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Citation: QIN Bo, KONG Qing-Lan, LIU Zhi-Ping, YANG Xiao-Na, NING Wei-Wei, DU Yan-Ze, ZHENG Jia-Jun. Synthesis of Monolith Hierarchical Sodalite Zeolite Composed of Nanocrystals by Steam-Assisted Conversion Method[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(11): 2025-2031. doi: 10.11862/CJIC.2018.240 shu

Synthesis of Monolith Hierarchical Sodalite Zeolite Composed of Nanocrystals by Steam-Assisted Conversion Method

QIN Bo ^1,2 ,
KONG Qing-Lan ¹ ,
LIU Zhi-Ping ^1,, ,
YANG Xiao-Na ¹ ,
NING Wei-Wei ¹ ,
DU Yan-Ze ^1,2 ,
ZHENG Jia-Jun ^1,,

1.
Research Centre of Energy Chemical & Catalytic Technology, Taiyuan University of Technology, Taiyuan 030024, China
2.
Dalian Research Institute of Petroleum & Petrochemicals, SINOPEC, Dalian, Liaoning 116045, China

Corresponding author: LIU Zhi-Ping, liuzhiping@tyut.edu.cn ZHENG Jia-Jun, zhengjiajun@tyut.edu.cn
Received Date: 5 July 2018
Revised Date: 21 August 2018

Figures(7)

Hierarchical sodalite (SOD) zeolite was synthesized by "steam-assisted conversion (SAC)" method using the as-synthesized polystyrene (PS) microspheres as templates. The factors affecting the formation of the hierarchical SOD were discussed in details. The as-synthesized samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N₂ adsorption-desorption, and mercury intrusion method. The results exhibited that the as-synthesized monolithic SOD zeolite consisted of sphere-like polycrystalline aggregates which were further composed of primary SOD nano-crystals with a size of 50~100 nm. An intercrystalline and intracrystalline mesoporous structure ranging from 2 to 50 nm along with a macropore with 50~300 nm resulted from the removal of PS microspheres were created in the as-prepared SOD samples.
- sodalite,
- zeolite,
- steam-assisted conversion,
- macropores,
- polystyrene microspheres
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