Citation: ZHANG Xin, SHEN Zheng-Yang, JIAN Ni, YAO Jian-Hua, GAO Ming-Xia, PAN Hong-Ge, LIU Yong-Feng. Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 101-108. doi: 10.11862/CJIC.2019.025 shu

Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂

1.
Institute of Laser Advanced Manufacturing, Zhejiang University of Technology, Collaborative Innovation Center of High-end Laser Manufacturing Equipment, Hangzhou 310014, China
2.
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: LIU Yong-Feng, mselyf@zju.edu.cn
Received Date: 11 October 2018
Revised Date: 25 November 2018

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A solid-solution MAX phase (Ti_0.5V_0.5)₃AlC₂ was successfully synthesized with a pressureless sintering method, and its catalytic effect on hydrogen storage reaction of MgH₂ was systematically investigated. The solid solution MAX phase (Ti_0.5V_0.5)₃AlC₂ exhibited superior catalytic activity, thanks to the synergistic catalysis effect of Ti and V. The on-set dehydrogenation temperature of MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ samples was only 230℃ (mass fraction of (Ti_0.5V_0.5)₃AlC₂ was 10%), which was 60℃ lower than that of pristine MgH₂. The desorption rate of MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample at 217℃ was calculated to be 0.35%·min^-1, which was 4 times faster than that of the pristine sample. At 150℃, the dehydrogenated MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample absorbs 4.7% of H₂ within 60 s under 5 MPa H₂. The apparent activation energy of the MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample was determined to be 79.6 kJ·mol^-1, representing a 48% reduction in the reaction barrier, compared with pristine MgH₂ (153.8 kJ·mol^-1). This reasonably explains the significant improvement in dehydrogenation performance.
- hydrogen storage materials,
- metal hydride,
- MgH₂,
- catalyst doping,
- solid-solution MAX phase
1. [1]
  Chu S, Majumdar A. Nature, 2012, 488(17):294-303
2. [2]
  SHANGGUAN Wen-Feng. Chinese J. Inorg. Chem., 2001, 17(9):619-626
3. [3]
  Zhang X B, Chai Y J, Yin W Y, et al. J. Rare Earths, 2003, 21(S1):162-164
4. [4]
  ZHANG Xin-Bo, ZHAO Min-Shou. Chem. J. Chinese Universities, 2003, 24(9):1680-1682 doi: 10.3321/j.issn:0251-0790.2003.09.045
5. [5]
  Zhang X B, Sun Z D, Yin W Y, et al. ChemPhysChem, 2005, 6(3):520-525 doi: 10.1002/(ISSN)1439-7641
6. [6]
  Zhang X B, Sun Z D, Yin W Y, et al. Electrochim. Acta, 2005, 50(9):1957-1964 doi: 10.1016/j.electacta.2004.09.016
7. [7]
  Zhang X B, Sun Z D, Yin W Y, et al. Electrochim. Acta, 2005, 50(14):2911-2918 doi: 10.1016/j.electacta.2004.11.039
8. [8]
  QIAO Yu-Qing, ZHAO Min-Shou, ZHU Xin-Jian, et al. Journal of Functional Materials, 2005, 36(12):1875-1878 doi: 10.3321/j.issn:1001-9731.2005.12.019
9. [9]
  LIU Yang, LI Yuan-Yuan, PENG Dan-Dan, et al. Chinese J. Inorg. Chem., 2017, 33(12):1875-1878
10. [10]
  Liu Y F, Yang Y X, Gao M X, et al. Chem. Rec., 2016, 16(1):189-204 doi: 10.1002/tcr.v16.1
