Citation: LI Hui-Hua, GE You, ZHU Hong-Li, FENG Xiao-Miao, LIU Yu-Ge. Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes[J]. Chinese Journal of Inorganic Chemistry, ;2018, 34(10): 1799-1807. doi: 10.11862/CJIC.2018.231 shu

Preparation by Electro-Deposition Method and Application in Flexible All-Solid-State Supercapacitors of Poly(3, 4-ethylenedioxythiophene) Microtubes

LI Hui-Hua ¹ ,
GE You ¹ ,
ZHU Hong-Li ¹ ,
FENG Xiao-Miao ^1,, ,
LIU Yu-Ge ^2,,

1.
Key Laboratory for Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials(IAM); Jiangsu National Synergetic Innovation Center for Advanced Materials(SICAM); Nanjing University of Posts & Telecommunications, Nanjing 210023, China
2.
School of Chemistry and Chemical Engineering, Lingnan Normal University, Zhanjiang, Guangdong 524000, China

Corresponding author: FENG Xiao-Miao, iamxmfeng@njupt.edu.cn LIU Yu-Ge, liuyugehb@126.com
Received Date: 16 April 2018
Revised Date: 14 July 2018

Figures(8)

Poly(3, 4-ethylenedioxythiophene) (PEDOT) microtube electrodes doped with different acids and surfactants were obtained by one-step electrochemical deposition method and could be used for flexible and all-solid-state supercapacitors (SCs). We also investigated the effect of deposition time on the capacitance performance of PEDOT microtubes doped with the same acid medium and surfactant. The structures of the final product were characterized by different characterization techniques including scanning electron microscopy (SEM) and FT-IR spectra. The electrochemical results showed that the capacitance of PEDOT microtubes doped with sulfuric acid (H₂SO₄) and sodium dodecyl sulfate (SDS) could be improved significantly. The areal capacitance of the prepared supercapacitor with deposition time of 600 s could achieve to 113.5 mF·cm^-2 at the scan rate of 10 mV·s^-1. The areal capacitances under the different bending angles remained at 93% of initial capacitive value revealing that the supercapacitor had highly mechanical stability. In addition, it remained 95.5% of the initial capacitive value after 2 000 cycles at a current density of 0.6 mA·cm^-2 showing its superior cycling stability. The prepared flexible all-solid-state supercapacitor can power a light-emitting-diode (LED) which meets the practical applications of micro-power supplies.
- electro-deposition,
- solid-state,
- flexible,
- supercapacitor
1. [1]
  Aricò A S, Bruce P, Scrosati B, et al. Nat. Mater., 2005, 4(5):366-377 doi: 10.1038/nmat1368
2. [2]
  Lu Q Q, Wang X Y, Cao J, et al. Energy Storage Mater., 2017, 8:77-84 doi: 10.1016/j.ensm.2017.05.001
3. [3]
  Simon P, Gogotsi Y. Nat. Mater., 2008, 7(11):845-854 doi: 10.1038/nmat2297
4. [4]
  Miller J R, Simon P. Science, 2008, 321(5889):651-652 doi: 10.1126/science.1158736
5. [5]
  Pushparaj V L, Shaijumon M M, Kumar A, et al. Proc. Natl.Acad. Sci., 2007, 104(34):13574-13577 doi: 10.1073/pnas.0706508104
6. [6]
  Shi S, Xu C J, Yang C, et al. Sci. Rep., 2013, 3:2598-2604 doi: 10.1038/srep02598
7. [7]
  Chen T, Dai L M. J. Mater. Chem. A, 2014, 2(28):10756-10775 doi: 10.1039/c4ta00567h
8. [8]
  D′Arcy J M, El-Kady M F, Khine P P, et al. ACS Nano, 2014, 8(2):1500-1510 doi: 10.1021/nn405595r
9. [9]
  Österholm A M, Shen D E, Dyer A L, et al. ACS Appl. Mater.Interfaces, 2013, 5(24):13432-13440 doi: 10.1021/am4043454
10. [10]
  Pandey G, Rastogi A, Westgate C R. J. Power Sources, 2014, 245:857-865 doi: 10.1016/j.jpowsour.2013.07.017
11. [11]
  Hsu Y K, Chen Y C, Lin Y G, et al. J. Power Sources, 2013, 242:718-724 doi: 10.1016/j.jpowsour.2013.05.153
12. [12]
  Tsakova V, Winkels S, Schultze J. Electrochim. Acta, 2001, 46(5):759-768 doi: 10.1016/S0013-4686(00)00643-5
13. [13]
  Patra S, Munichandraiah N. J. Appl. Polym. Sci., 2007, 106(2):1160-1171 doi: 10.1002/(ISSN)1097-4628
14. [14]
  Li W K, Chen J, Zhao J J, et al. Mater. Lett., 2005, 59:800-803 doi: 10.1016/j.matlet.2004.11.024
15. [15]
  Anothumakkool B, Bhange S N, Badiger M V, et al.Nanoscale, 2014, 6(11):5944-5952 doi: 10.1039/c4nr00659c
16. [16]
  Wang Z L, He X J, Ye S H, et al. ACS Appl. Mater.Interfaces, 2014, 6(1):642-647 doi: 10.1021/am404751k
17. [17]
  Selvaganesh S V, Mathiyarasu J, Phani K L N, et al.Nanoscale Res. Lett., 2007, 2(11):546-549 doi: 10.1007/s11671-007-9100-6
18. [18]
  Xu H H, Hu X L, Sun Y M, et al. Nano Res., 2014, 8(4):1148-1158
19. [19]
  Chen Y Q, Zhang X N, Xie Z P. ACS Nano, 2015, 9(8):8054-8063 doi: 10.1021/acsnano.5b01784
20. [20]
