Citation: CHEN Xiao-Li, CUI Hua-Li, YANG Hua, REN Yi-Xia, WANG Ji-Jiang, WANG Xiao. Syntheses, Crystal Structures and Properties of Three Metal Complexes Based on 3, 3', 4, 4'-Tetracarboxyazobenzene[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2298-2306. doi: 10.11862/CJIC.2018.266 shu

Syntheses, Crystal Structures and Properties of Three Metal Complexes Based on 3, 3', 4, 4'-Tetracarboxyazobenzene

School of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Laboratory of New Energy & New Function Materials, Yan'an University, Yan'an, Shaanxi 716000, China

Corresponding author: CHEN Xiao-Li, chenxiaoli003@163.com
Received Date: 30 August 2018
Revised Date: 14 September 2018

Figures(14)

Three transition metal complexes based on H₄ddb ligand, namely[Co₂(ddb)(phen)₂(H₂O)₆]·3H₂O (1), [Co(ddb)_0.5(bpy)_0.5(H₂O)₃]_n (2) and {[Ag(dpe)]·0.5(H₂ddb)·H₂O}_n (3). (H₄ddb=3, 3', 4, 4'-tetracarboxyazobenzene, bpy=4, 4'-pyridine, dpe=1, 2-di(4-pyridyl) ethylene) have been synthesized and structurally characterized by elemental anal-yses, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analyses. Complex 1 is binuclear structure, which is linked into 3D supramolecular network through rich hydrogen bonding interactions. Complex 2 shows 2D network constructed from Co²⁺ ion cross-linked by ddb^4- ligands via μ₄:η¹, η¹, η¹, η¹ coordina-tion mode. Complex 3 is linear chain structure based on Ag(Ⅰ) ion and dpe ligands. Interestingly, the guest molecule H₂ddb^2- extends a 3D supramolecular structure of 3 through intermolecular hydrogen bonding interactions. In addition, the thermal stabilities and luminescence properties of 1~3 were also studied.
- transition metal,
- 3, 3', 4, 4'-tetracarboxyazobenzene,
- crystal structure,
- luminescence
1. [1]
  Yang X, Xu Q. Cryst. Growth Des., 2017, 17:1450-1455 doi: 10.1021/acs.cgd.7b00166
2. [2]
  Kreno L E, Leong K, Farha O K, et al. Chem. Rev., 2012, 112:1105-1125 doi: 10.1021/cr200324t
3. [3]
  Gil-Hernández B, Savvin S, Makhloufi G, et al. Inorg. Chem., 2015, 54:1597-1605 doi: 10.1021/ic502586a
4. [4]
  Ding L G, Yao B J, Jiang W L, et al. Inorg. Chem., 2017, 56:2337-2344 doi: 10.1021/acs.inorgchem.6b03169
5. [5]
  Zhao X L, Sun W Y. CrystEngComm, 2014, 16:3247-3258 doi: 10.1039/c3ce41791c
6. [6]
  Pang J, Jiang F, Wu M, et al. Chem. Commun., 2014, 50:2834-2836 doi: 10.1039/c3cc48381a
7. [7]
  Zhang Y B, Furukawa H, Yaghi O M, et al. J. Am. Chem. Soc., 2015, 137:2641-2650 doi: 10.1021/ja512311a
8. [8]
  Zhao J, Wang Y N, Dong W W, et al. Chem. Commun., 2015, 51:9479-9482 doi: 10.1039/C5CC02043C
9. [9]
  Gai Y L, Jiang F L, Hong M C, et al. Cryst. Growth Des., 2014, 14:1010-1017 doi: 10.1021/cg401452p
10. [10]
  Li X Z, Li M A, Li Z, et al. Angew. Chem. Int. Ed., 2008, 47:6371-6374 doi: 10.1002/anie.v47:34
11. [11]
  Cunha D, Yahia M B, Hall S, et al. Chem. Mater., 2013, 25:2767-2776 doi: 10.1021/cm400798p
12. [12]
  Patra R, Titi H M, Goldberg I. CrystEngComm, 2013, 15:2853-2862 doi: 10.1039/c3ce27006h
13. [13]
  Pan L, Liu H, Lei X, et al. Angew. Chem. Int. Ed., 2003, 42:542-546 doi: 10.1002/anie.200390156
14. [14]
  Habib H A, Sanchiz J, Janiak C. Dalton Trans., 2008:4877-4884
15. [15]
  Sun D, Han L L, Yuan S, et al. Cryst. Growth Des., 2013, 13:377-385 doi: 10.1021/cg301573c
16. [16]
  Wang C C, Jing H P, Zhang Y Q, et al. Transition Met. Chem., 2015, 40:573-584 doi: 10.1007/s11243-015-9950-1
17. [17]
  Wang J, Lu L, Wu W P, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2012, 42:25-29 doi: 10.1080/15533174.2011.609223
18. [18]
  Wang J, Lu L, Wu W P, et al. J. Chem. Res., 2011, 35:424-427 doi: 10.3184/174751911X13101136526834
19. [19]
  Wang J, Lu L, Wu W P, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2013, 43:791-794 doi: 10.1080/15533174.2012.749909
20. [20]
  Wang J, Lu L, Wu W P, et al. Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 2012, 42:1217-1221 doi: 10.1080/15533174.2011.652278
21. [21]
  Lu L, Wang J, Bai J W, et al. Cryst. Res. Technol., 2008, 43:1327-1330 doi: 10.1002/crat.v43:12
22. [22]
  Lightfoot P, Snedden A. J. Chem. Soc. Dalton Trans., 1999:3549-3551
23. [23]
  Sun C Y, Li L C, Jin L P. Polyhedron, 2006, 25:3017-3024 doi: 10.1016/j.poly.2006.05.009
24. [24]
  Lee S W, Kim H J, Lee Y K, et al. Inorg. Chim. Acta, 2003, 353:151-158 doi: 10.1016/S0020-1693(03)00246-9
25. [25]
  Ahmad M, Sharma M K, Das R, et al. Cryst. Growth Des., 2012, 12:1571-1578 doi: 10.1021/cg201619x
26. [26]
  (a) Sheldrick G M. SADABS, University of Göttingen, Germany, 1996.
  (b) Sheldrick G M. SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution and Refinement, Göttingen University, Germany, 1997.
27. [27]
  WANG Li, KGAN Quan-Peng, HAO Jing, et al. Chinese J. Inorg. Chem., 2018, 34(3):525-533
28. [28]
  LIU Ji-Wei. Chinese J. Inorg. Chem., 2017, 33(4):705-712
29. [29]
  Chen S, Fan R Q, Sun C F, et al. Cryst. Growth Des., 2012, 12:1337-1346 doi: 10.1021/cg201411b
30. [30]
  Xia J, Wang H S, Shi W, et al. Inorg. Chem., 2007, 46:3450-3458 doi: 10.1021/ic061620p
31. [31]
  Nakamoto K, Translated by HUANG De-Ru, WANG Ren-Qing. Infrared Raman Spectra of Inorganic and Coordination Compounds. Beijing: Chemical Industry Press, 1986: 235
32. [32]
  Li D X, Chen M M, Li F L, et al. Inorg. Chem. Commun., 2013, 35:302-306 doi: 10.1016/j.inoche.2013.07.014
33. [33]
  Zhang L Y, Liu G F, Zheng S L, et al. Eur. J. Inorg. Chem., 2003:2965-2971
34. [34]
  Wang X L, Qin C, Wang E B, et al. Angew. Chem. Int. Ed., 2004, 43:5036-5040 doi: 10.1002/(ISSN)1521-3773
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