Citation: WANG Peng-Fei, WANG Li-Jun. Zn-Based MOF Containing Rod-Shaped Metal-Carboxylate/Hydroxyl SBU Exhibiting Afterglow Property at Low Temperature[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(12): 2254-2260. doi: 10.11862/CJIC.2018.246 shu

Zn-Based MOF Containing Rod-Shaped Metal-Carboxylate/Hydroxyl SBU Exhibiting Afterglow Property at Low Temperature

WANG Peng-Fei ^1,2,, ,
WANG Li-Jun ¹

1.
School of Chemistry and Material Engineering, Chizhou University, Chizhou, Anhui 247000, China
2.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210023, China

Corresponding author: WANG Peng-Fei, njuwangpf@163.com
Received Date: 22 July 2018
Revised Date: 13 August 2018

Figures(7)

A three-dimensional (3D) porous Zn(Ⅱ)-based framework, {[Zn₄(O-BTC)₂(H₂O)₅]·2DMF·0.5H₂O}_n (1), which is constructed from a multifunctional tricarboxylate ligand, 2-hydroxyl-1, 3, 5-benzenetricarboxylic acid (HO-H₃BTC) and Zn(Ⅱ) salts was prepared. Complex 1 has been characterized by X-ray single-crystal diffraction, PXRD, elemental analysis, infrared spectroscopy, thermogravimetric analysis, and solid-state UV-Vis absorption spectra. Complex 1 exhibits a three-dimensional (3D) framework structure based on the rod-shaped Zn-carboxylate/hydroxyl secondary building unit (SBU). Solid-state luminescence studies showed that 1 exhibits intense blue emission at room temperature. Interestingly, 1 could exhibit afterglow property only under low temperature (10 K) condition.
- MOFs,
- rod-shaped metal-SBU,
- luminescent properties,
- afterglow
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