Citation: HE Wei-Wei, Feng Si-Yang, QU Zhi-Rong, TANG Hui, WANG Zuo-Xiang. Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole[J]. Chinese Journal of Inorganic Chemistry, ;2019, 35(1): 155-164. doi: 10.11862/CJIC.2019.010 shu

Syntheses, Crystal Structures and Properties of Cu(Ⅱ), Ni(Ⅱ) and Cd(Ⅱ) Complexes Based on 4-Methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole

1.
Key Laboratory of Organosilicon Chemistry and Materials Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China
2.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Corresponding author: QU Zhi-Rong, quzr@hznu.edu.cn WANG Zuo-Xiang, wangzx0908@aliyun.com
Received Date: 15 September 2018
Revised Date: 24 October 2018

Figures(9)

Complexes of[CuL₂Cl]Cl·H₂O (1), [NiL₂(H₂O)₂](NO₃)₂ (2), [CuL₂(H₂O)₂](ClO₄)₂ (3) and[CdL₂(NO₃)₂]·CH₃CN (4) were synthesized by the reactions of 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole (L) with CuCl₂·2H₂O, Ni(NO₃)₂·6H₂O, Cu(ClO₄)₂·6H₂O and Cd(NO₃)₂·4H₂O, respectively. Their structures were determined by single crystal X-ray diffraction, and characterized by IR, UV-Vis, fluorescence and TGA. Complex 1 belongs to orthorhombic system with space group Fddd, and the central Cu1(Ⅱ) ion has a distorted tetragonal pyramid geometry[CuN₄Cl]. The complexes of 2, 3 and 4 all belong to monoclinic system with space groups P2₁/_n, P2₁/_n and P2₁/c, respectively. All the central metal ions of 2, 3 and 4 have distorted octahedral configuration[NiN₄O₂], [CuN₄O₂], [CdN₄O₂].
- 4-methyl-3-phenyl-5-(2-pyridyl)-1, 2, 4-triazole,
- complexes,
- syntheses,
- crystal structures,
- fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142