11. [11]
  Crivello J C, Dam B, Denys R V, et al. Appl. Phys. A, 2016, 122(2):97-117 doi: 10.1007/s00339-016-9602-0
12. [12]
  Jain I P, Lal C. Int. J. Hydrogen Energy, 2010, 35(10):5133-5144 doi: 10.1016/j.ijhydene.2009.08.088
13. [13]
  Puszkiel J A, Riglos M V C, Ramallo-López J M, et al. J. Mater. Chem. A, 2017, 5(25):12922-12933 doi: 10.1039/C7TA03117C
14. [14]
  Puszkiel J A, Larochette P A, Gennari F C. J. Power Sources, 2009, 186(1):185-193 doi: 10.1016/j.jpowsour.2008.09.101
15. [15]
  Vajo J J. J. Phys. Chem. B, 2004, 108(37):13977-13983 doi: 10.1021/jp040060h
16. [16]
  Xia G L, Tan Y, Chen X, et al. Adv. Mater., 2015, 27(39):5981-5988 doi: 10.1002/adma.201502005
17. [17]
  Peng D D, Ding Z M, Zhang L, et al. Int. J. Hydrogen Energy, 2018, 43(7):3731-3740 doi: 10.1016/j.ijhydene.2018.01.004
18. [18]
  Au Y S, Obbink M K, Srinivasan S, et al. Adv. Funct. Mater., 2014, 24(23):3604-3611 doi: 10.1002/adfm.201304060
19. [19]
  Rather S, Taimoor A A, Muhammad A, et al. Mater. Res. Bull., 2016, 77:23-28 doi: 10.1016/j.materresbull.2016.01.025
20. [20]
  Xie X B, Chen M, Liu P, et al. J. Power Sources, 2017, 371(15):112-118
21. [21]
  Mustafa N S, Ismail M. J. Alloys Compd., 2017, 695(25):2532-2538
22. [22]
  Chakrabarti S, Biswas K. Int. J. Hydrogen Energy, 2017, 42(2):1012-1017 doi: 10.1016/j.ijhydene.2016.08.152
23. [23]
  Soni P K, Bhatnagar A, Shaz M A, et al. Int. J. Hydrogen Energy, 2017, 42(31):20026-20035
24. [24]
  Hanada N, Ichikawa T, Hino S, et al. J. Alloys Compd., 2006, 420(1/2):46-49
25. [25]
  Liang G, Huot J, Boily S, et al. J. Alloys Compd., 1999, 292(1/2):247-252
26. [26]
  Cui J, Wang H, Liu J W, et al. J. Mater. Chem. A, 2013, 1(18):5603-5611 doi: 10.1039/c3ta01332d
27. [27]
  Wang Y, Zhang Q, Wang Y, et al. J. Alloys Compd., 2015, 645(1):S509-S512
28. [28]
  Liu Y F, Du H F, Zhang X, et al. Chem. Commun., 2016, 52(4):705-708 doi: 10.1039/C5CC08801A
29. [29]
  Wang K, Du H, Wang Z, et al. Int. J. Hydrogen Energy, 2017, 42(7):4244-4251 doi: 10.1016/j.ijhydene.2016.10.073
30. [30]
  Malka I E, Czujko T, Bystrzycki J. Int. J. Hydrogen Energy, 2010, 35(4):1706-1712 doi: 10.1016/j.ijhydene.2009.12.024
31. [31]
  Oelerich W, Klassen T, Bormann R. J. Alloys Compd., 2001, 315(1/2):237-242
32. [32]
  Wang Z Y, Ren Z H, Jian N, et al. J. Mater. Chem. A, 2018, 6(33):16177-16185 doi: 10.1039/C8TA05437A
33. [33]
  Jia Y, Cheng L N, Pan N, et al. Adv. Energy Mater., 2011, 1(3):387-393 doi: 10.1002/aenm.v1.3
34. [34]
  Naguib M, Bentzel G W, Shah J, et al. Mater. Res. Lett., 2014, 2(3):233-240
35. [35]
  Kissinger H E. Anal. Chem., 1957, 29(11):1702-1706 doi: 10.1021/ac60131a045
36. [36]
  Huot J, Liang G, Boily S, et al. J. Alloys Compd., 1999, 293-295:495-500 doi: 10.1016/S0925-8388(99)00474-0
37. [37]
  Chen G, Zhang Y, Chen J, et al. Nanotechnology, 2018, 29(26):265705 doi: 10.1088/1361-6528/aabcf3
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Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