Citation: YANG Yu-Ting, TU Chang-Zheng, YAO Li-Feng, XU Li-Li, WANG Jun-Shi, YIN Hong-Ju, WANG Fan. Metal Ions Tuned Architectures Based on Diphenic Acid and 1,4-Bis(benzimidazol-1-ylmethyl)-benzene: Syntheses, Structures and Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2049-2056. doi: 10.11862/CJIC.2018.257 shu

Metal Ions Tuned Architectures Based on Diphenic Acid and 1,4-Bis(benzimidazol-1-ylmethyl)-benzene: Syntheses, Structures and Properties

College of Chemistry and Environmental Science, Qujing Normal University, Qujing, Yunnan 655011, China

Corresponding author: YANG Yu-Ting, 18288438002@163.com
Received Date: 29 March 2018
Revised Date: 21 August 2018

Figures(10)

Two novel complexes, [Cu₂(bbix)(dpa)₂(C₂H₅OH)₂]_n (1) and {[Cd(bbix)_0.5(dpa)]·0.5H₂O}_n (2) (H₂dpa=diphenic acid, bbix=1, 4-bis(benzimidazol-1-ylmethyl)-benzene), were synthesized and structurally characterized under solvothermal conditions.Both 1 and 2 exhibit two-dimensional (2D) architecture.Complex 1 has 6³ wave-like layer consisting of Cu-dpa helical chains in which the Cu(Ⅱ) ions as 3-connecting nodes.While the layer structure of 2 consists of one-dimensional chains containing alternated 4-membered and 8-membered rings.Furthermore, the solid-state properties of thermal stability for all crystalline materials and the fluorescence property of 2 at room temperature have been investigated.
- coordination polymer,
- crystal structure,
- diphenic acid,
- 1,4-bis(benzimidazol-1-ylmethyl)-benzene,
- fluorescence
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