Citation: HOU Xue-Dan, GUO Shou-Wu, WANG Qian, WANG Xiao-Fei. Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1910-1916. doi: 10.11862/CJIC.2018.237 shu

Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries

1.
School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi′an 710021, China
2.
School of Materials Science and Chemical Engineering, Xi′an Technological University, Xi′an 710021, China

Corresponding author: GUO Shou-Wu, swguo@sjtu.edu.cn WANG Xiao-Fei, wangxiaof@sust.edu.cn
Received Date: 15 May 2018
Revised Date: 17 August 2018

Figures(4)

Bulk Ni₃Mn-layered double hydroxides (Ni₃Mn-LDHs) was exfoliated into single-layer Ni₃Mn-LDHs nanosheets via liquid phase exfoliation, and then incorporated with CNT to obtain Ni₃Mn-LDHs/CNT composites by self-assemble method. The structure of the composites was characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The electrochemical process was analyzed by galvanostatic tests, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The Ni₃Mn-LDHs/CNT composites improved the ORR and OER catalytic activities significantly, the obtained Ni₃Mn-LDHs/CNT cathode presented nearly 300% higher discharge capacity, excellent rate and cycling stability than the CNT cathode in lithium-oxygen batteries.
- composite materials,
- lithium-oxygen batteries,
- catalyst,
- functional
1. [1]
  Bruce P G, Freunberger S A, Hardwick L J, et al. Nat. Mater., 2012, 11:19-29 doi: 10.1038/nmat3191
2. [2]
  CAI Sheng-Rong, WANG Xiao-Fei, ZHU Ding, et al. Chinese J. Inorg. Chem., 2016, 32(12):2082-2087
3. [3]
  Wang J, Yin Y B, Liu T, et al. Nano Res., 2018, 11:3434-3441 doi: 10.1007/s12274-018-1972-5
4. [4]
  Liu Q C, Chang Z W, Li Z J, et al. Small Methods, 2018, 2:1700231(16 Pages)
5. [5]
  Xu J J, Zhang X B. Nat. Energy, 2017, 2:1-2
6. [6]
  Chang Z, Xu J J, Zhang X B. Adv. Energy Mater., 2017, 7:1-21
7. [7]
  Zhang P, Zhao Y, Zhang X B. Chem. Soc. Rev., 2018, 47:2921-3004 doi: 10.1039/C8CS00009C
8. [8]
  Yang Z D, Chang Z W, Zhang Q, et al. Sci. Bull., 2018, 63:433-440 doi: 10.1016/j.scib.2018.02.014
9. [9]
  Xu J J, Chang Z W, Yin Y B, et al. ACS Cent. Sci., 2017, 3:598-604 doi: 10.1021/acscentsci.7b00120
10. [10]
  Zhu Q C, Du F H, Xu S M, et al. ACS Appl. Mater. Interfaces, 2015, 8:3868-3873
11. [11]
  Yang X Y, Xu J J, Chang Z W, et al. Adv. Energy Mater., 2018, 8:1-7
12. [12]
  Jung J W, Choi D W, Lee C K, et al. Nano Energy, 2018, 46:193-202 doi: 10.1016/j.nanoen.2018.01.045
13. [13]
  Kim J G, Kim Y, Noh Y, et al. ACS Appl. Mater. Interfaces, 2018, 10:5429-5439 doi: 10.1021/acsami.7b14599
14. [14]
  Gao R, Yang Z, Zheng L, et al. ACS Catal., 2018, 8:1955-1963 doi: 10.1021/acscatal.7b03566
15. [15]
  Chang Z W, Meng F L, Zhong H X, et al. Chin. J. Chem., 2018, 36:287-292 doi: 10.1002/cjoc.v36.4
16. [16]
  Meng F L, Chang Z, Xu J, et al. Mater. Horiz., 2018, 5:298-302 doi: 10.1039/C7MH01014A
17. [17]
  Yang Z D, Chang Z W, Xu J J, et al. Sci. China Chem., 2017, 60:1540-1545 doi: 10.1007/s11426-017-9156-0
18. [18]
  Wang Q, O'Hare D. Chem. Rev., 2012, 112:4124-4155 doi: 10.1021/cr200434v
19. [19]
  Chitravathi S, Kumar S, Munichandraiah N. RSC Adv., 2016, 6:103106-103115 doi: 10.1039/C6RA19054E
20. [20]
  Xu S M, Zhu Q C, Long J, et al. Adv. Funct. Mater., 2016, 26:1365-1374 doi: 10.1002/adfm.201504128
21. [21]
  Liu Y, Liu Y, Shi H H, et al. J. Alloys Compd., 2016, 688:380-387 doi: 10.1016/j.jallcom.2016.07.224
22. [22]
  Shao M F, Zhang R K, Li Z H, et al. Chem. Commun., 2015, 51:15880-15893 doi: 10.1039/C5CC07296D
23. [23]
  Song F, Hu X L. Nat. Commun., 2014, 5:1-9
24. [24]
  Zhao M M, Zhao Q X, Li B, et al. Nanoscale, 2017, 9:15206-15225 doi: 10.1039/C7NR04752E
25. [25]
  Liang J B, Ma R Z, Iyi N, et al. Chem. Mater., 2010, 22:371-378 doi: 10.1021/cm902787u
26. [26]
  Jia G, Hu Y F, Qian Q F, et al. ACS Appl. Mater. Interfaces, 2016, 8:14527-14534 doi: 10.1021/acsami.6b02733
27. [27]
  Sun Y F, Gao S, Lei F C, et al. Chem. Soc. Rev., 2014, 44(3):623-636
28. [28]
  Voiry D, Yamaguchi H, Li J W, et al. Nat. Mater., 2013, 12(9):850-855 doi: 10.1038/nmat3700
29. [29]
  Duan X, Song M, Zhang L, et al. New J. Chem., 2017, 41:12789-12794 doi: 10.1039/C7NJ02282D
30. [30]
  Zhu X, Yan Y, Wan W, et al. Mater. Lett., 2018, 215:71-74 doi: 10.1016/j.matlet.2017.12.056
31. [31]
  YI Luo-Cai, CI Su-Qin, SUN Cheng-Li, et al. Prog. Chem., 2016, 28(8):1251-1264
32. [32]
  Wang X F, Wang Q, Hou X D, et al. J. Alloys Compd., 2018, 744:196-203 doi: 10.1016/j.jallcom.2018.02.045
33. [33]
  Wang F, Li H, Wu Q, et al. Electrochim. Acta, 2016, 202:1-7 doi: 10.1016/j.electacta.2016.04.007
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通讯作者: 陈斌, bchen63@163.com

Single-Layer Ni₃Mn-Layered Double Hydroxides as Bifunctional Catalyst for Rechargeable Li-O₂ Batteries