  Chen S, Zhu J W, Wang X. ACS Nano, 2010, 4(10):6212-6218 doi: 10.1021/nn101857y
21. [21]
  Wu L X, Li R Z, Guo J L, et al. AIP Adv., 2013, 3(8):082129-082133 doi: 10.1063/1.4820353
22. [22]
  Chen W, Rakhi R B, Hu L B, et al. Nano Lett., 2011, 11(12):5165-5172 doi: 10.1021/nl2023433
23. [23]
  Hu H B, Zhang K, Li S X, et al. J. Mater. Chem. A, 2014, 2(48):20916-20922 doi: 10.1039/C4TA05345A
24. [24]
  Zhao J, Lai H W, Lyu Z Y, et al. Adv. Mater., 2015, 27(23):3541-3545 doi: 10.1002/adma.v27.23
25. [25]
  Xie Y B, Du H X, Xia C. Microporous Mesoporous Mater., 2015, 204:163-172 doi: 10.1016/j.micromeso.2014.11.021
26. [26]
  Yang H L, Xu H H, Li M, et al. ACS Appl. Mater. Interfaces, 2016, 8(3):1774-1779 doi: 10.1021/acsami.5b09526
27. [27]
  Sun J F, Huang Y, Fu C X, et al. J. Mater. Chem. A, 2016, 4(38):14877-14883 doi: 10.1039/C6TA05898A
28. [28]
  Lee J A, Shin M K, Kim S H, et al. Nat. Commun., 2013, 4:1970-1977 doi: 10.1038/ncomms2970
1. [1]
  Huirong BAO , Jun YANG , Xiaomiao FENG . Preparation and electrochemical properties of NiCoP/polypyrrole/carbon cloth by electrodeposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1083-1093. doi: 10.11862/CJIC.20250008
2. [2]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
3. [3]
  Huayan Liu , Yifei Chen , Mengzhao Yang , Jiajun Gu . Strategies for enhancing capacity and rate performance of two-dimensional material-based supercapacitors. Acta Physico-Chimica Sinica, 2025, 41(6): 100063-0. doi: 10.1016/j.actphy.2025.100063
4. [4]
  Yijing GU , Huan PANG , Rongmei ZHU . Applications of nickel-based metal-organic framework compounds in supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2029-2038. doi: 10.11862/CJIC.20250186
5. [5]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
6. [6]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
7. [7]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . Preparation of High Density Activated Carbon by Mechanical Compression of Precursors for Compact Capacitive Energy Storage. Acta Physico-Chimica Sinica, 2025, 41(3): 100028-0. doi: 10.3866/PKU.WHXB202406009
8. [8]
  Yingtong FAN , Yujin YAO , Shouhao WAN , Yihang SHEN , Xiang GAO , Cuie ZHAO . Construction of copper tetrakis(4-carboxyphenyl)porphyrin/silver nanowire composite electrode for flexible and transparent supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1309-1317. doi: 10.11862/CJIC.20250043
9. [9]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
10. [10]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
11. [11]
  Feng Lin , Zhongxin Jin , Caiying Li , Cheng Shao , Yang Xu , Fangze Li , Siqi Liu , Ruining Gu . Preparation and Electrochemical Properties of Nickel Foam-Supported Ni(OH)₂-NiMoO₄ Electrode Material. University Chemistry, 2025, 40(10): 225-232. doi: 10.12461/PKU.DXHX202412017
12. [12]
  Jing Zhang , Su Zhang , Qiqi Li , Linken Ji , Yutong Li , Yukang Ren , Xiaobei Zang , Ning Cao , Han Hu , Peng Liang , Zhuangjun Fan . Integrating high surface area and electric conductivity in activated carbon by in situ formation of the less-defective carbon network during selective chemical etching. Acta Physico-Chimica Sinica, 2025, 41(10): 100114-0. doi: 10.1016/j.actphy.2025.100114
13. [13]
  Ao XIA , Botao YU , Jun CHEN , Guoqiang TAN . Preparation and electrochemical property of Ce-doped MnO₂. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2514-2526. doi: 10.11862/CJIC.20250163
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
16. [16]
  Huimin Liu , Kezhi Li , Xin Zhang , Xuemin Yin , Qiangang Fu , Hejun Li . SiC Nanomaterials and Their Derived Carbons for High-Performance Supercapacitors. Acta Physico-Chimica Sinica, 2024, 40(2): 2304026-0. doi: 10.3866/PKU.WHXB202304026
17. [17]
  Yan XU , Suzhi LI , Yan LI , Lushun FENG , Wentao SUN , Xinxing LI . Structure variation of cadmium naphthalene-diphosphonates with the changing rigidity of N-donor auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 395-406. doi: 10.11862/CJIC.20240226
18. [18]
  Tengjiao Wang , Tian Cheng , Rongjun Liu , Zeyi Wang , Yuxuan Qiao , An Wang , Peng Li . Conductive Hydrogel-based Flexible Electronic System: Innovative Experimental Design in Flexible Electronics. University Chemistry, 2024, 39(4): 286-295. doi: 10.3866/PKU.DXHX202309094
19. [19]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
20. [20]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(3304)
HTML views(737)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142