Citation: SU Peng-He, ZHEN Lu-An, CHEN Ya, LIU Xiao-Tong, ZHU Bao-Lin, ZHANG Shou-Min, HUANG Wei-Ping. Catalytic Performances for Hydroformylation of Cyclohexene of MgSNTs-Supported Amorphous Co-B Catalysts[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2197-2204. doi: 10.11862/CJIC.2018.275 shu

Catalytic Performances for Hydroformylation of Cyclohexene of MgSNTs-Supported Amorphous Co-B Catalysts

1.
College of Chemistry, Nankai University, Tianjin 300071, China
2.
Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300071, China
3.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Nankai University, Tianjin 300071, China

Received Date: 12 June 2018
Revised Date: 4 October 2018

Figures(4)

Novel silicate nanotubes supported amorphous Co-B (Co-B/MgSNTs) were synthesized via a hydrothermal method followed by impregnation-chemical reduction processes. The catalysts were characterized with X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectrometer (XPS), atomic emission spectrometer (ICP) and brunauer-Emmett-Tellerv (BET) surface-area analyzers. The catalytic activity and recyclability of catalysts for hydroformylation of cyclohexene were evaluated. The conversion of cyclohexene over the catalysts is 75.8% and selectivity for aldehyde is 65.8%. The results indicate that Co-B nanoparticles were deposited on the inner and outer surface of MgSNTs, which had large specific surface area and high stability. Furthermore, the tubular structure of nanotubes could prevent nanoparticle from agglomeration. The catalyst used for 3 recycles shows good catalytic activity.
- nanotubes,
- silicate,
- hydroformylation,
- cyclohexene
1. [1]
  Xu D F, Zhao B G. Sci. China:Chem., 2017, 60(7):839-840 doi: 10.1007/s11426-016-9004-4
2. [2]
  Cai C X, Yu S C, Liu G D, et al. Adv. Synth. Catal., 2011, 353:2665-2670 doi: 10.1002/adsc.v353.14/15
3. [3]
  Bhagade S S, Chaurasia S R, Bhanage B M. Catal. Today, 2018, 309:147-152 doi: 10.1016/j.cattod.2017.08.022
4. [4]
5. [5]
  TONG Xue, YANG Feng-Li, REN Jing, et al. Chinese J. Inorg. Chem., 2018, 34(1):129-134
6. [6]
  Li Y Q, Wang P, Liu H, et al. Green Chem., 2016, 18:1798-1806 doi: 10.1039/C5GC02127H
7. [7]
  Pospech J, Fleischer I, Franke R, et al. Angew. Chem. Int. Ed., 2013, 52:2852-2872 doi: 10.1002/anie.201208330
8. [8]
  Patureau F W, Worch C, Siegler M A, et al. Adv. Synth. Catal., 2012, 354:59-64 doi: 10.1002/adsc.201100692
9. [9]
  Fuchs D, Rousseau G, Diab L, et al. Angew. Chem. Int. Ed., 2012, 51:2178-2182 doi: 10.1002/anie.201108946
10. [10]
  Xue X R, Song Y, Xu Y C, et al. New J. Chem., 2018, 42:6640-6643 doi: 10.1039/C8NJ00447A
11. [11]
  Izumi Y, Asakura K, Iwasawa Y. J. Catal., 1991, 127(2):631-644 doi: 10.1016/0021-9517(91)90188-A
12. [12]
  Alini S, Bottino A, Capannelli G, et al. Appl. Catal., A, 2005, 292:105-112 doi: 10.1016/j.apcata.2005.05.048
13. [13]
  Sivasankar N, Frei H. J. Phys. Chem. C, 2011, 115(15):7545-7553 doi: 10.1021/jp112391n
14. [14]
  Izumi Y, Iwasawa Y. J. Phys. Chem., 1992, 96:10942-10948 doi: 10.1021/j100205a062
15. [15]
  Han D F, Li X H, Zhang H D, et al. J. Catal., 2006, 243(2):318-328
16. [16]
  Liu J, Yan L, Jiang M, et al. Chin. J. Catal., 2016, 37(2):268-272
17. [17]
  Zhao Y P, Zhang X M, Sanjeevi J, et al. J. Catal., 2016, 334:52-59 doi: 10.1016/j.jcat.2015.11.011
18. [18]
  Ahmed M, Sakthivel A. J. Mol. Catal. A:Chem., 2016, 424(1):85-90
19. [19]
  Sun Q, Dai Z F, Liu X L, et al. J. Am. Chem. Soc., 2015, 137(15):5204-5209 doi: 10.1021/jacs.5b02122
20. [20]
  Garcia M A S, Oliveira K C B, Costa J C S, et al. ChemCatChem, 2015, 7:1566-1572 doi: 10.1002/cctc.v7.10
21. [21]
  Zhang Y, Zhang H B, Lin G D, et al. Appl. Catal., A, 1999, 187:213-224 doi: 10.1016/S0926-860X(99)00229-X
22. [22]
  Prasad V, Vasanthkumar M S. J. Nanopart Res., 2015, 17:398-496 doi: 10.1007/s11051-015-3199-7
23. [23]
  Hu X J, Shi Y K, Zhang Y J, et al. Catal. Commun., 2015, 59:45-49 doi: 10.1016/j.catcom.2014.09.043
24. [24]
  Shi Y K, Hu X J, Zhu B L, et al. RSC Adv., 2014, 4:62215-62222 doi: 10.1039/C4RA11156G
25. [25]
  Du X J, Fu N H, Zhang S L, et al. Nano Res., 2016, 9(9):2681-2686 doi: 10.1007/s12274-016-1155-1
26. [26]
  CHEN Lan-Hua, LI Xuan, GUO Xiang-Ke, et al. Chinese J. Inorg. Chem., 2013, 7(29):1333-1338
27. [27]
  Li F, Ma R, Cao B, et al. Appl. Catal., A, 2016, 514:248-252 doi: 10.1016/j.apcata.2016.01.035
28. [28]
  Zhang X, Liu R R, Zang Y P, et al. Chem. Commun., 2016, 52:5946-5949 doi: 10.1039/C6CC02513G
29. [29]
  Arzac G M, Rojas T C, Fernández A. ChemCatChem, 2011, 3:1305-1313 doi: 10.1002/cctc.201100101
30. [30]
  Arzac G M, Rojas T C, Fernández A. Appl. Catal., B, 2012, 128:39-47 doi: 10.1016/j.apcatb.2012.02.013
31. [31]
  Li Y Q, Xu H B, Huang H Y, et al. Electrochem. Commun., 2018, 86:140-144 doi: 10.1016/j.elecom.2017.12.011
32. [32]
  Hebrard F, Kalck P. Chem. Rev., 2009, 109:4272-4282 doi: 10.1021/cr8002533
33. [33]
  Shi Y K, Hu X J, Zhu B L, et al. Chem. Res. Chin. Univ., 2015, 31(5):851-857 doi: 10.1007/s40242-015-5002-9
34. [34]
  Heck R F, Breslow D S. J. Am. Chem. Soc., 1961, 83:4023-4027 doi: 10.1021/ja01480a017
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沈阳化工大学材料科学与工程学院沈阳 110142