Citation: ZHANG Chun-Li. Two Cd(Ⅱ)-Based Metal-Organic Frameworks for Luminescence Sensing of Metal Ions and Organic Molecules[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 165-173. doi: 10.11862/CJIC.2019.021 shu

Two Cd(Ⅱ)-Based Metal-Organic Frameworks for Luminescence Sensing of Metal Ions and Organic Molecules

ZHANG Chun-Li ^,

School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, Anhui 234000, China

Corresponding author: ZHANG Chun-Li, zhangsz1966@163.com
Received Date: 17 September 2018
Revised Date: 6 November 2018

Figures(9)

Two cadmium metal-organic frameworks, {[Cd(L)(fma)]·0.5H₂O}_n (1) and {[Cd(L)_0.5(sdb)]·DMF}_n (2) (L=E, E-2, 5-dihexyloxy-1, 4-bis-(2-pyridin-vinyl) benzene, H₂fma=fumaric acid, H₂sdb=4, 4'-sulfonyldibenzoic acid), have been hydrothermally synthesized. Their applications in luminescence sensing of metal anions and organic molecules were explored. The results show that Fe³⁺ has a significant quenching influence on the luminescence intensity of MOFs 1 and 2. In addition, MOFs 1 and 2 also show some luminescence quenching ability on salicylaldehyde.
- metal-organic framework,
- luminescence sensing,
- synthesis
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沈阳化工大学材料科学与工程学院沈阳 110142