Citation: WANG Peng, LI Zhao, ZHOU Ying-Mei, XU Yan, ZHU Jie, WANG Shi-Fan, CAI Ke-Ying, LI Jing, DU Xi-Hua, YANG Peng-Ju. Synthesis of Carbon Nanotubes Modified g-C₃N₄ Photocatalysts for Enhanced Photocatalytic Degradation Activity[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 217-224. doi: 10.11862/CJIC.2019.022 shu

Synthesis of Carbon Nanotubes Modified g-C₃N₄ Photocatalysts for Enhanced Photocatalytic Degradation Activity

WANG Peng ¹ ,
LI Zhao ^1,2 ,
ZHOU Ying-Mei ¹ ,
XU Yan ¹ ,
ZHU Jie ¹ ,
WANG Shi-Fan ¹ ,
CAI Ke-Ying ¹ ,
LI Jing ¹ ,
DU Xi-Hua ¹ ,
YANG Peng-Ju ^3,,

1.
School of Chemistry and Chemical Engineering, Xuzhou Institute of Technology, Xuzhou, Jiangsu 221018, China
2.
School of Chemical Engineering & Technology, China University of Mining and Technology, Xuzhou, Jiangsu 221116, China
3.
State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, China

Corresponding author: YANG Peng-Ju, yangpengju10@mails.ucas.ac.cn
Received Date: 16 September 2018
Revised Date: 21 November 2018

Figures(13)

