Citation: ZHANG Xin, SHEN Zheng-Yang, JIAN Ni, YAO Jian-Hua, GAO Ming-Xia, PAN Hong-Ge, LIU Yong-Feng. Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 101-108. doi: 10.11862/CJIC.2019.025 shu

Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂

1.
Institute of Laser Advanced Manufacturing, Zhejiang University of Technology, Collaborative Innovation Center of High-end Laser Manufacturing Equipment, Hangzhou 310014, China
2.
State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: LIU Yong-Feng, mselyf@zju.edu.cn
Received Date: 11 October 2018
Revised Date: 25 November 2018

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A solid-solution MAX phase (Ti_0.5V_0.5)₃AlC₂ was successfully synthesized with a pressureless sintering method, and its catalytic effect on hydrogen storage reaction of MgH₂ was systematically investigated. The solid solution MAX phase (Ti_0.5V_0.5)₃AlC₂ exhibited superior catalytic activity, thanks to the synergistic catalysis effect of Ti and V. The on-set dehydrogenation temperature of MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ samples was only 230℃ (mass fraction of (Ti_0.5V_0.5)₃AlC₂ was 10%), which was 60℃ lower than that of pristine MgH₂. The desorption rate of MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample at 217℃ was calculated to be 0.35%·min^-1, which was 4 times faster than that of the pristine sample. At 150℃, the dehydrogenated MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample absorbs 4.7% of H₂ within 60 s under 5 MPa H₂. The apparent activation energy of the MgH₂-10%(Ti_0.5V_0.5)₃AlC₂ sample was determined to be 79.6 kJ·mol^-1, representing a 48% reduction in the reaction barrier, compared with pristine MgH₂ (153.8 kJ·mol^-1). This reasonably explains the significant improvement in dehydrogenation performance.
- hydrogen storage materials,
- metal hydride,
- MgH₂,
- catalyst doping,
- solid-solution MAX phase
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Synthesis and Catalytic Effects of Solid-Solution MAX-phase (Ti_0.5V_0.5)₃AlC₂ on Hydrogen Storage Performance of MgH₂