Citation: QIN Bo, KONG Qing-Lan, LIU Zhi-Ping, YANG Xiao-Na, NING Wei-Wei, DU Yan-Ze, ZHENG Jia-Jun. Synthesis of Monolith Hierarchical Sodalite Zeolite Composed of Nanocrystals by Steam-Assisted Conversion Method[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2025-2031. doi: 10.11862/CJIC.2018.240 shu

Synthesis of Monolith Hierarchical Sodalite Zeolite Composed of Nanocrystals by Steam-Assisted Conversion Method

QIN Bo ^1,2 ,
KONG Qing-Lan ¹ ,
LIU Zhi-Ping ^1,, ,
YANG Xiao-Na ¹ ,
NING Wei-Wei ¹ ,
DU Yan-Ze ^1,2 ,
ZHENG Jia-Jun ^1,,

1.
Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024, China
2.
Dalian Research Institute of Petroleum & Petrochemicals, SINOPEC, Dalian, Liaoning 116045, China

Corresponding author: LIU Zhi-Ping, liuzhiping@tyut.edu.cn ZHENG Jia-Jun, zhengjiajun@tyut.edu.cn
Received Date: 5 July 2018
Revised Date: 21 August 2018

Figures(7)

Hierarchical sodalite (SOD) zeolite was synthesized by "steam-assisted conversion (SAC)" method using the as-synthesized polystyrene (PS) microspheres as templates. The factors affecting the formation of the hierarchical SOD were discussed in details. The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ adsorption-desorption, and mercury intrusion method. The results exhibited that the as-synthesized monolithic SOD zeolite consisted of sphere-like polycrystalline aggregates which were further composed of primary SOD nano-crystals with a size of 50~100 nm. An intercrystalline and intracrystalline mesoporous structure ranging from 2 to 50 nm along with a macropore with 50~300 nm resulted from the removal of PS microspheres were created in the as-prepared SOD samples.
- sodalite,
- zeolite,
- steam-assisted conversion,
- macropores,
- polystyrene microspheres
1. [1]
  Chen W Z, Han D M, Sun X H, et al. Fuel, 2013, 106(2):498-504
2. [2]
  Tukur N M, Al-Khattaf S. Chem. Eng. Process, 2005, 44(11):1257-1268 doi: 10.1016/j.cep.2005.02.009
3. [3]
  Al-sabawi M, Atias J A, de Lasa H. Ind. Eng. Chem. Res., 2008, 47(20):7631-7641 doi: 10.1021/ie701745k
4. [4]
  Kortunov P, Vasenkov S, Krger J, et al. Chem. Mater., 2005, 17(9):2466-2474 doi: 10.1021/cm050031z
5. [5]
  Zhao Q Q, Qin B, Zheng J J, et al. Chem. Eng. J., 2014, 257:262-272 doi: 10.1016/j.cej.2014.07.056
6. [6]
  Zheng J J, Zhang H Y, Liu Y J, et al. Catal. Lett., 2016, 146(8):1457-1469 doi: 10.1007/s10562-016-1776-8
7. [7]
  Du Y Z, Kong Q L, Gao Z H, et al. Ind. Eng. Chem. Res., 2018, 57:7395-7403 doi: 10.1021/acs.iecr.8b00751
8. [8]
  Zhou J, Hua Z L, Liu Z C, et al. ACS Catal., 2011, 1(4):287-291 doi: 10.1021/cs1000976
9. [9]
  Mahrouqi D A, Vinogradov J, Jackson M D. Adv. Colloid Interface Sci., 2017, 240:60-76 doi: 10.1016/j.cis.2016.12.006
10. [10]
  Xue Z T, Ma J H, Hao W M, et al. J. Mater. Chem., 2012, 22(6):2532-2538 doi: 10.1039/C1JM14740D
11. [11]
  Zheng J J, Zhang X W, Zhang Y, et al. Microporous Mesoporous Mater., 2009, 122(1/2/3):264-269
1. [1]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
2. [2]
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3. [3]
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4. [4]
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5. [5]
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6. [6]
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7. [7]
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8. [8]
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9. [9]
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10. [10]
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11. [11]
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12. [12]
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13. [13]
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14. [14]
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15. [15]
  Fei Nie , Jiawei Liu , Chunxin Zhao , Hongbo Cui , Yan Li , Bin Cui . Construction of a Chemical Experimental Demonstration Center Supporting the Cultivation of Top-Notch Innovative Talents under the “Grand Ideological and Political” Framework: A Case Study of Northwest University. University Chemistry, 2024, 39(7): 32-39. doi: 10.12461/PKU.DXHX202404122
16. [16]
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17. [17]
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18. [18]
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19. [19]
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20. [20]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029

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