Citation: WANG Yan, CHEN Fei-Fei, HU Xiao-Shuang, ZHAO Ran, CHI Yu-Xian, JIN Jing. Syntheses, Crystal Structures and Luminescent Properties of Ag-Ln Coordination Polymers[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(2): 225-235. doi: 10.11862/CJIC.2019.014 shu

Syntheses, Crystal Structures and Luminescent Properties of Ag-Ln Coordination Polymers

School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Corresponding author: CHI Yu-Xian, yxchi@lnnu.edu.cn JIN Jing, Jinjing_crystal@126.com
Received Date: 26 September 2018
Revised Date: 24 October 2018

Figures(21)

Using pyrazine-2-carboxylic acid (2-Hpzc), 3, 5-pyridinedicarboxylic acid (3, 5-H₂PDA) and oxalic acid (H₂ox) as ligands, nine Ag-Ln coordination polymers are synthesized by hydrothermal methods:{[LnAg(2-pzc)₂(ox)]·H₂O}_n (Ln=Pr (1), Nd (2), Sm (3), Eu (4)), [LnAg(3, 5-PDA)(ox)(H₂O)]_n (Ln=Pr (5), Nd (6)), [LnAg(3, 5-PDA)(3, 5-HPDA)(ox)_0.5(H₂O)₂]_n (Ln=Sm (7), Dy (8), Ho (9)). All of them possess the 3D network structure, i.e., coordination polymers 1~4 are isomorphic and connected by 2-pzc^- and ox^2-, while coordination polymers 5~9 use 3, 5-PDA^2- and ox^2- as bridging ligands. Photophysical properties of these coordination polymers are studied, and they show characteristic emissions of corresponding Ln(Ⅲ) ions which should be attributed to the sensitization of the Ag-ligand section (d-block). In addition, under the co-action of crystal field and 4d orbits of Ag(Ⅰ) ion, the 4f orbits of Ln(Ⅲ) ions are tuned and cause obvious shift of partial energy levels, which present shifts of the corresponding NIR emission bands and can be corroborated in their UV-Vis-NIR absorption spectra.
- Ag-Ln coordination polymer,
- crystal structure,
- sensitization,
- luminescence
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