Citation: MA Ling-Juan, HOU Meng-Ning, MA Hong-Bin, CAO Zhen, XUE Zhen, LU Yue-Ru. MoO₃-C₃N₄ Photocatalysts with High Performance for Degradation of Methyl Orange under Visible Light[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1899-1909. doi: 10.11862/CJIC.2018.251 shu

MoO₃-C₃N₄ Photocatalysts with High Performance for Degradation of Methyl Orange under Visible Light

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu, Shandong 273165, China

Corresponding author: MA Ling-Juan, malingjuan@qfnu.edu.cn
Received Date: 26 April 2018
Revised Date: 4 September 2018

Figures(14)

High performance MoO₃-C₃N₄ photocatalysts were prepared by impregnation method with (NH₄)₆Mo₇O₂₄·4H₂O and C₃N₄ as precursors. The MoO₃-C₃N₄ photocatalysts were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), high resolution transmission electron microscopy (HRTEM) and nitrogen physisorption isotherm. And methyl orange (MO) degradation was chosen to test the photocatalytic performance of MoO₃-C₃N₄. It was found that all MoO₃-C₃N₄ samples showed very high surface area, exhibited high photocatalytic activity for MO degradation under visible light irradiation and the content of MoO₃ affected the photocatalytic activity. The rate constant of 1.60%(w/w) MoO₃-C₃N₄ was 50 times higher than that of pure C₃N₄. The enhancement of photocatalytic activity over the heterojunction catalyst could be directly attributed to the Z-scheme photo-generated charge carrier transfer process, which contributes to suppressed recombination rate of photogenerated electron-hole pairs and prolonged lifetime of charge carriers caused by hybridization of MoO₃.
- MoO₃-C₃N₄,
- C₃N₄,
- photocatalysis,
- methyl orange,
- photodegradation
1. [1]
  Chong M N, Jin B, Chow C W K, et al. Water Res., 2010, 44(10):2997-3027 doi: 10.1016/j.watres.2010.02.039
2. [2]
  Fu F L, Wang Q. J. Environ. Manage., 2011, 92(3):407-418 doi: 10.1016/j.jenvman.2010.11.011
3. [3]
  Fujishima A, Zhang X T, Tryk D A. Surf. Sci. Rep., 2008, 63:515-582 doi: 10.1016/j.surfrep.2008.10.001
4. [4]
  Crini G. Bioresour. Technol., 2006, 97(16):2173-2181 doi: 10.1016/j.biortech.2005.09.022
5. [5]
  Gupta V K, Suhas. J. Environ. Manage., 2009, 90(8):2313-2342 doi: 10.1016/j.jenvman.2008.11.017
6. [6]
  Hermosilla D, Merayo N, Gascó A, et al. Environ. Sci. Pollut. Res., 2015, 22(1):168-191 doi: 10.1007/s11356-014-3516-1
7. [7]
  Forgacs E, Cserháti T, Oros G. Environ. Int., 2004, 30(7):953-971 doi: 10.1016/j.envint.2004.02.001
8. [8]
  Abbasi A, Ghanbari D, Salavati-Niasari M, et al. J. Mater. Sci.:Mater. Electron., 2016, 27(5):4800-4809 doi: 10.1007/s10854-016-4361-4
9. [9]
  Akhavan O. J. Colloid Interface Sci., 2009, 336(1):117-124 doi: 10.1016/j.jcis.2009.03.018
10. [10]
  Chan S H S, Wu T Y, Juan J C, et al. J. Chem. Technol. Biotechnol., 2011, 86(9):1130-1158 doi: 10.1002/jctb.v86.9
11. [11]
  Roy P, Berger S, Schmuki P. Angew. Chem. Int. Ed., 2011, 50(13):2904-2939 doi: 10.1002/anie.201001374
12. [12]
  Bavykin D V, Friedrich J M, Walsh F C. Adv. Mater., 2006, 18(5):1124-1129
13. [13]
  Schneider J, Matsuoka M, Takeuchi M, et al. Chem. Rev., 2014, 114(19):9919-9986 doi: 10.1021/cr5001892
14. [14]
  Nakata K, Fujishima A. J. Photochem. Photobiol. C, 2012, 13(3):169-189 doi: 10.1016/j.jphotochemrev.2012.06.001
15. [15]
  Woan K, Pyrgiotakis G, Sigmund W. Adv. Mater., 2009, 21(21):2233-2239 doi: 10.1002/adma.v21:21
16. [16]
  Tong H, Ouyang S X, Bi Y P, et al. Adv. Mater., 2012, 24(2):229-251 doi: 10.1002/adma.201102752
17. [17]
  Li Y M, Ji S D, Gao Y F, et al. Sci. Rep., 2013, 5:1370-1382
18. [18]
