Citation: YANG Li-Guo, WANG Fang, YU You-Zhu, WANG Xin, ZHANG Yong-Hui, YANG Hua, WANG Da-Qi, LI Da-Cheng. Sandwich-Type Tb and Dy Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1891-1898. doi: 10.11862/CJIC.2018.235 shu

Sandwich-Type Tb and Dy Complexes with Schiff-Base Ligand: Syntheses, Crystal Structures and Magnetic Properties

YANG Li-Guo ^1,, ,
WANG Fang ¹ ,
YU You-Zhu ¹ ,
WANG Xin ¹ ,
ZHANG Yong-Hui ¹ ,
YANG Hua ² ,
WANG Da-Qi ² ,
LI Da-Cheng ²

1.
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, Henan 455000, China
2.
School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, Shandong 252000, China

Corresponding author: YANG Li-Guo, lgyang@ayit.edu.cn
Received Date: 15 May 2018
Revised Date: 14 July 2018

Figures(8)

Two new sandwich-type di-lanthanide complexes[M₂L₃(H₂O)] (M=Tb (1), Dy (2), H₂L=N, N'-bis(4-methyloxysalicylidene)benzene-1, 2-diamine) were synthesized by treating the Schiff-base ligand with M(acac)₃·6H₂O (M=Tb, Dy) and characterized by elemental analysis, IR spectra and X-ray single crystal diffraction. X-ray single crystal diffraction analysis reveals that 1 and 2 have a similar new triple-deck dinuclear sandwich structure. The magnetic measurements of complexes 1 and 2 indicated that 1 and 2 exhibit the antiferromagnetic interactions between lanthanide ions, and field-induced slow magnetic relaxation. The deduced effective energy barrier (U_eff) and relaxation time (τ₀) are 35.45 cm^-1 and 2.7×10^-10 s for 2.
- Tb(Ⅲ) and Dy(Ⅲ) complexes,
- Schiff base,
- crystal structures,
- magnetic properties
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