Citation: RONG Jie-Wei, ZHANG Wen-Wei. Syntheses, Structures and Photoluminescent Properties of Metal-Organic Frameworks Based on Triangle Flexible Multi-Carboxylic Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2307-2315. doi: 10.11862/CJIC.2018.281 shu

Syntheses, Structures and Photoluminescent Properties of Metal-Organic Frameworks Based on Triangle Flexible Multi-Carboxylic Ligand

RONG Jie-Wei ^1,2 ,
ZHANG Wen-Wei ^2,,

1.
School of Chemical and Materials Engineering, Huainan Normal University, Huainan, Anhui 232038, China
2.
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China

Corresponding author: ZHANG Wen-Wei, wwzhang@nju.edu.cn
Received Date: 30 August 2018
Revised Date: 23 October 2018

Figures(7)

Two novel metal-organic frameworks {[Zn₃(TCPB)₂(4, 4'-BPY)]·DMF·3H₂O}_n (1) with trinuclear zinc cluster units and {[Co_1.5(TCPB)(DMF)(H₂O)]·DMF}_n (2) with trinuclear cobalt cluster SBUs, have been prepared under solvothermal conditions based on flexible 1, 3, 5-tri(4-carboxyphenoxy) benzene ligand (H₃TCPB) with the help of ancillary bridging N-donor pyridyl linker 4, 4'-bipyridine (4, 4'-BPY), and characterized by single crystal X-ray diffraction, IR spectra, elemental analyses, thermogravimetric analyses (TGA) and powder X-ray diffraction (PXRD). The single crystal X-ray diffraction analysis reveals that complex 1 crystallizes in triclinic space group P1 and exhibits three-dimensional (3D) (3, 8)-connected network with Schläfli symbol of {4³}₂·{4⁶·6¹⁸·8⁴}·{6}, complex 2 also belongs to the triclinic system with space group of P1 and shows two-dimensional (2D) (3, 6)-connected net-like layered framework with Schläfli symbol of {4³}₄·{4⁶·6¹⁸·8⁴}. In addition, the study of the solid state photoluminescent property of complex 1 indicates that it emits light blue fluorescence arising from TCPB^3- and 4, 4'-BPY ligands at room temperature, while complex 2 is non-emissive under similar conditions.
- flexible carboxylic ligand,
- metal-organic framework,
- crystal structure,
- photoluminescence
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
  Song X Z, Song S Y, Zhang H J. Struct. Bond., 2015, 163:109-144
6. [6]
  Ma D X, Li B Y, Zhou X J, et al. Chem. Commun., 2013, 49:8964-8966 doi: 10.1039/c3cc44546a
7. [7]
  Banerjee M, Das S, Yoon M, et al. J. Am. Chem. Soc., 2009, 131:7524-7525 doi: 10.1021/ja901440g
8. [8]
  Qin Y H, Huang L, Zheng J X, et al. Inorg. Chem. Commun., 2016, 72:78-82 doi: 10.1016/j.inoche.2016.08.018
9. [9]
  Bigdeli F, Abedi S, Monfared H H, et al. Inorg. Chem. Commun., 2016, 72:122-127 doi: 10.1016/j.inoche.2016.08.010
10. [10]
  Wang C, Liu D, Lin W. J. Am. Chem. Soc., 2013, 135:13222-13234 doi: 10.1021/ja308229p
11. [11]
  He Y P, Tan Y X, Zhang J. Inorg. Chem., 2013, 52:12758-12762 doi: 10.1021/ic4020256
12. [12]
  Wu J X, Yan B. Inorg. Chem. Commun., 2016, 70:189-192 doi: 10.1016/j.inoche.2016.06.021