  Asahi R, Morikawa T, Ohwaki T, et al. Science, 2001, 293(5528):269-271 doi: 10.1126/science.1061051
19. [19]
  Banisharif A, Khodadadi A A, Mortazavi Y, et al. Appl. Catal. B:Environ., 2015, 165(2):209-221
20. [20]
  Wang X C, Maeda K, Thomas A, et al. Nat. Mater., 2009, 8:271-275 doi: 10.1038/nmat2406
21. [21]
  Yan S C, Li Z S, Zou Z G. Langmuir, 2009, 25(17):10397-10401 doi: 10.1021/la900923z
22. [22]
  Dong F, Wu L W, Sun Y J, et al. J. Mater. Chem., 2011, 21(39):15171-15174 doi: 10.1039/c1jm12844b
23. [23]
  Liu J H, Zhang T K, Wang Z C, et al. Mater. Chem., 2011, 21(14):5430-5434 doi: 10.1039/c1jm00049g
24. [24]
  Wang Y, Wang X C, Antonietti M. Angew. Chem. Int. Ed., 2012, 51(1):68-89 doi: 10.1002/anie.201101182
25. [25]
  Fang S, Xia Y, Lv K L, et al. Appl. Catal. B:Environ., 2016, 185:225-232 doi: 10.1016/j.apcatb.2015.12.025
26. [26]
  Ma S L, Zhan S H, Jia Y N, et al. Appl. Catal. B:Environ., 2016, 186:77-87 doi: 10.1016/j.apcatb.2015.12.051
27. [27]
  Mao Z Y, Chen J J, Yang Y F, et al. ACS Appl. Mater. Interfaces, 2017, 7(9):5320-5330
28. [28]
  Pan C S, Xu J, Wang Y J, et al. Adv. Funct. Mater., 2012, 22(7):1518-1524 doi: 10.1002/adfm.v22.7
29. [29]
  Wang Y J, Shi R, Lin J, et al. Energy Environ. Sci., 2011, 4(8):2922-2929 doi: 10.1039/c0ee00825g
30. [30]
  Zhang L, Jing D W, She X L, et al. J. Mater. Chem. A, 2014, 2(7):2071-2078 doi: 10.1039/C3TA14047D
31. [31]
  Hu S Z, Jin R R, Lu G, et al. RSC Adv., 2014, 4(47):24863-24869 doi: 10.1039/c4ra03290j
32. [32]
  Li Y P, Huang L Y, Xu J B, et al. Mater. Res. Bull., 2015, 70:500-505 doi: 10.1016/j.materresbull.2015.05.013
33. [33]
  Shakir I, Shahid M, Kang D J. Chem. Commun., 2010, 46(24):4324-4326 doi: 10.1039/c000003e
34. [34]
  Ma C H, Zhou J, Cui Z W, et al. Sol. Energy Mater. Sol. Cells, 2016, 150:102-111 doi: 10.1016/j.solmat.2016.02.010
35. [35]
  He Y M, Zhang L H, Wang X X, et al. RSC Adv, 2014, 4(110):65163-65172 doi: 10.1039/C4RA11498A
36. [36]
  Jiang D L, Chen L L, Zhu J J, et al. Dalton Trans., 2013, 42(44):15726-34 doi: 10.1039/c3dt52008k
37. [37]
  Chen Y P, Lu C L, Xu L, et al. CrystEngComm, 2010, 12(11):3740-3747 doi: 10.1039/c000744g
38. [38]
  She X J, Wu J J, Xu H, et al. Adv. Energy Mater., 2017, 7:1700025 doi: 10.1002/aenm.201700025
39. [39]
  Huang L Y, Xu H, Zhang R X, et al. Appl. Surf. Sci., 2013, 283(14):25-32
40. [40]
  Niu P, Liu G, Cheng H M. J. Phys. Chem. C, 2012, 116(20):11013-11018 doi: 10.1021/jp301026y
41. [41]
  XU Meng-Qiu, CHAI Bo, YAN Jun-Tao, et al. Chinese J. Inorg. Chem., 2017, 33(3):389-395
42. [42]
  Yan H J, Chen Y, Xu S M. Int. J. Hydrogen Energy, 2012, 37(1):125-133 doi: 10.1016/j.ijhydene.2011.09.072
43. [43]
  Asakura K, Nakatani K, Kubota T, et al. J. Catal., 2000, 194(2):309-317 doi: 10.1006/jcat.2000.2937
44. [44]
  Soldat J, Marschall R, Wark M. Mater. Res. Bull., 2014, 5:3746-3752
45. [45]
  Wang Y, Di Y, Antonietti M, et al. Chem. Mater., 2010, 22(18):5119-5121 doi: 10.1021/cm1019102
46. [46]
  Wang Y F, Liu J X, Wang Y W, et al. Mater. Sci. Semicond. Process., 2014, 25:330-336 doi: 10.1016/j.mssp.2014.02.017
47. [47]
  Dong H J, Chen G, Sun J X, et al. Appl. Catal. B:Environ., 2013, 219(3):86-95
48. [48]
  Chang Y C, Yan C Y, Wu R J, et al. J. Chin. Chem. Soc., 2014, 61(3):345-349 doi: 10.1002/jccs.v61.3
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MoO3-C3N4 Photocatalysts with High Performance for Degradation of Methyl Orange under Visible Light

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MoO₃-C₃N₄ Photocatalysts with High Performance for Degradation of Methyl Orange under Visible Light