Citation: LIU Yuan-Yuan, LI Xin Shu, ZHANG Hui-Min, DING Bin. Three Polyoxometalate-Based Cu(Ⅱ) and Cu(Ⅰ) Coordination Polymers with Mono-and Bis-triazole Derivatives: Hydrothermal Assembly and Photocatalytic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2280-2290. doi: 10.11862/CJIC.2018.274 shu

Three Polyoxometalate-Based Cu(Ⅱ) and Cu(Ⅰ) Coordination Polymers with Mono-and Bis-triazole Derivatives: Hydrothermal Assembly and Photocatalytic Properties

LIU Yuan-Yuan ^1,2,, ,
LI Xin Shu ¹ ,
ZHANG Hui-Min ¹ ,
DING Bin ^1,2

1.
Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin 300387, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China

Corresponding author: LIU Yuan-Yuan, hxxylyy@mail.tjnu.edu.cn
Received Date: 6 August 2018
Revised Date: 26 September 2018

Figures(12)

Three novel polyoxometalate (POM)-based Cu(Ⅱ) and Cu(Ⅰ) hybrid materials with multi-dentate mono-and bis-triazole derivatives, namely {[Cu(L¹)₂(Mo₄O₁₃)]·2H₂O}_n (1), {[Cu_1.5(L²)(HL₂)(H₂O)(Mo₄O₁₃)]·2H₂O}_n (2), {[Cu₂(L₃)_1.5(Mo₄O₁₃)]·H₂O}_n (3) (L₁=4-pyridine-2-1, 2, 4-triazole, HL₂=3-(4H-1, 2, 4-triazol-4-yl) benzoic acid, L₃=trans-4, 4'-azo-1, 2, 4-triazole) have been designed and synthesized by hydrothermal method. The structures of 1~3 have been determined by single crystal X-ray diffraction, FT-IR infrared spectra and powder X-ray diffraction analyses. In 1, Mo₄O₁₃^2- anions and Cu(Ⅱ) centers are inter-linked by bidentate L₁, which are arranged into 2D POMs-based Cu(Ⅱ) hybrid metal-organic framework. In 2, Mo₄O₁₃^2- anions and Cu(Ⅱ) centers are inter-linked via bridging aqua atoms (O18), bi-dentate HL₂ and tri-dentate L₂^-, which are arranged into 3D POM-based Cu(Ⅱ) micro-porous metal-organic framework. In 3, L₃ ligands bridge neighboring Cu(Ⅰ) centers and Mo₄O₁₃^2- anions, which ultimately forms unique two-fold interpenetrating 3D POM-based Cu(Ⅰ) hybrid coordination framework. Photocatalytic activities for decomposition of different organic dyes of rhodamine B (RhB), methylene blue (MB) and methyl orange (MO) have been investigated for 1~3, indicating that 1~3 are good candidates for photocatalytic degradation of the organic dyes.
- triazole,
- Cu (Ⅱ),
- Cu (Ⅰ),
- polyoxometalate,
- photocatalytic
1. [1]
  (a) Banerjee R, Phan A, Wang B, et al. Science, 2008, 319: 939-943
  (b) Zhu P P, Sun L J, Sheng N, et al. Cryst. Growth Des., 2016, 16: 3215-3223
  (c) Bijelic A, Rompel A. Acc. Chem. Res., 2017, 50: 1441-1448
2. [2]
  (a) Anjass M H, Kastner K, Nagele F, et al. Angew. Chem. Int. Ed., 2017, 56: 14749-14752
  (b) He W W, Li S L, Zang H Y, et al. Coord. Chem. Rev., 2014, 279: 141-160
  (c) Wang X, Zhang Q, Nam C, et al. Angew. Chem. Int. Ed., 2017, 56: 11826-11829
3. [3]
  (a) Yi X F, Izarova N V, Stuckart M, et al. J. Am. Chem. Soc., 2017, 139: 14501-14510
  (b) Liu Y P, Zhao S F, Guo S X, et al. J. Am. Chem. Soc., 2016, 138: 2617-2628
4. [4]
  (a) Yu Y, Zhang Q, Buscaglia J M. Analyst, 2016, 141: 4424-4431
  (b) Zhang Q, Kaisti M, Prabhu A, et al. Electrochim. Acta, 2017, 261: 256-264
  (c) Zhang Z M, Duan X P, Yao S, et al. Chem. Sci., 2016, 7: 4220-4229
  (d) Liu R J, Zhang G J, Cao H B, et al. Energy Environ. Sci., 2016, 9: 1012-1023
5. [5]