13. [13]
  Chen D M, Tian J Y, Liu C S. Inorg. Chem. Commun., 2016, 68:29-32 doi: 10.1016/j.inoche.2016.03.023
14. [14]
  Wang Y P, Li X Y, Li H H, et al. Inorg. Chem. Commun., 2016, 70:27-30 doi: 10.1016/j.inoche.2016.05.008
15. [15]
  Wang H H, Zhou L J, Wang Y L, et al. Inorg. Chem. Commun., 2016, 73:94-97 doi: 10.1016/j.inoche.2016.10.006
16. [16]
  Cui Y J, Yue Y F, Qian G D, et al. Chem. Rev., 2012, 112:1126-1162 doi: 10.1021/cr200101d
17. [17]
  Zhu M, Li M T, Zhao L, et al. Inorg. Chem. Commun., 2017, 79:69-73 doi: 10.1016/j.inoche.2017.03.020
18. [18]
  Pan Z R, Zheng H G, Wang T W, et al. Inorg. Chem., 2008, 47:9528-9536 doi: 10.1021/ic801221r
19. [19]
  Zhang M D, Di C M, Zheng H G. Inorg. Chem. Commun., 2013, 27:88-91 doi: 10.1016/j.inoche.2012.10.012
20. [20]
  Xu H B, Zhou S H, Xiao L L, et al. J. Mater. Chem. C, 2015, 3:291-297 doi: 10.1039/C4TC01991A
21. [21]
  Dong X Y, Wang R, Wang J Z, et al. J. Mater. Chem. A, 2015, 3:641-647 doi: 10.1039/C4TA04421E
22. [22]
  Chen M, Wang Z W, Zhao H, et al. Inorg. Chem. Commun., 2014, 45:84-88 doi: 10.1016/j.inoche.2014.04.007
23. [23]
  Hassan M, Haque E, Reddy K R, et al. Nanoscale, 2014, 6:11988-11994 doi: 10.1039/C4NR02365J
24. [24]
  Zhao S N, Su S Q, Song X Z, et al. Cryst. Growth Des., 2013, 13:2756-2765 doi: 10.1021/cg3018387
25. [25]
  Fan L, Zhang X, Sun Z, et al. Cryst. Growth Des., 2013, 13:2462-2475 doi: 10.1021/cg400172w
26. [26]
  Deng Z P, Zhang Z Y, Huo L H, et al. CrystEngComm, 2012, 14:6548-6558 doi: 10.1039/c2ce25339a
27. [27]
  Kan W Q, Ma J F, Liu B, et al. CrystEngComm, 2012, 14:286-299 doi: 10.1039/C1CE05877K
28. [28]
  Yan C, Fan Y Z, Chen L, et al. CrystEngComm, 2015, 17:546-552 doi: 10.1039/C4CE01909A
29. [29]
  Zhai Q G, Zeng R R, Li S N, et al. CrystEngComm, 2013, 15:965-976 doi: 10.1039/C2CE26063H
30. [30]
  Chaudhari A K, Nagarkar S S, Joarder B, et al. Cryst. Growth Des., 2013, 13:3716-3721 doi: 10.1021/cg400749m
31. [31]
  APEX 2, SAINT, XPREP, Bruker AXS Inc., Madison, Wisconsin, USA, 2007.
32. [32]
  SADABS, Bruker AXS Inc., Madison, Wisconsin, USA, 2001.
33. [33]
  Sheldrick G M. SHELXS-97 and SHELXL-97, University of Göttingen, Germany, 1997.
34. [34]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7-13 doi: 10.1107/S0021889802022112
35. [35]
  Zhang J, Yang W B, Wu X Y, et al. Cryst. Growth Des., 2016, 16:475-482 doi: 10.1021/acs.cgd.5b01481
36. [36]
  Chen M, Zhao H, Liu C S, et al. Chem. Commun., 2015, 51:6014-6017 doi: 10.1039/C5CC00018A
37. [37]
  Kan W Q, Ma J F, Liu Y Y, et al. CrystEngComm, 2012, 14:2316-2326 doi: 10.1039/c2ce06176g
38. [38]
  Gao Y P, Guo L, Dong W, et al. J. Solid State Chem., 2016, 240:82-90 doi: 10.1016/j.jssc.2016.05.023
39. [39]
  Robin A Y, Fromm K M. Coord. Chem. Rev., 2006, 250:2127-2157 doi: 10.1016/j.ccr.2006.02.013
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