Citation: ZHAI Li-Jun, NIU Lan-Yu, HAO Xiao-Yan, CHEN Li-Jie, LI Guo-Fang, FAN Li-Ming. Crystal Structures, Magnetic Property, and Photocatalytic Activity of Two Coordination Polymers Based on π-Conjugated Benzenedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1936-1942. doi: 10.11862/CJIC.2018.242 shu

Crystal Structures, Magnetic Property, and Photocatalytic Activity of Two Coordination Polymers Based on π-Conjugated Benzenedicarboxylic Acid

1.
Department of Chemistry and Chemical Engineering, Taiyuan Institute of Technology, Taiyuan 030008, China
2.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Corresponding author: ZHAI Li-Jun, jinzhongzhailijun@163.com FAN Li-Ming, limingfan@nuc.edu.cn
Received Date: 7 July 2018
Revised Date: 13 August 2018

Figures(10)

Two coordination polymers, namely {[Mn₂(L)₂(H₂O)₅]·2H₂O}_n (1) and[Cd(L)(H₂O)₂]_n (2), have been assembled from the π-conjugated ligand of 3, 3'-(1, 3, 6, 8-tetraoxobenzol[lmn][3, 8]-phenanthroline-2, 7(1H, 3H, 6H, 8H)diyl)-di-benzoic acid) (H₂L) under hydrothermal condition. Their structures have been determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses (EA), IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric (TG) analyses. Structural analysis reveals that complex 1 is a 2D sheet with 1D { Mn₃(COO)₂} chain, which was further expanded to a 3D supramolecular structure through hydrogen bonds. While complex 2 is a 1D polymeric chain, which can be packed into a 3D supramolecular through hydrogen bonding interactions. Besides, the variable-temperature susceptibility of 1 as well as the photocatalytic activity of 2 have been investigated.
- coordination polymers,
- crystal structure,
- magentic property,
- photocatalytic activity
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沈阳化工大学材料科学与工程学院沈阳 110142