Graphitic carbon nitride hybridized with a small number of carbon nanotubes (CNT) was synthesized using urea as precursor. The resulting CNT/g-C₃N₄ composite photocatalysts were characterized by scanning electron microscope (SEM), transmission electron microscope (TEM), Fourier infrared spectrometer (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible-near infrared Reflection Spectrophotometer (UV-Vis-NIR Spectrophotometer) and photoluminescence spectroscopy (PL). Results indicate that the synergistic interaction between CNT and g-C₃N₄ changed the optical properties of bulk g-C₃N₄, affected the energy band structure, enhanced the absorption of visible light, optimized the distribution of the photogenerated carrier and improved the electron-hole separation rate. The photocatalytic degradation of rhodamine B solution (RhB) was performed under visible light irradiation. The photocatalytic activity of CNT/g-C₃N₄ composite was the highest when 0.1%(w/w) CNT was loaded on the substrate, the rate constant for the photocatalyst was 3.1 times as high as that of pure g-C₃N₄. It was also found that the superoxide radical was the main active species for catalytic degradation in this system.
- photocatalysis,
- graphitic carbon nitride,
- carbon nanotubes,
- visible light
1. [1]
  Zheng Y, Lin L H, Ye X J. et al. Angew. Chem. Int. Ed., 2014, 53:11926-11930 doi: 10.1002/anie.201407319
2. [2]
  Zhang J S, Zhang M W, Yang C. et al. Adv. Mater., 2014, 26:4121-4126 doi: 10.1002/adma.v26.24
3. [3]
  Chen K, Chai Z G, Li C, et al. ACS Nano, 2016, 10:3665-3673 doi: 10.1021/acsnano.6b00113
4. [4]
  Wang X C, Maeda K, Thomas A, et al. Nat. Mater., 2009, 8:76-80 doi: 10.1038/nmat2317
5. [5]
  Xia J X, Ji M X, Di J, et al. Appl. Catal. B, 2016, 191:235-245 doi: 10.1016/j.apcatb.2016.02.058
6. [6]
  Yang P J, Ou H H, Fang Y X, et al. Angew. Chem. Int. Ed., 2017, 56:3992-3996 doi: 10.1002/anie.201700286
7. [7]
  Shi L, Wang T, Zhang H B, et al. Adv. Funct. Mater., 2015, 25:5360-5367 doi: 10.1002/adfm.201502253
8. [8]
  Yang P J, Wang R R, Zhou M, et al. Angew. Chem. Int. Ed., 2018, 57:8674-8677 doi: 10.1002/anie.v57.28
9. [9]
  Lang X J, Chen X D, Zhao J C. Chem. Soc. Rev., 2014, 43:473-486 doi: 10.1039/C3CS60188A
10. [10]
  Xiao J D, Xie Y B, Nawaz F, et al. Appl. Catal. B, 2016, 183:417-425 doi: 10.1016/j.apcatb.2015.11.010
11. [11]
  Deng D H, Yu L, Chen X Q, et al. Angew. Chem. Int. Ed., 2013, 125:389-393 doi: 10.1002/ange.201204958
12. [12]
  Tu W G, Zhou Y, Zou Z G. Adv. Funct. Mater., 2013, 23:4996-5008 doi: 10.1002/adfm.v23.40
13. [13]
  Chen Y L, Li J H, Hong Z H, et al. Phys. Chem. Chem. Phys., 2014, 16:8106-8113 doi: 10.1039/c3cp55191a
14. [14]
  Ge L, Han C C. Appl. Catal. B, 2012, 117:268-274
15. [15]
  Zhao S, Guo T, Li X. et al. Appl. Catal. B, 2018, 224:725-732 doi: 10.1016/j.apcatb.2017.11.005
16. [16]
  Chew L M, Xia W, Dudder H, et al. Catal. Today, 2016, 270:85-92 doi: 10.1016/j.cattod.2015.09.023
17. [17]
  Wang P, Chen S Y, Bai Y X, et al. Fuel, 2017, 195:69-81 doi: 10.1016/j.fuel.2017.01.050
18. [18]
  LIU Chong, LIU Li-Lai, NIE Jia-Hui. Chem. J. Chinese Universities, 2018, 39(7):1511-1517
19. [19]
  ZHANG Hua-Sen, LI Xi-Bao, FENG Zhi-Jun, et al. Journal of the Chinese Ceramic Society, 2018, 46(2):281-287
20. [20]
  Sun N, Liang Y, Ma X J, et al. Chem.-Eur. J., 2017, 23:15466-15473 doi: 10.1002/chem.v23.61
21. [21]
  Gao J T, Wang Y, Zhou S J, et al. ChemCatChem, 2017, 9:1708-1715 doi: 10.1002/cctc.201700492
22. [22]
  Luo L, Zhang A, Janik M K, et al. Appl. Surf. Sci., 2017, 396:78-84 doi: 10.1016/j.apsusc.2016.10.190
23. [23]
  Liu L Y, Xu H, Xu Y G, et al. Appl. Catal. B, 2017, 207:429-437 doi: 10.1016/j.apcatb.2017.01.071
24. [24]
  Wen J Q, Xie J, Yang Z H, et al. ACS Sustainable Chem. Eng., 2017, 5:2224-2236 doi: 10.1021/acssuschemeng.6b02490
25. [25]
  Shen T T, Lang D, Cheng F Y, et al. ChemistrySelect, 2016, 1:1006-1015 doi: 10.1002/slct.201600041
26. [26]
  Xu Q L, Zhu B C, Jiang C J. et al. Solar RRL, 2018, 2:1800006 doi: 10.1002/solr.v2.3
27. [27]
  Meng Q G, Yuan M Z, Lv H Q, et al. ChemistrySelect, 2017, 2:6970-6978 doi: 10.1002/slct.201700705
28. [28]
  Liu J, Yang H M, Liu N Y, et al. Green Chem., 2014, 16:4559-4565 doi: 10.1039/C4GC01126K
1. [1]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
4. [4]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
5. [5]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
6. [6]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
7. [7]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
8. [8]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
9. [9]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
10. [10]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
11. [11]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
14. [14]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
17. [17]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
18. [18]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
19. [19]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
20. [20]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020

Get Citation

PDF

XML

Metrics

PDF Downloads(22)
Abstract views(2974)
HTML views(648)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of Carbon Nanotubes Modified g-C3N4 Photocatalysts for Enhanced Photocatalytic Degradation Activity

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of Carbon Nanotubes Modified g-C₃N₄ Photocatalysts for Enhanced Photocatalytic Degradation Activity