Citation: ZHANG Wan-Yu, ZHANG Xiao-Juan, TONG Jia-Lin, CHEN Tian-Ci, TIAN Jun-Qiang, HU Rong, WANG Zhi-Ming. Optical Properties and Biological Applications of Meso-tetrakis (p-methylphenyl) Porphyrin and Its Cobalt Complex[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2161-2171. doi: 10.11862/CJIC.2018.279 shu

Optical Properties and Biological Applications of Meso-tetrakis (p-methylphenyl) Porphyrin and Its Cobalt Complex

1.
School of Petrochemical Engineering, Shenyang University of Technology, Liaoyang, Liaoning 111003, China
2.
Shenzhen Research Institute, The Hong Kong University of Science and Technology, Shenzhen, Guangdong 518000, China

Corresponding author: ZHANG Xiao-Juan, zxj51565@163.com WANG Zhi-Ming, wangzhm1983@163.com
Received Date: 22 May 2018
Revised Date: 2 October 2018

Figures(18)

The solvation effects of meso-tetrakis(p-methylphenyl) porphyrin (TMPP) and meso-tetrakis(p-methylphenyl) porphyrin cobalt (TMPP-Co), and the luminescence mechanism in aqueous systems have been studied in detail. It was found that the luminescence intensity of TMPP after the complexation of cobalt ions decreased significantly; the solvation effect of TMPP-Co was not only related to the polarity of the solvent but also related to the axial coordination of Co ions. The luminous intensities of TMPP and TMPP-Co showed a trend of increase and then decrease both in aqueous phase and in glycerol. In addition, TMPP-Co has a strong ability to generate singlet oxygen; the preparation of TMPP-TAT-NPs nanoparticles successfully stained cells and localized to the cell lysosomes.
- TMPP,
- photoelectric properties,
- singlet oxygen,
- cell staining
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沈阳化工大学材料科学与工程学院沈阳 110142