDs. Chinese Chemical Letters, 2024, 35(10): 109554-. doi: 10.1016/j.cclet.2024.109554
12. [12]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
13. [13]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2124-2132. doi: 10.11862/CJIC.20240158
14. [14]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
15. [15]
  Chen LU , Qinlong HONG , Haixia ZHANG , Jian ZHANG . Syntheses, structures, and properties of copper-iodine cluster-based boron imidazolate framework materials. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 149-154. doi: 10.11862/CJIC.20240407
16. [16]
  Linfang ZHANG , Wenzhu YIN , Gui YIN . A 2-dicyanomethylene-3-cyano-4,5,5-trimethyl-2,5-dihydrofuran-based near-infrared fluorescence probe for the detection of hydrogen sulfide and imaging of living cells. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 540-548. doi: 10.11862/CJIC.20240405
17. [17]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
18. [18]
  Hanqing Zhang , Xiaoxia Wang , Chen Chen , Xianfeng Yang , Chungli Dong , Yucheng Huang , Xiaoliang Zhao , Dongjiang Yang . Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chinese Journal of Structural Chemistry, 2023, 42(10): 100089-100089. doi: 10.1016/j.cjsc.2023.100089
19. [19]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
20. [20]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(1021)
HTML views(89)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142