Citation: YU Ji, WEI Hai-Yan, Li LI, YANG Zhen-Yu, CAI Jian-Xin. Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1792-1798. doi: 10.11862/CJIC.2018.232 shu

Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers

College of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: YU Ji, yuji@ncu.edu.cn
Received Date: 16 April 2018
Revised Date: 19 July 2018

Figures(6)

SnO₂ fibers and SnO₂-C fibers were synthesized through electrospun technology and calcined under air or Ar atmosphere. Samples were characterized by different methods. The results showed that SnO₂ fibers and SnO₂-C fibers have a grid-like structure, which can effectively alleviate the disadvantages caused by the huge volume change of SnO₂ during charging-discharging process. SnO₂-C fibers showed a better electrochemical performance than SnO₂ nanoparticles, but worse than that of SnO₂ fibers. SnO₂ fibers could discharged a much high capacity and had a good rate performance and long cycle life at the same time. After working at the current density of 0.4, 0.8, 1.6, 2.4 A·g^-1 and 4 A·g^-1 for 10 cycles, SnO₂ fibers could still discharge a capacity of 1 372, 832, 685, 642 and 599 mAh·g^-1. And when the current density went back to 0.4 A·g^-1, its capacity could arrive 1 113 mAh·g^-1 again. Furthermore, the SnO₂ fibers could also release a high discharge capacity of 613 mAh·g^-1 and almost 100% coulomb efficiency after 200 cycles at the current density of 1.6 A·g^-1, showing an excellent electrochemistry performance.
- lithium-ion battery,
- SnO₂ fibers,
- SnO₂-C fibers,
- anode material,
- electrospinning
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Preparation and Lithium Storage Properties of Grid-like SnO₂ Fibers