  (a) Kaisti M, Zhang Q, Levon K, et al. Sens. Actuators B: Chem., 2017, 241: 321-326
  (b) Yu Y, Zhang Q, Wang Y, et al. Analyst, 2016, 141: 5607-5617
  (c) Fu H, Qin C, Lu Y, et al. Angew. Chem. Int. Ed., 2012, 51: 7985-7989
  (d) Genovese M, Lian K. J. Mater. Chem. A, 2017, 5: 3939-3947
6. [6]
  (a) Wei X, Panindre P, Zhang Q, et al. ACS Sens., 2016, 1: 862-865
  (b) Zhu S L, Xu X, Ou S, et al. Inorg. Chem., 2016, 55: 7295-7300
  (c) Xin X, Tian X R, Yu H T, et al. Inorg. Chem., 2018, 57: 11474-11481
  (d) Li X X, Zhang L J, Cui C Y, et al. Inorg. Chem., 2018, 57: 10323-10330
7. [7]
  (a) Chen L Y, Luque R, Li Y W, et al. Chem. Soc. Rev., 2017, 46: 4614-4630
  (b) Bennett J W, Bjorklund J L, Forbes T Z, et al. Inorg. Chem., 2017, 56: 13014-13028
  (c) Lysenko A B, Bondar O A, Senchyk G A, et al. Inorg. Chem., 2018, 57: 6076-6083
8. [8]
  Zhu P P, Sun L J, Sheng N, et al. Cryst. Growth Des., 2016, 16:3215-3223 doi: 10.1021/acs.cgd.6b00119
9. [9]
  Li X X, Wang Y X, Wang R H, et al. Angew. Chem. Int. Ed., 2016, 55:6462-6466 doi: 10.1002/anie.201602087
10. [10]
  Haasnoot J G. Coord. Chem. Rev., 2000, 200-202:131-185 doi: 10.1016/S0010-8545(00)00266-6
11. [11]
  Li X X, Xu H Y, Kong F Z, et al. Angew. Chem. Int. Ed., 2013, 52:13769-13773 doi: 10.1002/anie.201307650
12. [12]
  Zhu P P, Sheng N, Li M T, et al. J. Mater. Chem. A, 2017, 5:17920-17925 doi: 10.1039/C7TA05254E
13. [13]
  (a) Ding B, Yi L, Cheng P, et al. Inorg. Chem., 2006, 45: 5799-5803
  (b) Ding B, Liu S X, Cheng Y, et al. Inorg. Chem., 2016, 55: 4391-4402
14. [14]
  Liu J Y, Wang Q, Zhang L J, et al. Inorg. Chem., 2014, 53:5972-5985 doi: 10.1021/ic500183b
15. [15]
  Wang Y, Yuan B, Xu Y Y, et al. Chem. Eur. J., 2015, 21:2107-2116 doi: 10.1002/chem.v21.5
16. [16]
  (a) Cheng Y, Wu J, Guo C, et al. J. Mater. Chem. B, 2017, 5: 2524-2535
  (b) Wang X R, Du J, Huang Z, et al. J. Mater. Chem. B, 2018, 6: 4569-4574
17. [17]
  (a) Gusev A N, Nemec I, Herchel R, et al. Dalton Trans., 2014, 43: 7153-7163
  (b) Naik A D, Marchand-Brynaert J, Garcia Y. Synthesis, 2008, 1: 149-154
18. [18]
  Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1997.
19. [19]
  Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997.
20. [20]
  Spek A L. J. Appl. Crystallogr., 2003, 36:7-13 doi: 10.1107/S0021889802022112
21. [21]
  Senchyk G A, Lysenko A B, Domasevitch K V, et al. Inorg. Chem., 2017, 56:12952-12966 doi: 10.1021/acs.inorgchem.7b01735
22. [22]
  Fiher M E. Am. J. Phys., 1964, 32:343-345 doi: 10.1119/1.1970340
23. [23]
  Wang X L, Gong C H, Zhang J W, et al. CrystEngComm, 2015, 17:4179-4189 doi: 10.1039/C5CE00411J
24. [24]
  (a) Cui J W, An W J, Kristof Van H, et al. Dalton Trans., 2016, 45: 17474-17484
  (b) Jia C, Xie X W, Ge M, et al. Mater. Sci. Semicond. Process., 2015, 36: 71-77
25. [25]
  Dolbecq A, Mialane P, Keita B, et al. J. Mater. Chem., 2012, 22:24509-24521 doi: 10.1039/c2jm33246a
26. [26]
  (a) Zhang Q, Khajo A, Sai T, et al. J. Phys. Chem. A, 2012, 116: 7629-7635
  (b) Hu J M, Blatov V A, Yu B Y, et al. Dalton Trans., 2016, 45: 2426-2429
27. [27]
  Meng X M, Fan C B, Bi C F, et al. CrystEngComm, 2016, 18:2901-2912 doi: 10.1039/C5CE02473K
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