Citation: CHEN Hao, YU Zhe-Jian, XU Dan-Dan, LI Yang, WANG Ming-Ming, XIA Liang-Min, LUO Shu-Ping. In-Situ Formed Amorphous Co Nanoparticles for Efficiently Catalytic Hydrogen Production from the Methanolysis of Ammonia Borane[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 141-148. doi: 10.11862/CJIC.2019.017 shu

In-Situ Formed Amorphous Co Nanoparticles for Efficiently Catalytic Hydrogen Production from the Methanolysis of Ammonia Borane

State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China

Corresponding author: LUO Shu-Ping, Luoshuping@zjut.edu
Received Date: 14 August 2018
Revised Date: 14 November 2018

Figures(8)

Amorphous Co nanoparticles formed in-situ displayed high catalytic activity for hydrogen generation from the methanolysis reaction of ammonia borane, among many homogeneous catalysts and heterogeneous catalysts of cobalt. Its turnover number (TON) was up to 6 000 for ten cycles and its turnover frequency (TOF) was up to 515 mol_H₂·mol_metal^-1·h^-1. Moreover, the easily preparation and the great recycling performance made it have good application in future. After the kinetics studies, its catalytic activation energy (E_a) for the methanolysis reaction was measured as 20.00 kJ·mol^-1, which was lower than most of the reported values for other nano-sized catalysts. Through the ¹¹B NMR, trimethylborate was the only product. Furthermore, the catalytic reaction mechanism was preliminarily explained and discussed.
- in-situ synthesis,
- ammonia borane,
- methanolysis,
- hydrogen generation
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